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氯化物催化合成甲,乙,丙酸异戊酯的活性和机理探讨
引用本文:杨仕豪,李莉萍.氯化物催化合成甲,乙,丙酸异戊酯的活性和机理探讨[J].湛江医学院学报,1996,14(2):128-129,126.
作者姓名:杨仕豪  李莉萍
作者单位:广东医学院化学教研室
摘    要:本文分别用氯化铁,氯化铝和氯化铜催化合成甲、乙、丙酸异戊酯,实验证明氯化铁,氯化铝有较高催化活性,对五个碳以下的有机酸和醇的酯化活性较高,并对其机理进行了的探讨。

关 键 词:甲酸异戊酯  乙酸异戊酯  活性  合成  氯化物

THE CATALYTIC ACTIVITY OF CHLORIDES IN THE SYNTHESIS OF ISOAMYL FORMATE,ACETATE AND PROTIONATE
Yang Shihao,Li Liping,Luo Hui.THE CATALYTIC ACTIVITY OF CHLORIDES IN THE SYNTHESIS OF ISOAMYL FORMATE,ACETATE AND PROTIONATE[J].Journal of Guangdong Medical College,1996,14(2):128-129,126.
Authors:Yang Shihao  Li Liping  Luo Hui
Abstract:Using ferric chloride,aluminum chloride and cupric chloride as catalytics in the synthesis of isoamyl formate,acetate and propionate. The results shown that Fecl3 and Alcl3 have good catalytic activities. Authors consider that organic acids and alcohols having carbon atoms lesser than 6 would be easily esterified by these chlorides.The mechanism of is discussed.
Keywords:ferric chloride  aluminum chloride  cupric chloride  estrification  activity  
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