Heavy Metal Pollution in Air-Water-Soil-Plant System of Zhuzhou City,Hunan Province,China

The sources, distribution and mobility of heavy metals in Zhuzhou City, Hunan Province, China were systematically studied based on environmental monitoring data and random sampling from fields and markets. The significant positive correlations between some pairs of heavy metals (total Cd–Hg, total Cu–Pb) within the Zhuzhou section of the Xiang River may indicate that they are coming from the same pollution sources with similar pollution channels and removal patterns in the water bodies. Heavy metals from wastewater partly settled in the sediment after entering the Xiang River, which caused an inconsistent change in heavy metal concentrations over time in the middle and lower parts of the Xiang River. There was no significant difference in total Pb and Zn in topsoil between years in the period 1990–1997, which showed the balance between input and output. Heavy metals accumulated mainly in the topsoil with little downward movement. Heavy metals in the vegetables and rice were higher than the edible standard and background value to some degree with minor exceptions. The maximum heavy metal level observed divided by the acceptable level was in the order of Cd > Pb > Cu > Zn. Significant positive correlations were only found between cabbage uptake and total soil content for Hg, Pb and Cd, with no significant correlationfor the other elements. The plant uptake of a heavy metal was somewhat influenced by the co-existence of other elements.     

Lysimeter study of effects of acid deposition on properties and leaching of gleyed dystric brunisolic soil in Norway

The effects of artificial rain of various acidities were studied in a lysimeter experiment. Lysimeters, 29 cm in diameter, and 40 cm deep contained a Gleyed Dystric Brunisol. Natural structure, stratification and original vegetation were maintained. Artificial rain was produced from groundwater with “high” concentrations of neutral salts and from rainwater with lower concentrations. pH levels of 6, 4, 3 and 2 were established by adding H₂SO₄. Effects of dilution with given amounts of acid were examined by comparing the effects of 50 mm “rain” month^?1 of pH 3 and pH 2 with 500 mm “rain” month^?1 of pH 4 and pH 3, respectively. The study continued for 5 yr. Totals of 1250 or 12500 mm “rain” were applied in addition to a natural input of 2773 mm. Increased input of SO₄ ^2? increased the output of SO₄ ^2? but, as concentration increased, sorption of SO₄ ^2? in the soil also increased. Concentrations of base cations in the leachate increased parallel to the output of SO₄ ^2?. However, significant effects on leaching of base cations and on the content of exchangeable cations in the soil, was only found in the pH 2 treatment with 1250 mm of “rain” and in the pH 4 and pH 3 treatment with 12500 mm of “rain”.     

Liming and wet acid deposition effects on tree growth and nutrition: Experimental results

Results from a factorial acid treatment and liming experiment in a stand of Scots pine planted in 1968 to 1970 are presented. Field plots, 75 m² in size, were supplied with 50 mm of artificial rain 38 times from 1974 to 1981. "Rain" of varying acidities was produced using groundwater mixed with H₂SO₄. Lime was applied at four levels in 1974 in a factorial acid treatment-liming design. Tree growth and foliar nutrient concentrations were measured annually from 1974 to 1988. The soil was sampled periodically from 1975 to 1988 at mainly 3 yr intervals. Tree growth was initially stimulated by increased acid loadings. Negative effects occurred after 5 yr. Positive effects of liming developed after 9 yr. No major signs of recovery from the most acid treatments have yet been found. Treatment effects appeared to be linear, indicating no threshold values for growth reactions. Treatment effects on foliar concentrations were found for a majority of elements analyzed. Increased acid loadings decreased the Mg, Ca and Mn concentrations, while K concentrations increased — especially during later years. Liming improved the nutrient status at increased acid loadings for Mg, Ca and Mn and decreased K concentrations. Soil sampling in 1984 showed major losses of Mg, Ca and Mn by increased acid loadings, while the K content was less affected. A link seems to exist between tree growth and the Mg situation in soil and foliage.     

Liming and wet acid deposition effects on tree growth and nutrition:Experimental results

Results from a factorial acid treatment and liming experiment in a stand of Scots pine planted in 1968 to 1970 are presented. Field plots, 75 m² in size, were supplied with 50 mm of artificial rain 38 times from 1974 to 1981. “Rain” of varying acidities was produced using groundwater mixed with H₂SC₄. Lime was applied at four levels in 1974 in a factorial acid treatment-liming-design. Tree growth and foliar nutrient concentrations were measured annually from 1974 to 1988. The soil was sampled periodically from 1975 to 1988 at mainly 3 yr intervals. Tree growth was initially stimulated by increased acid loadings. Negative effects occurred after 5 yr. Positive effects of liming developed after 9 yr. No major signs of recovery from the most acid treatments have yet been found. Treatment effects appeared to be linear, indicating no threshold values for growth reactions. Treatment effects on foliar concentrations were found for a majority of elements analyzed. Increased acid loadings decreased the Mg, Ca and Mn concentrations, while K concentrations increased — especially during later years. Liming improved the nutrient status at increased acid loadings for Mg, Ca and Mn and decreased K concentrations. Soil sampling in 1984 showed major losses of Mg, Ca and Mn by increased acid loadings, while the K content was less affected. A link seems to exist between tree growth and the Mg situation in soil and foliage.     

Interaction between simulated rain and barren rock surface

During the latter decades extensive fish kills have been observed in the mountainous areas of southernmost Norway. These kills have been attributed to the increased acidity of the river-water. The increased acidity is generally assumed to be caused by acid precipitation. However, the relationship between precipitation and runoff quality is very complex. The present paper is concerned with the relationship between chemical composition of simulated rain and that of runoff from bare granitic rock, partly covered by lichens. When supplying simulated rain with a pH value of approximately 5 the very first runoff had pH values between 4.1 and 4.3. However, the pH in the runoff increased rapidly and leveled out at values between 4.6 and 4.7. When supplying simulated rain with pH approximately 3.5, the pH in the first runoff varied between 3.8 and 3.6. The pH then gradually decreased to the same values as those in the simulated rain. Runoff from ‘rain’ with pH 4.3, obtained the same pH value as that of the ‘rain’. The pH of the runoff was dependent not only on the rain acidity, but also on its content of neutral salts.     

Acidification of soils in five catchments in Norway

Soil plots were established in catchments within the frame of the Norwegian Monitoring Programme for Long-Range Transported Air Pollutants. Four soil plots of about 10 m by 20 m were established within each catchment in areas with relatively homogeneous soil and vegetation. Multiple soil cores were taken at 50 points in a grid from each plot (repeated 4 times) and the samples were pooled by depths. Each soil core was divided by soil horizon, by predefined depths or by a combination of these, usually giving one soil sample for each 2-cm-depth down to about 15 cm. The soil pH measured in water suspension varied for all soils between 3.5 and 4.9. Base saturation measured at pH 7 varied between 2% and 22% with the highest values in the upper, more humus rich layers. All of the monitored catchments include acid soils poor in base cations. After 8 years the plots were resampled using the same procedure as for the first sampling. In most of the plots a decreasing pH trend from the first to the second sampling was measured. However, the base saturation was generally higher in all plots at the second sampling compared with the first. There are no clear effects of the different pollution regimes in the various catchments. It must be emphasized, however, that 8 years is a short period for measuring long-term soil changes.     

Nitrex: The timing of response of coniferous forest ecosystems to experimentally-changed nitrogen deposition

In large regions of Europe and eastern North America atmospheric deposition of inorganic nitrogen (N) compounds has greatly increased the natural external supply to forest ecosystems. This leads to N saturation, in which availability of inorganic N is in excess of biological demand and the ecosystem is unable to retain all incoming N. The large-scale experiments of the NITREX project (NITRogen saturation EXperiments) are designed to provide information regarding the patterns and rates of responses of coniferous forest ecosystems to increases in N deposition and the reversibility and recovery of impacted ecosystems following reductions in N deposition.The timing of ecosystem response generally followed a hypothesized cascade of response. In all sites N outputs have responded markedly but to very different degrees within the first three years of treatment. Within this time significant effects on soil processes and on vegetation have only been detected at two sites. This delayed response is explained by the large capacity of the soil system to buffer the increased N supply by microbial immobilization and adsorption. We believe that this concept provides a framework for the evaluation and prediction of the ecosystem response to environmental change.     

Mobility of heavy metals in pine forest soils as influenced by experimental acidification

The mobility of Pb, Zn, Cd and Cu was examined at two adjacent experimental plots at åmli, southern Norway, B-1 and B-2. Both experiments were established on the same glacifluvial deposits, with forest consisting of uniform stands of Pinus sylvestris L. The forest in B-1 was planted between 1968 and 1970, while B-2 consisted of naturally regenerated trees. The experiments included plots supplied with artificial rain of varying acidity over a period of seven and eight years for B-1 and B-2, respectively, in addition to control plots. In experiment B-1, experimental acidification was carried out both in unlimed plots and in plots applied with three different levels of lime. The two experiments showed distinct differences with respect to effects of the acidification on mobilization of heavy metals from the O horizon. In experiment B-1, the amount of Zn and Cd decreased with decreasing pH in artificial rain, while Pb and Cu were not appreciably affected. The reduction in Zn and Cd concentrations ceased after termination of the acidification experiment. Liming reduced the leachability of Zn, but still appreciable amounts of Zn were obviously leached from the O horizon during the experiment. In experiment B-2 a high retention even of Zn and Cd was observed in the O horizon, probably due to microbial uptake and accumulation.     

Lysimeter study with a cambic Arenosol exposed to artificial acid rain: I. Concentrations of ions in leachate

The effects of artificial acid rain on soil leachate composition were studied in a lysimeter experiment. Cambic Arenosol (Typic Udipsamment) in monolith lysimeters was treated for 6 1/2 yr with 125 mm yr^?1 artificial rain in addition to natural precipitation. Artificial acid rain was produced from groundwater with H₂SO₄ added. pH levels of 6.1, 4 and 3 were used. Increasing content of H₂SO₄ in the artificial rain increased the concentration of Ca²⁺ and Mg²⁺ in the leachate significantly. The pH of the leachate was slightly reduced only by the most acidic treatment (pH 3). The H^+? retention was not accompanied by a proportionate increase in the Al ion concentration. A slight increase in the Al ion concentration was only observed in the leachate from the pH 3-treated lysimeter. We conclud that cation exchange and/or weathering were the main buffer mechanisms in the soil. The study supports conclusions from other acidification studies, that acidic precipitation is likely to increase the leaching of Ca²⁺ and Mg²⁺ from soils.     

Lysimeter study with a cambic arenosol exposed to artificial acid rain: II. Input-output budgets and soil chemical properties

The effects of artificial precipitation with different pH levels on soil chemical properties and element flux were studied in a lysimeter experiment. Cambic Arenosol (Typic Udipsamment) in monolith lysimeters was treated for 6 1/2 yr with 125 mm yr^?1 artificial rain in addition to natural precipitation. Artificial acid rain was produced from groundwater with H₂SO₄ added. pH levels of 6.1, 4 and 3 were used. ‘Rain’ acidity was buffered, mainly due to cation exchange with Ca²⁺ and Mg²⁺, which were increasingly leached due to the acid input. The H⁺ retention was not accompanied by a similar increase in the output of Al ions, but a slight increase in the leaching of Al ions was observed in the most acidic treatment. The net flux of SO₄ ^2? from the lysimeters increased with increasing input of H₂SO₄, but in the most acidified lysimeters significant sorption of SO₄ ^2? was observed. The sorption was, however, most likely a concentration effect. The ‘long-term’ acidification effects on soil were mainly seen in the upper O and Ah-horizons, where an impoverishment of exchangeable Ca²⁺ and Mg²⁺ was observed. An increased proportion of Al ions on exchange sites in the organic layer was observed in the pH 3-treated soil. By means of budget calculations the annual release of base cations due to weathering was estimated to be between 33 and 77 mmol_c m^?2.