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木屑快速热裂解生物油特性及其红外光谱分析
引用本文:吴汉靓,刘荣厚,邓春健.木屑快速热裂解生物油特性及其红外光谱分析[J].农业工程学报,2009,25(6):219-223.
作者姓名:吴汉靓  刘荣厚  邓春健
作者单位:上海交通大学农业与生物学院生物质能工程研究中心,上海,200240
基金项目:国家863计划项目资助(2008AA05Z404)
摘    要:该文以杨木木屑快速热裂解制取的生物油为原料,对其进行了理化特性研究及傅立叶变换红外光谱(FTIR)分析,同时和甜高粱茎秆残渣热裂解生物油的特性进行了比较。结果表明,木屑生物油含水率较低(25.01%),热值较高(20.62 MJ/kg),常温下运动黏度为3.44 mm2/s,密度、灰分含量和残炭值分别为1072 kg/m3,0.305%,12.74%,且呈明显的酸性(pH=3.07)。随着温度的升高(25~100℃),木屑生物油运动黏度明显降低。木屑生物油的较低含水率和较高热值,使其在应用方面优于甜高粱茎秆残渣生物油。然而,从傅立叶变换红外光谱图上不同位置的吸收峰可以判断木屑生物油含有多种官能团,实际应用之前需要进一步的精制。

关 键 词:理化性质,热裂解,运动黏度,生物油,水分含量,木屑
收稿时间:8/6/2008 12:00:00 AM
修稿时间:2009/5/15 0:00:00

Properties and Fourier transform infrared spectrum analysis on bio-oil from fast pyrolysis of poplar sawdust
Wu Hanjing,Liu Ronghou and Deng Chunjian.Properties and Fourier transform infrared spectrum analysis on bio-oil from fast pyrolysis of poplar sawdust[J].Transactions of the Chinese Society of Agricultural Engineering,2009,25(6):219-223.
Authors:Wu Hanjing  Liu Ronghou and Deng Chunjian
Institution:Biomass Energy Engineering Research Center;School of Agriculture and Biology;Shanghai Jiao Tong University;Shanghai 200240;China
Abstract:Research of physical-chemical properties and Fourier Transform Infrared Spectrum(FTIR)analysis were conducted on bio-oil which was obtained through fast pyrolysis of poplar sawdust,apart from comparing with bio-oil from sweet sorghum stalk residues.The results showed that water content and heating value of bio-oil from sawdust was 25.01%and 20.62 MJ/kg,and its kinematic viscosity at room temperature,density,ash content and carbon residue content were 3.44 mm 2 /s,1072 kg/m 3 ,0.305%and 12.74%,respectively.S...
Keywords:physical-chemical properties  pyrolysis  kinematic viscosity  bio-oil  water content  poplar sawdust
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