| 纳米CuI催化偶联反应合成二苯醚类农药中间体 |
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| 引用本文： | 潘攀,蔡振亚,叶加久,杨春燕,徐小岚.纳米CuI催化偶联反应合成二苯醚类农药中间体[J].现代农业科技,2010(9):25-26. |
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| 作者姓名： | 潘攀 蔡振亚 叶加久 杨春燕 徐小岚 |
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| 作者单位： | 1. 合肥工业大学化学工程学院,安徽合肥,230009
2. 可控化学与材料化工安徽省重点实验室;安徽医科大学基础医学院 |
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| 基金项目： | 安徽高校省级自然科学研究重点项目 |
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| 摘 要： | 二苯醚是一种重要的农药中间体,通过W/O微乳法,制备出形貌均一的球状纳米CuI,并应用于催化C-O交叉偶联反应中,在温和的反应条件下,合成了具有优良产率的二苯醚类化合物,该方法可在今后的农药合成中应用。
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| 关 键 词： | 纳米碘化亚铜 二苯醚 W/O微乳液 交叉偶联反应 农药合成 |
Preparation of Nano-CuI and its Application to Synthesis of Diphenyl Ethers |
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| Authors: | PAN Pan CAI Zhen-ya YE Jia-jiu YANG Chun-yan XU Xiao-lan |
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| Institution: | PAN Pan1 CAI Zhen-ya1 YE Jia-jiu1 YANG Chun-yan1 XU Xiao-lan2,3 (1School of Chemical and Engineering,Hefei University of Technology,Hefei Anhui 230009,2Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering,3College of Basic Medicine,Anhui Medical University) |
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| Abstract: | Diphenyl ether is a very important pesticide intermediate. The nano-CuI was prepared in microemulsion which was applied to C-O cross-coupling reaction. Excellent yields of corresponding products were achieved in mild conditions.Such method could be applied in pesticide syntyesis. |
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| Keywords: | nano-CuI diphenyl ether W/O microemulsion cross-coupling pesticide syntyesis |
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