| Abstract: | A long‐term fertilizer experiment, over 27 years, studied the effect of mineral fertilizers and organic manures on potassium (K) balances and K release properties in maize‐wheat‐cowpea (fodder) cropping system on a Typic Ustochrept. The treatments consisted of control, 100% nitrogen (100% N), 100% nitrogen and phosphorus (100% NP), 50% nitrogen, phosphorus, and potassium (50% NPK), 100% nitrogen, phosphorus, and potassium (100% NPK), 150% nitrogen, phosphorus, and potassium (150% NPK), and 100% NPK+farmyard manure (100% NPK+FYM). Nutrients N, P, and K in 100% NPK treatment were applied at N: 120 kg ha—1, P: 26 kg ha—1, and K: 33 kg ha—1 each to maize and wheat crops and N: 20 kg ha—1, P: 17 kg ha—1, and K: 17 kg ha—1 to cowpea (fodder). In all the fertilizer and manure treatments removal of K in the crop exceeded K additions and the total soil K balance was negative. The neutral 1 N ammonium acetate‐extractable K in the surface soil (0—15 cm) ranged from 0.19 to 0.39 cmol kg—1 in various treatments after 27 crop cycles. The highest and lowest values were obtained in 100% NPK+FYM and 100% NP treatments, respectively. Non‐exchangeable K was also depleted more in the treatments without K fertilization (control, 100% N, and 100% NP). Parabolic diffusion equation could describe the reaction rates in CaCl2 solutions. Release rate constants (b) of non‐exchangeable K for different depth of soil profile showed the variations among the treatments indicating that long‐term cropping with different rates of fertilizers and manures influenced the rate of K release from non‐exchangeable fraction of soil. The b values were lowest in 100% NP and highest in 100% NPK+FYM treatment in the surface soil. In the sub‐surface soil layers (15—30 and 30—45 cm) also the higher release rates were obtained in the treatments supplied with K than without K fertilization indicating that the sub‐soils were also stressed for K in these treatments. |
