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淡水养殖珍珠棱柱层的微结构形貌特征
引用本文:严俊,邓小琼,胡丹静,方诗彬,刘培钧,方飚,胡仙超. 淡水养殖珍珠棱柱层的微结构形貌特征[J]. 南方水产, 2013, 0(1): 48-52
作者姓名:严俊  邓小琼  胡丹静  方诗彬  刘培钧  方飚  胡仙超
作者单位:[1]浙江省质量检测科学研究院黄金珠宝检测中心,浙江杭州310013 [2]浙江工业大学分析测试中心,浙江杭州310014
基金项目:浙江省质监局系统重大研究专项(20110103);浙江省教育厅项目(Y201225711)
摘    要:
通过x射线粉晶衍射(XRD)、场发射扫描电镜(FE—SEM)对不同颜色的淡水养殖珍珠的微结构进行较系统研究。结果表明,质优的珍珠其矿物相为文石,未见有方解石或球文石相,不同颜色的珍珠质层文石板片的厚度存在较大差异。质量较好的珍珠中接近珍珠核心区域存在棱柱层,该棱柱层由众多的纤维或条带状文石结晶体聚集而成,其中文石纤维或条带的定向近平行于珍珠层文石板片。此外,首次发现在淡水养殖珍珠的棱柱层中文石纤维与板片结晶体交替出现,同时初步建立了一种新的淡水养殖珍珠的内部结构模型。

关 键 词:淡水养殖珍珠  微结构  棱柱层  文石纤维

Microscopic morphology of prismatic layers of freshwater cultured pearl
YAN Jun,DENG Xiaoqiong,HU Danjing,FANG Shibin,LIU Peijun,FANG Biao,HU Xianchao. Microscopic morphology of prismatic layers of freshwater cultured pearl[J]. South China Fisheries Science, 2013, 0(1): 48-52
Authors:YAN Jun  DENG Xiaoqiong  HU Danjing  FANG Shibin  LIU Peijun  FANG Biao  HU Xianchao
Affiliation:1. Zhejiang Gold & Gem Quality Test Center, Zhejiang Test Academy of Quality, Hangzhou 310013, China; 2. Research Center of Analysis and Measurement, Zhefiang University of Technology, Hangzhou 310014, China)
Abstract:
The microscopic morphology of the internal structure of freshwater cultured pearl with different colors were investigated by X- ray diffraction (XRD) and field emission-scanning electronic microscope (FE-SEM). Results clearly reveal that aragonite is found in high quality freshwater cultured pearls, but calcite and vaterite are not found, and the thickness of aragonite sheet in nacreous layer is not the same to pearls with different colors. The prismatic layer is near to the nucleus of the high quality pearls, which is made of a number of cylindrical or banded aragonite fibers. The fibers are oriented nearly parallel to the aragonite sheet. In addition, it is firstly observed that the aragonite fiber and sheet appear alternately in prismatic layer. Meanwhile, a modified model of the internal structure of freshwater cultured pearls is firstly established.
Keywords:freshwater cultured pearl  microstructure  prismatic layer  aragonite fiber
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