Sensitivity analysis and field testing of the RISK-N model in the Central Valley of Chile

We present the results from a sensitivity analysis and a preliminary short-term, site-scale performance assessment of the analytical soil and groundwater nitrate transport RISK-N. The study was carried out in the Central Valley of Chile, on a 2.6 ha corn (Zea mays L.) field underlain by a shallow unconfined aquifer during the cropping season 2000–2001. Nitrogen levels in soils as well as NO₃⁻–N irrigation water and groundwater concentrations were monitored through the crop-growing period, the latter by a network of 16 monitoring wells. A sensitivity analysis shows that both the nitrate flux from the vadose zone and NO₃⁻–N groundwater concentration are mainly influenced by the initial soil nitrogen levels, water input, and soil porosity. Also, simulated groundwater NO₃⁻–N levels are sensitive to changes on the saturated zone denitrification constant. An additional analysis further reveals the significance of the latter parameter, in conjunction with the amount of applied nitrogen fertilizer. We obtained a good agreement between observed average and simulated values. While the model performs well when spatially averaged values are used (root mean square error, RMSE = 1.4 mg l⁻¹ of NO₃⁻–N), the prediction error increases (RMSE = 1.9 mg l⁻¹ of NO₃⁻–N) when the concentration in each well is considered. This fact could be explained by the time and space scale of the experiment and the characteristics of the RISK-N model. The model is easy to use and seems appropriate for mid- and long-term studies of nitrogen contamination in groundwater for agricultural conditions in the Central Valley of Chile and under limited field data availability conditions. However, it needs to be tested for longer periods and under different climatic conditions, soil types, and aquifer characteristics, before its range of applicability can be fully established and recognized.