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超声辅助磁性纳米四氧化三铁催化过氧化氢降解亚甲蓝染料的研
引用本文:赵孝梨,陈昱瑾,董入源,黄玉明.超声辅助磁性纳米四氧化三铁催化过氧化氢降解亚甲蓝染料的研[J].西南农业大学学报,2012,34(5):042-045.
作者姓名:赵孝梨  陈昱瑾  董入源  黄玉明
作者单位:西南大学化学化工学院;三峡库区生态环境教育部重点实验室
基金项目:国家自然科学基金资助项目(21075099)
摘    要:建立了一种基于超声辅助磁性四氧化三铁纳米微粒催化过氧化氢降解亚甲蓝染料的方法,研究了四氧化三铁纳米微粒浓度、过氧化氢浓度、pH值、反应时间、超声时间和温度等对催化降解反应的影响.结果表明,当四氧化三铁纳米粒子浓度为600mg/L,过氧化氢浓度为0.32mol/L,pH值为5,超声时间为3min,温度为30℃,反应时间为2h时,模拟染料废水中亚甲蓝的去除率最高可达到95%.

关 键 词:催化降解  磁性纳米四氧化三铁  亚甲蓝  过氧化氢

Sono-AssistedDegradationofMethyleneBluewith H2O2CatalyzedbyFe3O4 MagneticNanoparticles
ZHAO Xiao-li,CHEN Yu-jin,DONG Ru-yuan,Huang Yu-ming.Sono-AssistedDegradationofMethyleneBluewith H2O2CatalyzedbyFe3O4 MagneticNanoparticles[J].Journal of Southwest Agricultural University,2012,34(5):042-045.
Authors:ZHAO Xiao-li  CHEN Yu-jin  DONG Ru-yuan  Huang Yu-ming
Institution:College of Chemistry and Chemical Engineering;Key Laboratory of Eco-environments in Three Gorges Reservoir Region,Ministry of Education,Southwest University,Chongqing 400715,China
Abstract:A sono-assisted degradation method for methylene blue with H2O2 catalyzed by Fe3O4 magnetic nanoparticles was developed in the present study.Various factors affecting degradation of methylene were investigated including concentrstion of Fe3O4 nanoparticles,concentration of H2O2,solution pH,reaction time,ultrasonic time,and solution temperature.Under the optimal experimental conditions of 600 mg/L of nano-Fe3O4,0.32 mol/L of hydrogen peroxide,pH at 5,3 min of ultrasonic time,30 ℃ of solution temperature,and 2 h of reaction time,the removal efficiency of methylene blue was as high as 95%.
Keywords:catalytic degradation  magnetic Fe3O4 nanoparticles  methylene blue  hydrogen peroxide
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