Potato absorption and phytoavailability of Cd,Ni, Cu,Zn and Pb in sierozem soils amended with municipal sludge compost

Effects of sludge utilization on the mobility and phytoavailability of heavy metals in soil-plant systems have attracted broad attention in recent years. In this study, we analyzed the effects of municipal sludge compost(MSC) on the solubility and plant uptake of Cd, Ni, Cu, Zn and Pb in a soil-potato system to explore the mobility, potato plant uptake and enrichment of these five heavy metals in sierozem soils amended with MSC through a potato cultivation trial in Lanzhou University of China in 2014. Ridge regression analysis was conducted to investigate the phytoavailability of heavy metals in amended soils. Furthermore, CaCl_2, CH_3 COONH_4, CH_3COOH, diethylene triamine pentacetic acid(DTPA) and ethylene diamine tetraacetic acid(EDTA) were used to extract the labile fraction of heavy metals from the amended soils. The results show that the MSC could not only improve the fertility but also increase the dissolved organic carbon(DOC) content of sierozem soils. The total concentrations and labile fraction proportions of heavy metals increase with increasing MSC percentage in sierozem soils. In amended soils, Cd has the highest solubility and mobility while Ni has the lowest solubility and mobility among the five heavy metals. The MSC increases the concentrations of heavy metals in the root, stem, peel and tuber of the potato plant, with the concentrations being much higher in the stem and root than in the peel and tuber. Among the five heavy metals, the bioconcentration factor value of Cd is the highest, while that of Ni is the lowest. The complexing agent(DTPA and EDTA) extractable fractions of heavy metals are the highest in terms of phytoavailability. Soil properties(including organic matter, p H and DOC) have important impacts on the phytoavailability of heavy metals. Our results suggest that in soil-potato systems, although the MSC may improve soil fertility, it can also increase the risk of soils exposed to heavy metals.     

不同裂解温度的污泥生物质炭理化特性分析

研究裂解温度对污泥生物质炭基础理化性质的影响,为安全、合理、高效处置污泥提供理论依据。将干燥污泥分别在200、300、500、700℃下进行热裂解处理(SBC200、SBC300、SBC500、SBC700),获得污泥生物质炭,测定其基础理化特性。结果表明：不同温度制备的污泥生物质炭表面颗粒结构完好,孔径范围均集中在10~50 μm,其中低温生物质炭SBC200表面较光滑,最可几孔径和中值孔径最大,分别为20.1 μm和14.8 μm,高温生物质炭SBC700表面较粗糙,比表面积最大,为5.98 m²/g。随裂解温度的提高,污泥生物质炭的产率、含水量、电导率、挥发分、阳离子交换量显著下降,全碳、氧、全氮、氢含量、有效磷和铵态氮均逐渐降低,pH和灰分含量显著增加。将污泥制备成生物质炭,是安全处置污泥的有效途径,低温制得的污泥生物质炭具有更大的提高土壤肥力的潜力,而高温制得的生物质炭在改良土壤酸性的应用上具有更大的潜力。     

发酵污泥不同施用方式对土壤温度和棉花苗期生理特性的影响

[目的]研究城市发酵污泥在棉花上的最佳施用方式,降低棉花生产成本。[方法]采用盆栽试验方法,探讨不施用发酵污泥(CK)、污泥覆盖土壤表面(处理(1))、污泥与土壤混合(处理(2))、混合+覆盖(处理(3))4种方式对棉苗、根系生长的影响。[结果]污泥的不同处理对棉花苗期根际土壤温度增温效果明显,以10 cm处土层最明显,处理(1)、(2)、(3)地温平均较对照CK高1.2、2.9、1.5℃;显著促进棉花苗的生长,棉花出苗率、健苗率、株高、叶面积、叶片数与CK相比极显著增加;对棉花苗根有诱导和促进生长作用,根长、根数量、根粗、根体积显著高于CK。[结论]发酵污泥3种不同施用方式都能够促进棉花苗生长,改善叶片和根的各项生理指标。整体来看,处理(2)综合优势好,是发酵污泥较有效的施用方式。     

农村污水治理PPP项目风险因素分析--基于ISM-MICMAC模型

当前我国在探索将PPP模式应用于农村污水治理领域时面临诸多挑战,准确识别与分析项目风险因素具有实际意义。基于全寿命周期视角,采用文献研究与德尔菲法识别出农村污水治理PPP项目面临的21个风险因素,运用解释结构模型(ISM)与交叉影响矩阵相乘法(MICMAC)构建了风险因素的六级层次结构模型并分类,以揭示了风险因素间的内在联系,并提出政策建议。研究表明,项目缔约与运营阶段是关键阶段,合作单位选择是最根本的风险因素。此研究可为我国农村污水治理PPP项目风险分担与控制研究提供新思路,同时为政府部门提供投资决策与风险管理的依据。     

复合潜流人工湿地对农村生活污水的净化效果 及其微生物群落结构特征

试验探究了复合潜流人工湿地对农村生活污水的净化效果及其微生物群落结构特征。结果表明，当水力负荷为0.35 m³·(m²·d）^-1时，系统对TN、NH₄⁺-N、COD和TP去除效率分别为（89.84±7.64）%、（98.67±1.31）%、（61.63±16.01）%和（70.21±8.00）%。湿地中一共发现11个主要菌门、18个主要菌纲和33个主要菌属，变形菌门（Proteobacteria）、蓝藻门（Cyanobacteria）、拟杆菌门（Bacteroidetes）、厚壁菌门（Firmicutes）、绿弯菌门（Chloroflexi）、酸杆菌门（Acidobacteria）、放线菌门（Actinobacteria）是其中的优势菌门，它们在各级湿地中表层和底层的相对丰度分别是57.26%、61.37%、91.60%、93.22%、88.78%、88.02%。蓝藻菌纲（Cyanobacteria）、α-变形菌纲(Alphaproteobacteria) 、芽孢杆菌纲(Bacilli)和γ-变形菌纲(Gammaproteobacteria)、β-变形菌纲(Betaproteobacteria)是其中优势菌纲，约占主要菌纲的70%。共有17个优势菌属，在各级湿地中的分布情况不同，其中芽孢杆菌属（Bacillus）相对丰度最高，集中分布于第三级湿地，其次是Leptolyngbya、席藻属（Phormidium），在第一、二级湿地中广泛分布。复合潜流人工湿地具有良好污水净化效果，系统中有机物和氮素的去除主要依靠微生物作用，磷素的去除主要依靠基质吸附沉淀作用。     

MBBR和LSP工艺在污水深度处理中的性能探究

指出了MBBR工艺和LSP工艺属于当前应用较多的新型水处理工艺。当将传统的好氧曝气池改造为MBBR工艺时,改造结果表明:COD降低30.8%,BOD 5降低42.8%,氨氮降低25.0%,总氮降低17.2%,SS降低57.9%,总磷降低26.7%;而LSP工艺通过形成复杂的微生物食物链,消耗剩余污泥量,实现对污泥的减量化处理。应用到改造工程中,产泥量降低67.5%,同时能够强化处理系统的生化功能,COD和BOD 5都有明显降低,分别降低了11.7%和12.1%。     

电动技术去除剩余污泥中重金属

电动技术去除污泥中重金属受到多种因素的影响，因此非常有必要探讨适宜的修复参数。本论文系统研究了电解时间、介质pH、强化剂种类、电压和超声振荡时间等因素对电动力学去除剩余污泥中重金属Cu、Zn、Ni、Cr的影响。结果表明，最适宜的电解时间为12 h，最佳介质pH为2，最适电压为1.5 V·cm^-1，最适宜的超声振荡时间为1.0 h。添加EDTA对剩余污泥中Ni的去除效果最佳，最佳添加浓度为0.20 mol·L^-1；添加柠檬酸对剩余污泥中Zn的去除效果最佳，最佳添加浓度为0.25 mol·L^-1；酒石酸对剩余污泥中Cu的去除效果最佳，最佳添加浓度为0.25 mol·L^-1。研究为电动技术去除剩余污泥中重金属的实践提供了理论参考。     

Denitrifying granules in a marine Upflow Anoxic Sludge Bed (UASB) reactor

Marine land-based Recirculating Aquaculture Systems (RAS) are generally perceived as environmentally friendly aquatic production systems. To promote their sustainability even further and reduce the discharge of nutrients, there is a need for cost-effective end-of-pipe treatment technologies for removing nutrients. This includes nitrate-nitrogen (NO₃⁻-N) for which well-proven technologies for freshwater systems exists, while similar technologies for saltwater systems are less advanced. Granular technology has been developed since the 1970s in wastewater treatment under the upflow anaerobic sludge bed (UASB) concept. This concept is based on the enrichment of different bacterial aggregations into a compact granule, optimizing synergistic and syntrophic bacterial processes by reducing the diffusion distance of substrates between the different bacterial consortia forming the granule. The following study examined the: 1) granular formation; and 2) nitrate removal capacity of a marine Upflow Anoxic Sludge Bed (UASB) reactor operating at different up-flow velocities (0.40–2.11 m/h). The results showed that marine denitrifying granules developed within 27 days using preconditioned rainbow trout (Oncorhynchus mykiss) organic matter waste, and that the highest specific denitrification rate (321.9 ± 13.1 mg NO₃⁻-N/g Total Volatile Suspended Solids (TVSS)/d) was found at an upflow velocity of 0.97 m/h. The marine UASB denitrifying granule reactor had a total capacity of removing 14.9 kg NO₃⁻-N/m³ reactor volume per day at a hydraulic retention time of 1.9 h, making it a strong candidate for end-of-pipe denitrification of marine RAS effluent as well as for in-line treatment in marine systems.     

有机污泥干燥特性与干燥模型研究

为了有效处理含水率较高且体积庞大的有机污泥,实现与低温热解工艺相结合,进一步完善污泥处理与利用知识体系,研究了干燥温度与升温速率对污泥干燥过程中的质量、失重率、含水率、热量的影响。同时研究了不同温度下污泥的干燥速率和含水率的变化规律,并建立了污泥干燥的数学模型。实验结果表明:从不同干燥特性曲线可以看出,污泥的干燥特性符合理论的3个阶段,预热时间极短,恒速阶段持续时间也不长,最后的减速阶段时间最长。干燥终温为240℃时污泥干化时间最短,速率最快。二次模型的预测值与实测值决定系数为0.992 4,均方根误差和残差平方和分别为0.035和0.032,与其他数学模型相比,二次模型对污泥干燥过程的拟合优度最高。     

Process performance of anaerobic co-digestion of waste activated sludge and aquaculture sludge

The mesophilic anaerobic co-digestion (AcD) performances of waste activated sludge (WAS) and aquaculture sludge (AS) were studied. Mixtures of different compositions (0, 30, 50, 70 and 100 % of AS on the volume basis) were used as AcD substrates and tested via biochemical methane potential assay. The results showed that CH₄ production increased with AS/WAS ratio increment, and AS alone used as the substrate showed the maximum CH₄ yield, which was 8% higher than that achieved using WAS alone as the substrate. The CH₄ yield values were well fitted with the modified Gompertz model. The maximum methane potential (P₀) and maximum methane production rate (R₀) increased from 66.8 mL CH₄/g VS_fed to 70.9 mL CH₄/g VS_fed and from 4.40 mL CH₄/g VS_fed·d to 5.59 mL CH₄/g VS_fed·d, respectively, as the AS/WAS ratio increased from 0% to 100 %. In addition, lower levels of free ammonia and non-biodegradable organic matter contributed to the CH₄ production increasing with AS/WAS ratio increased.