| Fe/Zn双金属对地下水中PCBs的还原脱氯研究 |
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| 引用本文： | 刘园园,张兰英,邱明英,任何军,杜军. Fe/Zn双金属对地下水中PCBs的还原脱氯研究[J]. 安徽农业科学, 2012, 40(15): 8673-8676 |
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| 作者姓名： | 刘园园 张兰英 邱明英 任何军 杜军 |
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| 作者单位： | 吉林大学地下水资源与环境教育部重点实验室,吉林长春,130026 |
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| 基金项目： | 国家自然科学基金，吉林省科技厅项目 |
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| 摘 要： | [目的]研究Fe/Zn双金属对地下水中PCBs的还原脱氯效果。[方法]以Fe、Zn构建二元金属还原体系,以PCBs降解率为考察指标,研究了添加羟丙基-β-环糊精(HP-β-CD)时,Fe/Zn双金属对PCBs的降解效果,同时考察了负载率、金属投加量对PCBs脱氯的影响。[结果]合成的HP-β-CD对PCBs有很好的增溶作用,PCBs表观溶解度随HP-β-CD浓度增加而线性增加,形成1∶1的包结物;10℃下,当混合金属投加量为10 g,Zn质量分数为7%时,321μg/L PCBs降解7 d后的去除率为47.6%。[结论]该研究为PCBs污染的地下水原位修复提供了理论指导。
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| 关 键 词： | 羟丙基-β-环糊精 脱氯 多氯联苯 Fe/Zn双金属 |
Study on Reductive Dechlorination of PCBs in Groundwater by Fe/Zn Bimetal |
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| Affiliation: | LIU Yuan-yuan et al(Key Laboratory of Groundwater Resources and Environment,Ministry of Education,Jilin University,Changchun,Jilin 130026) |
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| Abstract: | [Objective] The research aimed to study reductive dechlorination effect of PCBs in groundwater by Fe/Zn bimetal.[Method] Fe/Zn bimetal as reduction system,PCBs degradation ratio as inspected index,degradation effect of PCBs by Fe/Zn bimetallic system when adding self-made hydroxypropyl-β-cyclodextrin(HP-β-CD) was studied.Meanwhile,we investigated the influences of loading ratio and Fe-Zn dosage on the dechlorination of PCBs.[Result] PCBs was significantly solubilized by the synthesized HP-β-CD.With increase of the HP-β-CD concentration,the apparent solubility of PCBs increased linearly,forming 1∶ 1 inclusion complex.When Fe-Zn dosage was 10 g,and mass fraction of Zn was 7%,the dechlorination efficiency of PCBs with 321 μg/L was 47.6% after degrading for 7 d at 10 ℃.[Conclusion] The research provided theoretical guiding for in situ remediation of the groundwater contaminated by PCBs. |
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| Keywords: | HP-β-CD Dechlorination PCBs Fe/Zn bimetal |
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