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掺杂稳定固定剂的沉积物样品吸附Cu、Zn的特征
引用本文:李西西,王晓丽,雷剑英,赵玉凤,刘瑾,梁文强,赵郭靓. 掺杂稳定固定剂的沉积物样品吸附Cu、Zn的特征[J]. 安徽农业科学, 2011, 39(18): 11028-11031
作者姓名:李西西  王晓丽  雷剑英  赵玉凤  刘瑾  梁文强  赵郭靓
作者单位:1. 中南民族大学化学与材料科学学院,湖北,武汉,430074
2. 吉林大学植物科学学院,吉林,长春,130062
基金项目:国家重点基础研究发展计划973项目(2004CB418501); 2010年中南民族大学大学生科研创新基金项目
摘    要:利用掺杂稳定固定剂的沉积物样品进行cu、zn的热力学吸附,考察铁氧化物类、有机质类、黏土矿物类及磷酸盐类等11种物质的掺杂对沉积物样品吸附cu、zn热力学特征的影响。结果表明,所选用的掺杂材料中羟基磷灰石和磷酸氢二铵可同时提高沉积物吸附cu、zn的能力,其中Cu的最大吸附量提高70%~130%,Zn的最大吸附量提高150%以上,说明羟基磷灰石和磷酸氢二铵可望用作污染沉积物中重金属Cu、Zn的稳定固定剂。

关 键 词:铁氧化物  有机物  羟基磷灰石  磷酸氢二铵  重金属吸附

Characteristics of Cu and Zn Adsorption onto Surficial Sediments after Spiked with Stabilitating and Immobilizing Materials
LI Xi-xi et al. Characteristics of Cu and Zn Adsorption onto Surficial Sediments after Spiked with Stabilitating and Immobilizing Materials[J]. Journal of Anhui Agricultural Sciences, 2011, 39(18): 11028-11031
Authors:LI Xi-xi et al
Affiliation:LI Xi-xi et al(College of Chemistry and Materials,South-central University for Nationalities,Wuhan,Hubei 430074)
Abstract:Thermodynamics adsorption of Cu and Zn on surfacail sediments was investigated after spiked with 11 kinds of stabilitating and immobilizing materials,including Fe oxides,organic materials,clay minerals,and phosphate minerals.The results showed that both Cu and Zn adsorption on surficial sediments could be improved with the addition of hydroxyapatite and diammonium hydrogen phosphate,with increase in the maximum adsorption of Cu and Zn by 70%-130% and above 150%,respectively,indicating that hydroxyapatite an...
Keywords:Fe oxide  Organic material  Hydroxyapatite  Diammonium hydrogen phosphate  Heavy metal adsorption  
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