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Antioxidant properties of blackberry and blueberry fruits grown in the Black Sea Region of Turkey
Authors:Ilkay Koca  Bulent Karadeniz
Institution:Ondokuz Mayis University, Faculty of Engineering, Food Engineering Department, Samsun 55139, Turkey
Abstract:Seven wild and ten cultivated blackberries (Arapaho, Bartin, Black Satin, Bursa 1, Bursa 2, Cherokee, Chester, Jumbo, Navaho, and Ness), and six lowbush (Vaccinium arctostaphylos) and four highbush (Vaccinium corymbosum) blueberries fruits (Ivanhoe, Jersey, Northland, and Rekord) were analyzed for total anthocyanins, total phenolics, and antioxidant activity as ferric reducing antioxidant power (FRAP) in this study. The respective ranges of total anthocyanin and total phenolic contents of the tested samples were: blackberries, 0.95–1.97 and 1.73–3.79 mg g−1 and blueberries, 0.18–2.94 and 0.77–5.42 mg g−1. FRAP values varied from 35.05 to 70.41 μmol g−1 for blackberries, 7.41 to 57.92 μmol g−1 for blueberries. Wild blackberries had the highest FRAP values while wild blueberries had the highest total phenolic and total anthocyanin contents. A linear relationship was observed between FRAP values and total phenolics for blueberries (r = 0.981). The anthocyanin pigments in samples were isolated and characterized by high-performance liquid chromatography (HPLC) with UV–visible detection. Cyn-3-glu was the predominant anthocyanin in all blackberry fruits.
Keywords:Cyn  cyanidin  plg  pelargonidin  peo  peonidin  malv  malvidin  delp  delphinidin  pet  petunidin  rut  rutinose  glu  glucoside  gal  galactoside  ara  arabinoside  HPLC  high-performance liquid chromatography  FRAP  ferric reducing antioxidant power  TACN  total anthocyanin  ORAC  oxygen radical-absorbing capacity  std dev  standard deviation
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