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Preparation of phenol formaldehyde resin from phenolated wood
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Preparation of phenol formaldehyde resin from phenolated wood
Authors:Gai-yun Li  Te-fu Qin  Shin-ichiro Tohmura  Atsushi Ikeda
Institution:(1) Research Institute of Wood Industry, Chinese Academy of Forestry, 100091 Beijing, P. R. China;(2) Department of Wood Composite Materials, Forestry and Forest Products Research Institute, 305-8687 Tsukuba, JAPAN;(3) Expert of Research Project on Man-Made Forestry Timber Dispatched by Japan International Cooperation Agency, Japan
Abstract:The technique for preparing phenol formaldehyde resin from phenolated wood (PWF) and its characters were studied and analyzed. Poplar (Populus spp) wood meal was liquefied by phenol in the presence of sulfuric acid as a catalyst. After the liquefied products were cooled, alkaline catalyst and formaldehyde were added. The mixture was kept at (60±2)°C for 1h and then was heated to (85±2)°C for 1h. The influence of molar ratio of formaldehyde to phenol (F/P) was investigated. The results showed when the molar ratio of formaldehyde to phenol was over 1.8, the PWF adhesives had high bond quality, bond durability and extremely low aldehydes emissions. Foundation item: The research was supported by Sino-Japanese Technical Cooperation Project (2-1-b) and the key technologies R & D Program for the 10th Five-Year Plan (325-11). Biography: LI Gai-yun (1974-), female, Assistant professor in Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, P. R. China Responsible editor: Zhu Hong
Keywords:Phenolated wood  Phenol formaldehyde (PF) adhesives  Bond quality  Bond durability  Aldehyde emission
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