| 碱性功能化离子液体在Knoevenagel缩合反应中的应用进展 |
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| 引用本文： | 胡小梅,张必弦.碱性功能化离子液体在Knoevenagel缩合反应中的应用进展[J].东北农业大学学报,2011,42(6):141-144. |
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| 作者姓名： | 胡小梅 张必弦 |
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| 作者单位： | 1. 东北农业大学生命科学学院,哈尔滨,150030
2. 黑龙江省农业科学院,哈尔滨,150086 |
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| 基金项目： | 黑龙江省科技厅留学基金(LC201027); 哈尔滨市科技创新人才研究专项资金项目(留学回国项目)(2011RFLXS028) |
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| 摘 要： | Knoevenagel缩合反应被广泛应用于合成香豆素、化妆品及药物中间体功能化离子液体的设计、合成为Knoevenagel缩合反应提供了高效、环保的制备途径。以功能化离子液体为催化剂或者溶剂，一系列的醛和酮类化合物与活泼亚甲基化合物的缩合反应可以顺利进行，避免了使用额外的催化剂。文章综述了碱性功能化离子液体在Knoev...
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| 关 键 词： | 碱性功能化离子液体 Knoevenagel缩合反应 醛 酮 亚甲基化合物 |
Application of basic functional ionic liquids for knoevenagel reactions |
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| Hu Xiaomei,ZHANG Bixian.Application of basic functional ionic liquids for knoevenagel reactions[J].Journal of Northeast Agricultural University,2011,42(6):141-144. |
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| Authors: | Hu Xiaomei ZHANG Bixian |
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| Institution: | HU Xiaomei1,ZHANG Bixian2(1.College of Life and Sciences,Northeast Agricultural University,Harbin 150030,China,2.Heilongjiang Academy of Agricultural Sciences,Harbin 150086,China) |
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| Abstract: | The Knoevenagel condensation reaction has been widely used to prepare coumarins,cosmetics,and pharmaceuticals.The application of functional Ionic liquids provides a high efficient and environmental friendly approach for Knoevenagel condensation reaction.Reactions of a wide range of aldehydes and ketones with methylene compounds proceed smoothly with ionic liquids as catalysts and solvents.In this paper,the progress in the use of functional ionic liquids for Knoevenagel reactions is reviewed. |
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| Keywords: | basic functional ionic liquids Knoevenagel condensation reaction aldehyde ketone methylene compounds |
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