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Ag沉积TiO_2光催化降解腐植酸研究
引用本文:陈德强,张代明,韦昭平.Ag沉积TiO_2光催化降解腐植酸研究[J].安徽农业科学,2010,38(17):9379-9381.
作者姓名:陈德强  张代明  韦昭平
作者单位:河海大学环境科学与工程学院,江苏南京,210098
基金项目:河海大学自然科学基金,中央高校基本科研业务费专项资金 
摘    要:目的]为饮用水中腐植酸的去除提供新思路。方法]采用光还原法对纳米TiO2进行Ag沉积,研究改性TiO2/UV体系对腐殖酸的光降解效率,并探讨TiO2用量及腐植酸初始浓度对光降解效率的影响。结果]适量Ag沉积可提高TiO2的光催化活性,Ag沉积量为0.8wt%时TiO2的光催化活性最大;焙烧温度为400℃时TiO2的光催化活性最强;增加TiO2用量可提高腐植酸的光降解反应速率;在试验浓度范围内,随着腐植酸初始浓度的增大,其光降解效率降低,光降解过程符合Langmuir-Hinshelwood动力学模型,反应速率常数k和Langmuir吸附常数K分别为0.173 5 mg/(L.min)和0.421 5 L/mg。结论]适量的Ag沉积可提高TiO2光催化降解腐植酸的活性。

关 键 词:TiO2  Ag沉积  腐植酸  光降解

Study on Photocatalytic Degradation of Humic Acid by Ag Deposited TiO2
CHEN De-qiang et al.Study on Photocatalytic Degradation of Humic Acid by Ag Deposited TiO2[J].Journal of Anhui Agricultural Sciences,2010,38(17):9379-9381.
Authors:CHEN De-qiang
Institution:CHEN De-qiang et al(College of Environmental Science and Engineering,Hehai University,Nanjing,Jiangsu 210098)
Abstract:Objective] The study was to provide a new method for removing humic acids in drinking water.Method] Nanometer TiO2 was deposited by Ag with photo reduction method.The photodegradation efficiency of modification TiO2/UV system on humic acid was studied and the effects of TiO2 dosage and initial concn.of humic acid on photodegradation efficiencies were explored.Results] Ag deposition with appropriate amount could improve the photocatalytic activity of TiO2.The photocatalytic activity of TiO2 was the maximu...
Keywords:TiO2
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