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Pasting,thermal and rheological properties of octenylsuccinylate modified starches from diverse small granule starches differing in amylose content
Institution:1. Instituto Politécnico Nacional, CEPROBI, Yautepec, Morelos, Mexico;2. Department of Food Science, Purdue University, West Lafayette, IN 47907, USA;3. Whistler Center for Carbohydrate Research, Purdue University, West Lafayette, IN 47907, USA;1. Departamento de Ingeniería Bioquímica, Escuela Nacional de Ciencias Biológicas, Instituto Politécnico Nacional, Prolongación del Carpio y Plan de Ayala s/n, Col. Santo Tomás, 11340 Ciudad de México, Mexico;2. Unidad de Investigación y Desarrollo de Alimentos, Instituto Tecnológico de Veracruz, M.A. de Quevedo 2779, Col. Formando Hogar, Veracruz, Ver. 91897, Mexico;1. Department of Food Science and Technology, Chaudhary Devi Lal University, Sirsa, India;2. Department of Food Science and Technology, Guru Nanak Dev University, Amritsar 143005, Punjab, India;1. Southern Regional Station, ICAR-National Dairy Research Institute, Bengaluru, India;2. ICAR-National Dairy Research Institute, Karnal, India;3. ICAR-Central Institute of Post-Harvest Engineering & Technology, Ludhiana, India;1. College of Food Science, Fujian Agriculture and Forestry University, Fuzhou 350002, PR China;2. Fujian Provincial Key Laboratory of Quality Science and Processing Technology in Special Starch, Fuzhou 350002, PR China
Abstract:Waxy maize (a standard starch of normal granule size) and five small granule starches from different botanical sources (rice, wheat B type, oat, quinoa and amaranth) were subjected to 2-octenyl-1-succinic anhydride (OSA) modification. Changes of pasting, gel texture, thermal and rheological properties were investigated. Different small granule starches showed quite different property changes after OSA modification. Pasting viscosity was generally increased in OSA starches, among which OSA oat starch had notably high peak and breakdown viscosity but low setback viscosity. Gel hardness of rice, wheat B type, oat and quinoa starches was reduced by OSA treatment, whereas that of waxy maize and amaranth starches was increased. Amylose content was considered to be the major factor influencing pasting, gel and thermal property of OSA starches. Esterification increased pseudoplastic flow behavior of all starches, while OSA oat starch uniquely had reduced flow consistency coefficient. The dynamic rheological properties were also changed differentially among OSA starches. Viscoelastic properties of rice, wheat B type, oat and quinoa starches were increased after OSA treatment, whereas those of waxy maize and amaranth starches were decreased. This study showed that diverse functionalities from OSA small granule starches may fulfil different demands in product development.
Keywords:Small granule starch  OSA modification  Pasting property  Rheological property
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