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砂地柏叶中鬼臼毒素的分离与鉴定
引用本文:王继栋,田 暄,张 兴.砂地柏叶中鬼臼毒素的分离与鉴定[J].西北农林科技大学学报(社会科学版),2000,28(6):25-29.
作者姓名:王继栋  田 暄  张 兴
作者单位:1. 西北农林科技大学,无公害农药研究服务中心,陕西,杨陵,西农校区,712100
2. 兰州大学,应用有机化学国家重点实验室,甘肃,兰州,730000
基金项目:国家自然科学基金资助项目! ( 3997950 6)
摘    要:在生物活性跟踪测试指导下 ,从砂地柏叶的乙醇提取物中通过硅胶柱层析 ,分离得到一种对菜青虫有高拒食活性的成分 ,经紫外光谱 (UV)、红外光谱 (IR)、质谱 (MS)、氢核磁共振谱 (1H- NMR)分析 ,鉴定其为鬼臼毒素。其对菜青虫在高质量浓度下呈拒食作用 ,低质量浓度下则具胃毒毒杀作用。

关 键 词:砂地柏  鬼臼毒素  植物性杀虫剂

The isolation and identification of podophyllotoxin from Sabina vulgaris Ant.
WANG Ji-dong,TIAN Xuan,ZHANG Xing.The isolation and identification of podophyllotoxin from Sabina vulgaris Ant.[J].Journal of Northwest Sci-Tech Univ of Agr and,2000,28(6):25-29.
Authors:WANG Ji-dong  TIAN Xuan  ZHANG Xing
Institution:1 (1 Research and Development Center of Biorational Pesticides,Northwest Science and Technology University of Agriculture and Forestry,Yangling,Shaanxi 712100,China; 2 National Laboratory of Applied Organic Chemistry,
Abstract:According to the guidance of bioactivity assaying and using silica column chromatography,a compound having high antifeeding activity to the tested insect Pieris rapae L.is isolated from the ethanol extract of the leaves of Sabina vulgaris Ant..Its molecular structure is identified to be podophyllotoxin,a known compound,by UV,IR,MS and 1H-NMR.It is also found that the podophyllotoxin has antifeeding activity in higher concentrations and has stomach poisionous activity in lower concentrations to the 5 instar larva of Pieris rapae L..
Keywords:Sabina vulgaris Ant    podophyllotoxin  botanical insecticide
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