Iron minerals in soils on red-earth deposits in the Cis-Ural region

In soils developed from the red-earth deposits in the Cis-Ural region (Perm oblast), hematite does not ensure the theoretically possible redness due to the concealing effect of rivaling pigments, i.e., humus in the upper horizons and Fe(II) in the gleyed horizons. The soil color depends on the minimal (spring) values of the hydrogen partial pressure index rH_min rather than on the average value of this index rHav. The hematite content decreases in the gleyed and humus horizons (despite the absence of the morphological features of gley in the latter due to the concealing effect of humus). The gley horizons are heterogeneous with respect to the state of iron. Upon the maximum wetting in the gley horizons of the mucky-humus gley soil, hematite is being reduced to Fe(II), which is proved by the low values of rH_min (<19). In a less humified dark humus gley soil, the values of rH_min exceed 19, which points to the inherited gley features in this soil. In the mucky-humus gley soil, an inverse dependence between the magnetic susceptibility χ and E_Hmin is observed upon E_Hmin <320 mV. In this case, the degree of reduction of the highly magnetic iron oxides rises from 0.3 to 1.0 due to a decreasing portion of maghemite γFe₂O₃ and an increasing portion of magnetite Fe₃O₄.