| Abstract: | In a rural community (Stephanskirchen, Southern Germany) situated near a waste incineration plant six A horizons were sampled to determine 14 polychlorinated biphenyls (PCBs) in bulk soil and particle size separates (clay, silt, fine and coarse sand) and to test the suitability of alkaline saponification for PCB extraction. The PCB concentrations were higher in alkaline saponification extracts than in Soxhlet extracts. However, the extraction efficiency of up to fourfold chlorinated PCBs was lower and more than sevenfold chlorinated PCBs were destroyed. Nevertheless, alkaline saponification was suitable to determine the indicator congeners 28, 52, 101, 138, 152, and 180. The sum of the PCB concentrations ranged from 8.4 to 59.5 μg kg?1 which was as high as in soils of big cities. However, the concentrations did not reach the threshold value for agricultural purposes of 200 μg kg?1 as proposed in literature for the sum of the six indicator congeners. The hexachlorinated PCBs 138 and 153 were the most abundant (together > 50% in all samples) whereas PCB 1 could not be detected in any sample. On the average, PCB concentrations increased as particle size decreased. When normalized to Corg, however, the fine sand fraction had the highest PCB concentrations. A slight decrease of lower chlorinated PCBs as particle size decreased indicated an increasing state of degradation. The PCB compositions in the emissions of a comparable waste incineration plant (Bamberg, Bavaria) and in Stephanskirchen soils differed markedly. Therefore, we did not get any indications that waste incineration was a main source of PCBs in the examined soils. Instead, higher chlorinated technical PCB mixtures such as Clophen A 60 or Aroclor 1260 may be the most important sources. |
