| 新手性吡啶类配体的合成及其不对称诱导性能研究 |
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| 引用本文： | 臧二乐.新手性吡啶类配体的合成及其不对称诱导性能研究[J].中国农业大学学报,1995(3):312-316. |
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| 作者姓名： | 臧二乐 |
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| 作者单位： | 北京农业大学应用化学系;100094; |
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| 摘 要： | 以2,6-二甲基吡啶和2,6-二溴吡啶为原料,经锂试剂分别与光学活性的樟脑、薄荷酮和3-甲酰基蒎烷反应合成了4个新的手性吡啶类化合物。测定了它们在苯甲醛和二乙基锌加成反应中的不对称诱导性能。
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| 关 键 词： | 吡啶衍生物 烷基化反应 不对称合成 |
| 收稿时间： | 1994/6/8 0:00:00 |
Studies on Synthesis of New Chiral Ligands Containing Pyridine and Their Properties in Asymmeiric Induction |
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| Zang Erle.Studies on Synthesis of New Chiral Ligands Containing Pyridine and Their Properties in Asymmeiric Induction[J].Journal of China Agricultural University,1995(3):312-316. |
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| Authors: | Zang Erle |
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| Institution: | Zang Erle (Dept.of Applied Chemistry,BAU,Beijing 100094) |
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| Abstract: | Several chiral ligands containing pyridine were prepared from 2,6-dimethyl pyridine or 2,6- dibromopyridine via their lithium reagents.Their asymmetric induction was observed in the reaction of benzaldehyde and diethyl zinc. |
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| Keywords: | pyridine derivatives alkylating reaction asymmetric synthesis |
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