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pH对土壤重金属吸附动力学的影响
作者姓名:LIN Yu-Suo  XUE Jia-Hua
作者单位:Nanjing Institute of Environmental Scienpe, Notional Environmental Protection, Agency, Nanjing 210042 (China);Nanjing Agricultural University, Nanjing 210014 (China)
摘    要:The pH effect on the sorption kinetics of heavy metals in soils was studied using a constant flow leaching method. The soil samples were red soil collected from Yingtan, Jiangxi, and yellow-brown soil from Nanjing, Jiangsu. The heavy metals tested were zinc and cadmium. Assuming that the experimental data fitted to the following kinetic rate equation: 1/c·dx/dt = kx-kx, the rate constant k of sorption could be determined from the slope of the straight line by plotting of 1/c·dx/dt vs. x. The results showed that the pH effect on the rate constants of heavy mental sorption in soils was very significant. The values of k decreased with increasing pH. The sorptions were more sensitive to pH in red soil than in yellow-brown soil.

关 键 词:heavy  metals    kinetics    soils    sorption

pH effect on kinetics of heavy metal sorption in soils
LIN Yu-Suo,XUE Jia-Hua.pH effect on kinetics of heavy metal sorption in soils[J].Pedosphere,1996,6(3):225-231.
Authors:LIN Yu-Suo and XUE Jia-Hua
Institution:Nanjing Institute of Environmental Scienpe, Notional Environmental Protection, Agency, Nanjing 210042 (China);Nanjing Agricultural University, Nanjing 210014 (China)
Abstract:The pH effect on the sorption kinetics of heavy metals in soils was studied using a constant flow leaching method. The soil samples were red soil collected from Yingtan, Jiangxi, and yellow-brown soil from Nanjing, Jiangsu. The heavy metals tested were zinc and cadmium. Assuming that the experimental data fitted to the following kinetic rate equation: 1/c·dx/dt = kx-kx, the rate constant k of sorption could be determined from the slope of the straight line by plotting of 1/c·dx/dt vs. x. The results showed that the pH effect on the rate constants of heavy mental sorption in soils was very significant. The values of k decreased with increasing pH. The sorptions were more sensitive to pH in red soil than in yellow-brown soil.
Keywords:heavy metals  kinetics  soils  sorption
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