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研究了天然有机物胡敏酸和富里酸 ,螯合剂EDTA和DTPA和四种简单有机酸对紫色土镉的溶出效应和吸附解吸行为的影响。结果表明 ,供试八种有机物均能显著促进镉从紫色土中的溶出。作用大小顺序为 :EDTA≥DTPA >柠檬酸 >胡敏酸 >草酸 >富里酸 >酒石酸≥水杨酸。有机物对土壤镉溶出和迁移的影响是其对土壤镉吸附和解吸综合作用的结果。有机物显著降低了紫色土对镉的吸附 ,其作用大小顺序与其对镉的溶出能力的相对大小顺序一致 ,同时也改变了吸附镉的解吸特性。有机物影响下 ,紫色土镉的吸附动力学模型以双常数方程拟合最佳。而吸附等温曲线以Freundlich方程拟合最好 ,吸附常数n与有机物对土壤镉的溶出率之间存在良好的相关性。 相似文献
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Ülgen İlknur Konak Dilek Ercili-Cura Juhani Sibakov Tuula Sontag-Strohm Muharrem Certel Jussi Loponen 《Journal of Cereal Science》2014
Functional properties of conventional oat materials are relatively poor with respect to foam and emulsion formation and stabilization. This is largely due to the poor solubility of oat proteins and the presence of lipids in aqueous extracts of oats. In the experimental part of this study, extracts were prepared from different type oat flours (oat endosperm flour, oat fine flour, CO2-defatted whole oat flour and CO2-defatted oat flour) with a buffered aqueous extraction procedure at acidic (pH 4.5 and 6.5) and basic (pH 8.5 and 10.5) regions. The solubility of proteins was the highest at pH 10.5 and NaCl concentration of 2%. Among the extracts, CO2-oat flour showed improved foaming and emulsifying properties at basic pH values. The presence of 0.1% NaCl resulted in the lowest foam volumes, but the emulsion activity and stability values being the highest. Sucrose addition resulted in increased foam and emulsion stability of suspensions. Heat treatment at 80 °C impaired foam properties, whereas the stability of emulsions increased with the increase in temperature from 20 °C to 80 °C. CO2-extracted oats can be useful raw materials in beverages and other aqueous applications where protein functionality plays an important role. 相似文献
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Changes in pH, titratable acidity, total soluble solids and proteins ofDabar sorghum (Sorghum bicolor (Linn) Moench.) during naturalfermentation at 37 °C for up to 36 h were monitored. The pH ofthe fermenting material decreased sharply with a concomitant increase in the titratable acidity. Total soluble solids increased with progressivefermentation time. The crude protein and non-protein nitrogen slightlyincreased during the last stages of fermentation. The in vitroprotein digestibility markedly increased as a result of fermentation.The globulin plus albumin fractions increased significantly (p 0.05)during the first 8 h of fermentation. Kaffirin fraction decreasedduring the first 8 h of fermentation but increased sharply as fermentationprogressed. Cross-linked kaffirins fluctuated during the fermentationprocess. Glutelin like protein, which was the minor fraction, trueglutelins, the second most abundant fraction, together with non-extractableproteins fluctuated during the fermentation process. 相似文献
4.
Nugdallah Gaafar A. El Tinay Abdullahi H. 《Plant foods for human nutrition (Dordrecht, Netherlands)》1997,51(3):277-282
Nine cowpea cultivars obtained from Wad Medani Research Station were used in this study. The variation in protein fraction was: albumins 4.0–12.0, globulins 65.6–79.7, prolamins 1.4–2.2, G1-glutelins 0.9–3.0, G2-glutelins 1.4–2.9. G3-glutenins 9.1–14.0 and insoluble protein 0.5–3.0%. Two cowpea cultivars, H8-14 and CB-46, selected for their high albumin content, were cooked in 150 ml of boiling distilled water under reflux for 45 minutes. The protein fractions in the cooked seeds were determined. Results indicated that albumin and globulin fractions decreased significantly (p0.05) for both cultivars after cooking. This decrease was accompanied by a significant increase in G3-glutelin fractions. 相似文献
5.
Sang?Youn?Oh Dong?Il?YooEmail author Younsook?Shin Wha?Seop?Lee Seong?Mu?Jo 《Fibers and Polymers》2002,3(1):1-7
Cellulose carbonate was prepared by the reaction of cellulose pulp and CO2 with treatment reagents, such as aqueous ZnCl2 (20–40 wt%) solution, acetone or ethyl acetate, at −5–0°C and 30–40 bar (CO2) for 2 hr. Among the treatment reagents, ethyl acetate was the most effective. Cellulose carbonate was dissolved in 10% sodium
hydroxide solution containing zinc oxide up to 3 wt% at −5–0°C. Intrinsic viscosities of raw cellulose and cellulose carbonate
were measured with an Ubbelohde viscometer using 0.5 M cupriethylenediamine hydroxide (cuen) as a solvent at 20°C according
to ASTM D1795 method. The molecular weight of cellulose was rarely changed by carbonation. Solubility of cellulose carbonate
was tested by optical microscopic observation, UV absorbance and viscosity measurement. Phase diagram of cellulose carbonate
was obtained by combining the results of solubility evaluation. Maximum concentration of cellulose carbonate for soluble zone
was increased with increasing zinc oxide content. Cellulose carbonate solution in good soluble zone was transparent and showed
the lowest absorbance and the highest viscosity. The cellulose carbonate and its solution were stable in refrigerator (−5°C
and atmospheric pressure). 相似文献
6.
The effect of main chain structure of anion-containing copolyesters on the properties of copolyester sizing agents was investigated.
The copolyesters were prepared by conventional two step polymerization technique from DMT, DMI, DMS, EG, and DEG. The copolyesters
synthesized were characterized by atomic absorption spectroscopy,1H-NMR Spectroscopy, GC, FTIR Spectroscopy, and DSC. The solubility decreased as the DMT content increased. The copolyesters
having DMT:DMI=1:1 showed the minimum viscosity. The effect of EG content on the solution stability was not clear and the
samples having high DMI content showed better solution stability. The water resistance was best when only DMI and EG were
used, while it was worst when DMT:DMI was 1:0. 相似文献
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[目的]研究木糖结晶的溶解度及介稳区。[方法]采用激光法试验考察了木糖在纯水、乙醇-水溶液中的溶解度以及木糖在水中的超溶解度,确定木糖水溶液的结晶介稳区。[结果]木糖在纯水和不同体积配比的乙醇-水溶液中的溶解度随着溶液体系温度降低而明显减小,结晶介稳区的宽度在低温范围内比高温阶段要宽。[结论]为利用农产品废弃物木糖结晶的生产操作提供了理论依据。 相似文献
10.
[目的]筛选出有限酶解鲶鱼肉蛋白的最佳用酶种类和酶解工艺条件,为鲶鱼食用肉粉的加工提供理论依据。[方法]以鲶鱼为原料,经预处理、采肉、漂洗、斩拌、有限酶解、打浆和干燥等工序加工而成鲶鱼食用肉粉。其中选择4种酶(风味蛋白酶、枯草杆菌中性蛋白酶、碱性蛋白酶和木瓜蛋白酶)作为水解用酶,分别在各酶最佳酶解条件下对鲶鱼肉糜进行水解,以鲶鱼肉粉的溶解度为评价指标。[结果]用中性蛋白酶作为有限酶解的酶类加工出的鲶鱼食用肉粉溶解度可达90%以上,最佳酶解工艺条件为:酶用量0.55%,酶解时间60 min,料水比1∶3(g∶g)。[结论]用中性蛋白酶作为有限酶解的酶类,加工出的鲶鱼食用肉粉溶解度最高,风味最佳。 相似文献