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Influence of sample pretreatment on the extractability of polycyclic aromatic hydrocarbons (PAH) from forest floor horizons
Authors:Georg Guggenberger  Martin Pichler  Wolfgang Zech
Abstract:Extraction of PAH from Oh-horizon material after dispersion of air-dried samples in water resulted in a 80% higher yield of 20 PAH species compared to extraction of air-dried, freeze-dried or ground samples. Concurrently, the free surface area (BET method) of the organic matter increased. It was assumed that dispersion resulted in a disaggregation and/or stretching of organic aggregates, which makes interior aggregate regions available to the extractant that were pre-viously not accessible for the extractant due to diffusion barriers.
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