耕作年限对水稻土有机碳分布和腐殖质结构特征的影响

分析比较了浙江慈溪耕作年限为50、100、500、700、1 000、2 000 a的水稻土剖面和不同粒级复合体中有机碳的分布特征,并利用红外光谱技术,探讨了长期耕作对水稻土腐殖质结构和功能基团的影响。结果表明,耕作年限在50~2 000 a范围内,稻田耕作表层有机碳含量受耕作年限影响不大,随着耕作年限的增加,约30~60 cm深度土层中有机碳含量有升高趋势。稻田土壤0~40 cm土层和40~80 cm土层有机碳储量变化幅度(Δ)随着耕作年限的增加逐渐下降,表明早期开垦的水稻土仍有很大的固碳潜力。100、500、1 000a水稻土耕作表层中,<2μm复合体的有机碳含量受耕作年限影响不大;随着耕作年限延长,<2μm复合体有机碳分配系数不断增大,10~50μm复合体有机碳分配系数则呈下降趋势。100、500、700 a水稻土胡敏酸的芳化度随耕作年限增加有所提高,500和700 a水稻土胡敏酸的脂肪族-CH2-、-CH3基团含量要高于100 a水稻土,胡敏酸的聚合程度基本上不受耕作年限影响。

EFFECT OF CULTIVATION HISTORY ON DISTRIBUTION OF ORGANIC CARBON AND STRUCTURE OF HUMUS IN PADDY SOILS

Distribution of organic carbon was studied in soil profiles and organo-mineral complex,different in particle size,sampled from paddy fields varying in cultivation history,50,100,500,700,1 000 and 2 000 years in Cixi City,Zhejiang Province.Effect of long-term cultivation on structure and functional groups of humus in paddy soils was explored with the aid of infrared spectrum(IR).It seemed that cultivation history did not have much effect on organic carbon content in topsoil of the paddy fields.Organic carbon...