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从泥炭中提取腐殖酸的工艺及其结构研究
引用本文:牛育华,李仲谨,余丽丽,郝明德,朱雷.从泥炭中提取腐殖酸的工艺及其结构研究[J].安徽农业科学,2009,37(35).
作者姓名:牛育华  李仲谨  余丽丽  郝明德  朱雷
作者单位:陕西科技大学化学与化工学院,陕西西安,710021;中国科学院水利部水土保持研究所,陕西杨陵,712100
基金项目:国家科技支撑计划,陕西省科技攻关-农业攻关项目,咸阳市-兴咸计划项目 
摘    要:探讨了不同预处理方法对从泥炭中提取腐殖酸效果的影响,同时也考察了碱提取液及其酸析液对提取结果的影响。结果表明,采用硝酸对试验样品进行预处理提取率最佳,通空气氧化和超声处理对提取率有益,但是提升效果不明显。碱溶分析表明,若投加0.1mol/L的Na4P2O4与碱液混合,腐殖酸的提取率会得到显著提升,且随着碱浓度的增大而增加,碱溶效果表现为:Na4P2O4+KOH>Na4P2O4+NaOH>KOH>NaOH>Na2CO3;酸析时,当CH+<2 mol/L时,HCl与H2SO4效果相当,且随着酸度的增加提取率增大,当C+>2 mol/L时,HCl优于稀HSO,这是由于硫酸将腐殖酸部分氧化,造成提取率降低。

关 键 词:泥炭  提取  腐殖酸  预处理  抽提液

Study on the Extraction Technology and Structure of Humic Acid from Peat
NIU Yu-hua et al.Study on the Extraction Technology and Structure of Humic Acid from Peat[J].Journal of Anhui Agricultural Sciences,2009,37(35).
Authors:NIU Yu-hua
Institution:NIU Yu-hua et al (College of Chemistry , Chemical Engineering,Shaanxi University of Science & Technology,Xi\'an,Shaanxi 710021)
Abstract:The influences of different pretreatment methods on the extraction effect of humic acid from peat were discussed.And the influences of alkali extract and its acid eduction on the extraction results were investigated.The results indicated that the extraction rate of pretreating test samples with nitric acid was the best.The ventilation oxidation and ultrasonic pretreatments were beneficial to the extraction rate,but the increase effect was not obvious.The alkali dissolution analysis showed that the extractio...
Keywords:Peat  Extraction  Humic acid  Pretreatment  Extract
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