| 超高效液相色谱-串联质谱测定蔬菜、水果和土壤中多菌灵的残留研究 |
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| 引用本文： | 刘慧群,刘新刚,董丰收,王相晶,郑永权. 超高效液相色谱-串联质谱测定蔬菜、水果和土壤中多菌灵的残留研究[J]. 农药科学与管理, 2009, 30(4): 20-24 |
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| 作者姓名： | 刘慧群 刘新刚 董丰收 王相晶 郑永权 |
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| 作者单位： | 东北农业大学,哈尔滨,150030;中国农业科学院植物保护研究所,农业部农药化学与应用技术重点开放实验室,北京,100193 |
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| 摘 要： | 应用超高效液相色谱-串联质谱仪建立了多茵灵在黄瓜、番茄、葡萄、苹果和土壤中的残留检测方法。前处理方法采用乙酸乙酯提取,多反应离子监测技术确定多茵灵的2对离子m／z191．2／132和m／z191．2／160为定性离子．m／z191．2／160为定量离子。结果表明,本方法的最低检出浓度为O．001mg／L,线性范围为0．001-1mg／L,添加回收率范围为87．86％～112．71％,变异系数为1．54％-6．22％。
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| 关 键 词： | 多菌灵 超高效液相色谱-串联质谱联用 残留 |
Determination of Carbendazim Residue in Soil,Fruit and Vegetable by UPLC-MS/MS |
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| Liu Huiqun,Wang Xiangjing Zheng Yongquan,Liu Xingang,Dong Fengshou. Determination of Carbendazim Residue in Soil,Fruit and Vegetable by UPLC-MS/MS[J]. Pesticide Science and Administration, 2009, 30(4): 20-24 |
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| Authors: | Liu Huiqun Wang Xiangjing Zheng Yongquan Liu Xingang Dong Fengshou |
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| Affiliation: | Northeast Agriculture University;Harbin 150030;China;Chinese Academy of Agricultural Science;Key Open Laboratory of Pesticide Chemistry and Application Technology;Ministry of Agriculture;Beijing 100193;China |
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| Abstract: | An uhral performance liquid chromatography-mass spectrometry/mass spectrometry （UPLC-MS/MS） method was developed for the determination of carbendazim residues in soil,cucumber, tomato, grape and apple. The samples were extracted with ethyl acetate and determined by UPLC-MS/MS. The precursor ion/product ion transitions were m/z 191.2/130 and m/z 191.2/160 at the mode of multi-reaction monitor and m/z 191.2/160 was used for quantification. The good linearity was obtained in the range of 0.001mg/L-1.00mg/L. The limit of detection was 0.001mg/kg. The recoveries were 87.86% -112.71% and the coefficient of variation were 1.54%-6.22%. |
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| Keywords: | carbendazim UPLC-MS / MS residue analysis |
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