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丙烯酸共聚物-有机膨润土复合高吸水性树脂的研究
引用本文:陈飞,唐宏科.丙烯酸共聚物-有机膨润土复合高吸水性树脂的研究[J].安徽农业科学,2010,38(18):9792-9794.
作者姓名:陈飞  唐宏科
作者单位:陕西科技大学,教育部轻化工助剂化学与技术重点实验室,陕西西安,710021
基金项目:陕西科技大学科研启动基金项目 
摘    要:采用丙烯酸(AA)、丙烯酰胺(AM)、丙烯酸甲酯(MA)为单体与有机膨润土复合,通过水溶液共聚法制备复合高吸水性树脂。考察丙烯酸中和度、单体配比、引发剂用量、交联剂用量、有机膨润土用量、反应温度对产品吸水倍率的影响。得到了最佳聚合反应条件:丙烯酸中和度75%,单体n(NaAA)∶n(AM)∶n(MA)=8∶2∶1,引发剂用量0.25%,交联剂用量0.03%,反应温度75℃。此条件下制备的高吸水性树脂对蒸馏水和0.9%盐水的吸收倍率分别为850和120 g/g。

关 键 词:高吸水性树脂  水溶液共聚  膨润土

Research on Acrylic Acid Copolymer-Organic Bentonite Combined High-hydrophilia Resin
CHEN Fei et al.Research on Acrylic Acid Copolymer-Organic Bentonite Combined High-hydrophilia Resin[J].Journal of Anhui Agricultural Sciences,2010,38(18):9792-9794.
Authors:CHEN Fei
Institution:CHEN Fei et al(Shaanxi University of Science and Technology,Key Laboratory of Auxiliary Chemistry and Technology for Light and Chemical Industry,Ministry of Education,Xi'an,Shaanxi 710021)
Abstract:The acrylic acid(AA),acrylamide(AM) and methyl acrylate(MA) were used as monomers to compound with organic bentonite and then the compound high-hydrophilia resin was prepared by water solution copolymerization.The influences of neutralization degree of AA,monomer match,dosages of primer,cross-linking agent and organic bentonite,and reaction temperature on the multiplying factor of the product were investigated.The optimum polymerization condition was obtained as follows: the neutralization degree of AA was ...
Keywords:High-hydrophilia resin  Water solution copolymerization  Bentonite  
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