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用Ti02-ACF降解甲苯和二甲苯的研究
引用本文:刘亚兰,李坚,耿绍辉.用Ti02-ACF降解甲苯和二甲苯的研究[J].北京林业大学学报,2012,34(5):157-160.
作者姓名:刘亚兰  李坚  耿绍辉
作者单位:东北林业大学生物质材料科学与技术教育部重点实验室;东北林业大学生物质材料科学与技术教育部重点实验室;东北林业大学生物质材料科学与技术教育部重点实验室
基金项目:黑龙江省科技厅自然基金项目(Z200922)
摘    要:将用Sol-Gel法制得的二氧化钛(TiO2)负载到活性碳纤维(ACF)上,利用超临界干燥手段和450 ℃高温真空煅烧工艺获得了具有气凝胶特性和高光催化活性的复合材料(TiO2-ACF),并探讨该材料对空气中甲苯和二甲苯的降解效果。结果表明: TiO2均匀负载在ACF的每根纤维上;TiO2粒径尺寸均在15~20 nm范围内,晶型为锐钛矿和金红石混合晶型,锐钛矿占77%;在紫外光的作用下,TiO2-ACF对甲苯和二甲苯的降解率比ACF约高30%。 

关 键 词:TiO2-ACF光催化材料  降解  甲苯  二甲苯
收稿时间:1900-01-01

Degradation toluene and xylene by TiO2-ACF photocatalytic material.
LIU Ya-lan,LI Jian,GENG Shao-hui..Degradation toluene and xylene by TiO2-ACF photocatalytic material.[J].Journal of Beijing Forestry University,2012,34(5):157-160.
Authors:LIU Ya-lan  LI Jian  GENG Shao-hui
Institution:Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin, 150040, P. R. China.
Abstract:Photocatalytic degradation of toluene and xylene in the air was investigated using titanium dioxide ( TiO 2 ) loaded on activated carbon fibers( ACF) . The TiO 2 and ACF combination ( TiO 2 -ACF ) was prepared by sol-gel,followed by supercritical fluid CO 2 dry process and calcination at 450 ℃ under the vacuum. And the aerogel properties of TiO 2 -ACF were obtained. SEM observation showed that the particles of TiO 2 were uniform with an average size of about 15 - 20 nm,and TiO 2 was deposited on almost each carbon fiber. After XRD analysis,anatase ratio was 77% ; TiO 2 -ACF may effective eliminate or reduce toluene and xylene in the air,and photocatalytic degradation was 30% higher than ACF.
Keywords:TiO2-ACF photocatalytic material  degradation  toluene  xylene
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