Fate of phosphate and nitrate in waters of an intensive agricultural area in the dry zone of Sri Lanka

The chemistry of surface waters and groundwater draining agricultural catchments in the north-central and northwestern areas of Sri Lanka is described. Hydrochemical data from 296 water samples are used to evaluate water quality and to identify the processes that control nitrate and phosphate concentrations in the water. The results indicate that nutrient concentrations in the groundwaters are greater than those in the surface waters. Increased nutrient levels were observed in groundwater in a selected area in the fortnight following fertilizer application. Detailed geochemical investigations of selected groundwater samples reveal a gradual rise of nitrate–N and other solutes along the horizontal flow direction. Compared to the application rates of fertilizer in the area, the average nutrient concentrations in all waters are relatively low (1.5 mg/l nitrate and 0.5 mg/l phosphate) and stable. The results suggest that prevailing reducing conditions, iron-rich overburden soil cover and manmade canal networks control nutrient accumulation in the groundwater.