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Stereochemistry of matairesinol formation by <Emphasis Type="Italic">Daphne</Emphasis> secoisolariciresinol dehydrogenase |
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| Authors: | Tomoya?Okunishi Norikazu?Sakakibara Shiro?Suzuki |
| Institution: | (1) Wood Research Institute, Kyoto University, Uji, Kyoto, 611-0011, Japan;(2) Present address: National Food Research Institute, Ibaraki, 305-8642, Japan |
| Abstract: | Secoisolariciresinol dehydrogenase activity was detected for the first time from Daphne odora and Daphne genkwa (Thymelaeaceae), which are known to produce optically pure (+)-matairesinol. In sharp contrast, (–)-matairesinol was formed selectively over the (+)-antipode by the secoisolariciresinol dehydrogenase preparation from both D. odora callus and D. genkwa shoots. |
| Keywords: | Matairesinols Secoisolariciresinol dehydrogenase Daphne odora Daphne genkwa Stereochemistry |
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