改良剂对镉污染酸性水稻土的修复效应与机理研究

为探明田间条件下施用石灰、钙镁磷肥、海泡石和腐殖酸等改良剂对Cd污染酸性水稻土的修复效应和作用机理, 通过在Cd污染区建立田间小区试验, 研究了改良剂单施和与石灰配施对Cd污染酸性水稻土中Cd作物有效性的影响。结果表明, 施用改良剂有效地改变了土壤中Cd的存在形态, 除腐殖酸外, 其他改良剂均使土壤酸提取态Cd不同程度地转化为可还原态Cd和残渣态Cd; 施用改良剂可使0.1 mol·L^-1 NaNO₃和 0.01 mol·L^-1CaCl₂提取态Cd 降低26%~97%, 降低效果为石灰+海泡石>海泡石>石灰+钙镁磷肥>钙镁磷肥>石灰>石灰+腐殖酸>腐殖酸; 改良剂使水稻地上部分的Cd吸收量降低6%~49%。试验结果还显示, 施用改良剂提高土壤pH是引起土壤中Cd作物有效性降低的主要原因之一。根据田间试验的结果, 海泡石可推荐作为Cd污染酸性水稻土的改良剂, 而腐殖酸则不宜使用。

Effects and mechanisms of amendments on remediation of cadmium contaminated acid paddy soils

A field experiment was conducted to study Cd immobilization in Cd contaminated soils. The study analyzed the remediation effects of lime (L), fused calcium magnesium phosphate (P), sepiolite (S), humic acid (H) and mixed lime amendments (LP, LS and LH) on Cd bioavailability in a Cd contaminated acid paddy soils. The results indicate that amendments significantly change the proportion of Cd forms in contaminated soils. Except for H, the other 3 amendments lower acid extractable fraction of Cd, while increasing oxidation fraction and residual Cd. The 4 amendments reduce the 0.1 mol·L^-1 NaNO₃ and 0.01 mol·L^-1 CaCl₂ extracted Cd by 26%~97%. The order of reduction is LS > S > LP > P > L > LH > H. The content of Cd in the aboveground parts of rice decreases by 6%~49% under amendment application. Amendment increasing soil pH is the main factor influencing soil Cd immobilization. In conclusion therefore, sepiolite could be a suitable amendment of Cd contaminated acid paddy soils. However, humic acid is not so suitable for remediating Cd contaminated acid paddy soils.