两种离子液体对Cd2+在四种土壤上吸附的影响

研究了2，3-吡啶二羧酸和咪唑-4，5-二羧酸两种离子液体阳离子部分对Cd2+在四种不同性质土壤上吸附的影响。结果表明，离子液体的存在显著影响了Cd2+在土壤中的吸附，与对照相比，添加1 mmol·L-12，3-吡啶二羧酸使得Cd2+在武进漂洗型水稻土、吴县潴育型水稻土、南京黄褐土和宜兴棕红壤四种土壤上的最大吸附量分别降低209、834、667、509 mg·kg-1，而添加1 mmol·L-1咪唑-4,5-二羧酸使Cd2+最大吸附量分别降低226、54、124、81 mg·kg-1，2，3-吡啶二羧酸对Cd2+在供试土壤上吸附量的影响显著大于咪唑-4，5-二羧酸。基于离子选择电极分析了平衡液中自由态Cd2+含量，发现两种离子液体都能与Cd2+络合，从而降低平衡液中Cd2+含量，其中2，3-吡啶二羧酸与Cd2+的络合能力大于咪唑-4，5-二羧酸。两种离子液体进入环境，会使Cd2+在土壤上的吸附量减少，从而增加Cd2+的移动性和环境风险。

Effects of two ionic liquids on Cd2+adsorption on four soils

The effects of 2,3-Pyridinedicarboxylic acid and 4,5-Imidazoledicarboxylic acid on Cd2+adsorption on four soils with different characteristics(Wujin, Wuxian, Nanjing and Yixing soils)were investigated. Results showed that the adsorption of Cd2+on soils depended on the characteristics of soils. The presence of ionic liquids significantly affected the adsorption of Cd2+on soils. Compared with the control, the presence of 1 mmol·L-1 2,3-Pyridinedicarboxylic acid reduced the maximum adsorption of Cd2+on Wujin, Wuxian, Nanjing and Yixing soils by 209, 834, 667 and 509 mg·kg-1, respectively, whereas adding 1 mmol·L-1 4,5-Imidazoledicarboxylic acid decreased the maximum Cd2+adsorption by 226, 54, 124 and 81 mg·kg-1 on Wujin, Wuxian, Nanjing, and Yixing soils, respectively. Therefore, 2,3-Pyridinedicar-boxylic acid showed greater effects on Cd2+adsorption on tested soils than 4,5-Imidazoledicarboxylic acid did. The free Cd2+ions in the e-quilibrium solution measured by Cd ion selective electrode showed that both ionic liquids were able to complex with Cd2+, leading to de-creased Cd2+ ion concentrations in soil solution, and consequently reduced Cd2+ adsorption on soils. The complexing capability of 2,3-Pyridinedicarboxylic was stronger than that of 4,5-Imidazoledicarboxylic acid, which resulted in greater inhibition of Cd2+sorption on soils. Our results indicate that ionic liquids could decrease the adsorption of Cd2+on soils, but increase the mobilization and environmental risk of soil Cd2+.