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| 2,6-二甲基-7-辛烯-2-烷基(或羟烷基)醚的合成研究 | |
| 引用本文： | 江焕峰,严兆华,萧树德. 2,6-二甲基-7-辛烯-2-烷基(或羟烷基)醚的合成研究[J]. 林产化学与工业, 1996, 16(4): 7-12 |
| 作者姓名： | 江焕峰 严兆华 萧树德 |
| 作者单位： | 中国科学院广州化学研究所 广州 510650(江焕峰，严兆华)，中国科学院广州化学研究所 广州 510650(萧树德) |
| 摘 要： | 以氢型丝光沸石为催化剂，二氢月桂烯与单醇或二醇加成反应生成2，6-二甲基-7-辛烯-2-烷基或羟烷基醚。实验结果发现，各种醇与烯生成醚化合物的趋势如下：直链伯醇易于支链伯醇；伯醇易于仲醇；低碳直链伯醇易于高碳直链伯醇，同时还发现，1，3-丁二醇、1，6-己二醇与烯的反应，只生成单醚。文中还考察了反应温度和时间对反应的影响。 |
| 关 键 词： | 二氢月桂烯 氢型丝光沸石 醚化 2，6-二甲基-7-烷基（或羟基）醚 |
SYNTHESIS OF 2, 6-DIMETHYL-7-OCTENYL 2-ALKYL OR 2-HYDROXYALKYL ETHERS |
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| Jiang Huanfeng,Yan Zhaohua,Xiao Shude. SYNTHESIS OF 2, 6-DIMETHYL-7-OCTENYL 2-ALKYL OR 2-HYDROXYALKYL ETHERS[J]. Chemistry & Industry of Forest Products, 1996, 16(4): 7-12 | |
| Authors: | Jiang Huanfeng Yan Zhaohua Xiao Shude |
| Abstract: | 2,6-Dimethyl-7-octenyl 2-alkyl or 2-hydroxyalkyl ethers were synthesized via addition reaction of dihydromyrcene with alcohols catalyzed by H-Mordenite. Experimental results show that the tendency of reactions between dihydromyrcene and each alcohol is as follows:lower straight chain primary alcohols are faster than higher ones,straight chain primary alcohols faster than branched-chain primary ones,primary alcohols faster than secondary ones. The resultants of 1, 3-butanediol and 1, 6-hexanediol with dihydromyrcene are only monoethers. In this paper,the effects of temperature and reaction time on the reaction are also investigated in detail. |
| Keywords: | Dihydromyrcene H-Mordenite Etherification 2 6-dimethyl-7-octenyl-2-alkyl (or hydroxyalkyl) ethers |
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