Sign Change of Poisson's Ratio for Carbon Nanotube Sheets

Most materials shrink laterally like a rubber band when stretched, so their Poisson's ratios are positive. Likewise, most materials contract in all directions when hydrostatically compressed and decrease density when stretched, so they have positive linear compressibilities. We found that the in-plane Poisson's ratio of carbon nanotube sheets (buckypaper) can be tuned from positive to negative by mixing single-walled and multiwalled nanotubes. Density-normalized sheet toughness, strength, and modulus were substantially increased by this mixing. A simple model predicts the sign and magnitude of Poisson's ratio for buckypaper from the relative ease of nanofiber bending and stretch, and explains why the Poisson's ratios of ordinary writing paper are positive and much larger. Theory also explains why the negative in-plane Poisson's ratio is associated with a large positive Poisson's ratio for the sheet thickness, and predicts that hydrostatic compression can produce biaxial sheet expansion. This tunability of Poisson's ratio can be exploited in the design of sheet-derived composites, artificial muscles, gaskets, and chemical and mechanical sensors.     

Membrane proteins of the endoplasmic reticulum induce high-curvature tubules

The tubular structure of the endoplasmic reticulum (ER) appears to be generated by integral membrane proteins, the reticulons and a protein family consisting of DP1 in mammals and Yop1p in yeast. Here, individual members of these families were found to be sufficient to generate membrane tubules. When we purified yeast Yop1p and incorporated it into proteoliposomes, narrow tubules (approximately 15 to 17 nanometers in diameter) were generated. Tubule formation occurred with different lipids; required essentially only the central portion of the protein, including its two long hydrophobic segments; and was prevented by mutations that affected tubule formation in vivo. Tubules were also formed by reconstituted purified yeast Rtn1p. Tubules made in vitro were narrower than normal ER tubules, due to a higher concentration of tubule-inducing proteins. The shape and oligomerization of the "morphogenic" proteins could explain the formation of the tubular ER.     

Biscrolling nanotube sheets and functional guests into yarns

Multifunctional applications of textiles have been limited by the inability to spin important materials into yarns. Generically applicable methods are demonstrated for producing weavable yarns comprising up to 95 weight percent of otherwise unspinnable particulate or nanofiber powders that remain highly functional. Scrolled 50-nanometer-thick carbon nanotube sheets confine these powders in the galleries of irregular scroll sacks whose observed complex structures are related to twist-dependent extension of Archimedean spirals, Fermat spirals, or spiral pairs into scrolls. The strength and electronic connectivity of a small weight fraction of scrolled carbon nanotube sheet enables yarn weaving, sewing, knotting, braiding, and charge collection. This technology is used to make yarns of superconductors, lithium-ion battery materials, graphene ribbons, catalytic nanofibers for fuel cells, and titanium dioxide for photocatalysis.     

Fuel-powered artificial muscles

Artificial muscles and electric motors found in autonomous robots and prosthetic limbs are typically battery-powered, which severely restricts the duration of their performance and can necessitate long inactivity during battery recharge. To help solve these problems, we demonstrated two types of artificial muscles that convert the chemical energy of high-energy-density fuels to mechanical energy. The first type stores electrical charge and uses changes in stored charge for mechanical actuation. In contrast with electrically powered electrochemical muscles, only half of the actuator cycle is electrochemical. The second type of fuel-powered muscle provides a demonstrated actuator stroke and power density comparable to those of natural skeletal muscle and generated stresses that are over a hundred times higher.     

Biodeterioration of historic timber structures: A comparative analysis

Abstract

Service life of timber structures in the north of Europe is decreased mainly by biological agents. Increasing risk of biological infestation due to global warming is widely discussed nowadays. Historic timber structures which have been monitored for decades provide us with valuable information on this subject. An investigation of the structures in the Kizhi museum, located in the northwest of Russia was carried out in the 1970s and in 2011–2012. Identification of wood-decay fungi that destroy constructive elements of seventeenth- and nineteenth-century monuments showed that the most frequent damages are caused by brown rot fungi. At the same time, imperfect fungi and ascomycetes which cause soft rot began to play a significant role in damaging historic timber structures. Borers (Hadrobregmus pertinax L. and H. confusus Kraaz) play the leading part in reducing the service life of seventeenth- and nineteenth-century heritage objects. During a forest inventory, some wood-borers not registered previously as timber structure pests in the Kizhi archipelago region (Republic of Karelia, Russia) were found. Twenty-seven species of foliose and fruticose lichens and ten species of crustose lichens were found on the monuments' structural elements.     

Torsional carbon nanotube artificial muscles

Rotary motors of conventional design can be rather complex and are therefore difficult to miniaturize; previous carbon nanotube artificial muscles provide contraction and bending, but not rotation. We show that an electrolyte-filled twist-spun carbon nanotube yarn, much thinner than a human hair, functions as a torsional artificial muscle in a simple three-electrode electrochemical system, providing a reversible 15,000° rotation and 590 revolutions per minute. A hydrostatic actuation mechanism, as seen in muscular hydrostats in nature, explains the simultaneous occurrence of lengthwise contraction and torsional rotation during the yarn volume increase caused by electrochemical double-layer charge injection. The use of a torsional yarn muscle as a mixer for a fluidic chip is demonstrated.     

Input of atmospheric precipitation nitrogen to the Baltic sea from its catchment

Input of atmospheric precipitation nitrogen (N) to the Baltic sea aquatorium from its drainage basin has been estimated. The deposition of nitrogen compounds on the catchment has been shown to be 5 times higher than their enter directly into the sea. An assessment of this input has been carried out by two methods (direct and indirect) and the results of calculations showed relatively high similarity. It has been demonstrated that the main source of data uncertainty is related to the values of nitrogen runoff and retention in different landuse types. Depending on the subregions the values of atmospheric nitrogen deposition runoff to the Baltic sea changed from 5 up to 16%, the minimum values were obtained for northern subregions and the maximum — for south-western ones. For the whole basin of the Baltic Sea during the 1987–1991 period these runoff values were 8–10% from the total amount of atmospheric nitrogen deposition input (1341–1401 kt) at catchment. The mean value was 122 kt in 1990 yr or 14% of total nitrogen input into the Baltic Sea from all sources. The given values must undoubtedly be taken into account in various scenarios of Transboundary Air Abatement Strategy.     

Uncertainty analysis of critical loads for terrestrial ecosystems in Russia

The goal of this study is to give a comprehensive and quantitative estimation of the uncertainty of computed in different scale nitrogen (N) and sulphur (S) critical loads (CL) values for terrestrial ecosystems of the Northern Asia, European part and the North-Western regions of Russia. The CL values are used to set goals for future deposition rates of acidifying compounds so that the environment is protected. In this research CL values for terrestrial ecosystems are determined using the expert-modelling geoinformation system (EM GIS) approach. UNCSAM software package is used as the tool for uncertainty analysis. The analysis presented here focuses on the estimation and effect of the input source uncertainties and sensitivities on the CL values in various regions under study. In spite of the region, nitrogen uptake by vegetation, nitrogen leaching from terrestrial ecosystems and the difference between deposition and uptake by plants of base cations (BC) are the most influential factors for all terrestrial ecosystems of Russia.