Distribution of elements in some Fe-Mn nodules and an iron-pan in some gley soils of New Zealand

Three soil nodules and an iron-pan have been analysed for the elements Al, Si, Ti, V, Mn, Fe, Co, Ni, Cu and Zn using an electron microprobe. From the surface analysis it appears that the nodules consist of two major concentration zones of enrichment, viz. Mn-rich, Fe-rich zones and a third zone low in Mn and Fe. The elements Co, Ni, Cu and Zn are enriched in the first zone, whereas vanadium is enriched in the second zone. Four concentration zones are distinguishable in the iron-pan, Ti-rich, Fe-rich, Ti and Fe-rich and a zone low in Ti and Fe. The metals Mn, Co, Ni, Cu and Zn are mainly enriched in the Ti/Fe-rich zone. The associations of the trace elements with the major components of the nodules and iron pan are discussed in terms of physico-chemical factors.