基于不同分析方法研究磷酸根在矿物表面吸附机制的进展

磷素是植物生长必需的营养元素,也是联系生态系统中生物与非生物作用的关键元素。对磷酸根在矿物表面吸附反应机制的深入认识,有助于了解其在陆地和水环境中的形态、迁移、转化和生物有效性。本文主要综述了磷酸根在常见(土壤)矿物表面吸附机制的研究进展。各种分析技术或方法,如OH–释放量分析、Zeta电位分析(电泳迁移率测试)、等温滴定量热法、原子力显微镜、X射线光电子能谱、红外光谱、核磁共振波谱、X射线吸收光谱、表面络合模型、量子化学计算等,均以不同方式揭示磷酸根在不同矿物体系的吸附机制。磷酸根在矿物(尤其是铁、铝氧化物)表面的吸附通常伴随着水基和羟基的交换。一般认为磷酸根在矿物表面主要形成双齿双核、单齿单核内圈络合物,且受pH的影响较大。pH以及磷酸根在矿物表面的吸附密度影响内圈络合物的质子化状态。在低pH、高磷浓度、较高反应温度、较长吸附时间,以及弱晶质矿物吸附等条件下矿物表面吸附的磷可在矿物表面转化形成含磷的表面沉淀,造成矿物溶解转化以及磷生物有效性的进一步降低。最后展望了磷酸盐在矿物-水界面吸附有关的研究热点和方向。     

喀斯特山区不同土地利用方式下石灰土化学风化特性

研究喀斯特山区不同土地利用方式（耕地、荒草地、退耕还草地和林草间作地）石灰土剖面化学风化特征，探讨矿质元素在石灰土剖面的分布、迁移和富集特征，从不同土地利用方式下土壤风化度，元素淋溶度、迁移度和残积度的角度分析土壤化学风化特征。结果表明：喀斯特山区石灰土剖面氧化物含量以SiO₂、Al₂O₃、Fe₂O₃为主，其他氧化物含量相对较低，均属于中等变异元素，SiO₂、Al₂O₃、MgO含量以荒草地较高，CaO、Na₂O含量以林草间作地较高，Fe₂O₃、MnO、P₂O₅、K₂O以耕地较高；研究区土壤处于中等化学风化阶段，富铝化程度弱，不同土地利用方式下荒草地土壤化学蚀变系数较强，林草间作地土壤富铝化程度较高；研究区土壤K、Na、Ca淋失严重，荒草地盐基离子淋失明显，林草间作地盐基离子淋失程度相对较低；土壤Fe、Al相对富集明显，残积程度高，林草间作地Al含量积累明显，退耕还草地Fe含量富集显著；实施“退耕—还草”等增加植被覆盖度的治理模式对土壤的保护作用显著。     

Effect of drying methods on the discoloration of three major domestic softwood species in Korea

1 Introduction Three major softwood species in Korea are Japanese pine (Pinus densiflora), Korean pine (Pinus koraiensis) and larch (Larix leptolepis) which have been used for traditional buildings and furniture for a long period of time. They are easily discolored due to drying and UV irradiation. It has been observed that the discoloration varies with different drying methods and the extent of UV irradiation (Mottonen and Luostarinen, 2001; Kang, 2003). To prevent beech from discolorat…     

Crack formation due to weathering of radial and tangential sections of pine and spruce

The development of cracks and changes in appearance have been investigated on radial and tangential sections of pine (Pinus sylvestris L.) and spruce (Picea abies Karst.) after exposure outdoors for 61 months. The degradation of the sections has also been studied at the micro-level. The annual ring orientation was the most important factor affecting crack development on weathering. After 61 months of outdoor exposure, the tangential sections of spruce had 1.7-2.2 times greater mean total crack length per area unit than the corresponding radial sections. In pine, the total crack length per area unit on the tangential sections was 2.2-2.6 times greater than that on the radial sections. Tangential and radial sections show the same colour change as a result of weathering. Tangential sections have more and deeper cracks than radial surfaces. The cracks on the tangential sections occur frequently in both earlywood and latewood. On radial sections, cracks occur primarily at the annual ring borders, but to a certain extent also in the earlywood. Decomposition of the cell wall takes place in both radial and tangential cell walls, and cracks tend to follow the fibril orientation in the S2-layer of the cell wall. The radial cell wall of the earlywood has a large number of pits which are degraded at an early stage.     

Mineral bioaccessibility in French breads fortified with different forms iron and its effects on rheological and technological parameters

The present study investigated the effect of different forms of Fe used in the fortification of wheat flour on the rheological characteristics of flour and technological quality of French breads and the bioaccessibility of added Fe, Zn and Ca naturally occurring by in vitro assay. The results demonstrated that the wheat flour was suitable for use in bakery products; however, the farinograph and extensograph parameters were affected by different forms of Fe, which also changed the technological quality of breads, with no negative impacts on bread making. The NaFeEDTA and SF microencapsulated proved to be the most effective’s forms of iron, due to its higher dialyzed Fe content. Zinc bioaccessibility is not high, thus the NaFeEDTA contributed positively for the absorption of this mineral. In contrast, a high bioaccessibility of calcium was observed, which was not affected by the majority forms of iron. Additionally, Fe, Ca and Zn naturally occurring also presented high bioacessibility. Thus, French bread made with flour fortified with iron can contribute to demand and supply of minerals, and the form of Fe used can affect not only Fe bioaccessibility, but also Zn, leading to changes in the rheological properties of wheat flour and technological quality.     

岩石-土壤-四川牡丹元素迁移体系中的微生物效应

[目的]研究四川牡丹岩土环境背景以及微生物在元素迁移过程中的作用,为了解营养元素的表生地球化学行为规律及微生物在元素迁移体系中的作用提供理论依据。[方法]利用ICP-OES测定四川牡丹生境母岩、土壤以及种子的大量(P,S,K,Ca,Na,Mg,Al)、微量(Fe,Mn,Cu)营养元素含量,同时利用Illumina高通量测序技术测定根际土壤中细菌、真菌的组成和结构。[结果](1)四川牡丹生长土壤以弱碱富钙为主要特征,元素组成基本保留了母岩特征;(2)元素从母岩到土壤中的迁移富集系数排序为:CaNaSPMgKAlFeMnCu,植物吸收系数排序为:PSKCuMgCaNaMnFeAl;(3)碱土金属淋溶率和铝铁率对土壤细菌的多样性(Alpha)影响显著,但对真菌的影响不显著;(4)P,Mn的迁移主要受母岩控制,而Ca,Mg,Fe,S等元素的迁移富集受到了微生物的影响。[结论]细菌和真菌在元素迁移体系中的作用相似,主要参与Fe,S,Mg,Ca的相关反应过程。     

乐昌峡水利枢纽工程右岸坝肩边坡变形稳定分析

乐昌峡水利枢纽右岸高边坡风化层深厚,岩石强度弱,大坝右岸坝肩开挖后,将形成约215m的开挖边坡,边坡处于降雨强度大的地区,在施工期边坡开挖过程中的变形稳定,直接影响到碾压混凝土大坝的施工工期,十分关键.为了验算边坡开挖中和开挖后的稳定性,首先采用有限元法,对边坡开挖过程进行模拟,给出边坡的变形、屈服区等应力应变情况,利用强度折减法得到边坡的抗滑稳定安全系数,其次,用刚体极限平衡法计算安全系数,并与有限元的计算结果进行对比分析.在缺少渗流基本资料情况下,对深厚风化层的稳定状态,在极限平衡分析中,进行受降雨影响下的敏感性分析.最后对该工程提出加强观测和排水等措施,对边坡的稳定具有指导意义.     

不同配比施肥对华北花岗片麻岩山地土壤促成的作用

华北花岗片麻岩山区土壤严重退化,恶劣的土壤环境是该地区植被恢复的限制性因子.利用不同配比的化肥对试验区内土壤进行促成技术研究,结果表明:各种配比的肥料间,对土壤有机质和营养元素的影响(以全P释放量为例),以NPK1和NPK2处理效果最好,其分别提高风化速率29.68%和31.21%;对土壤粒径的影响(以<1 mm粒径土壤重量百分比为例),同样以NPK1和NPK2处理效果最好,其分别提高风化速率30.50%和24.81%.综上分析可以说明,各种配比的化肥对土壤促成起到了一定的作用,试验区内土壤正朝成熟土壤方向演化.     

Yield and quality components of silage maize in killed and live cover crop sods

In sloping areas with high precipitation, planting maize into live winter cover crop sods may help to alleviate the environmental problems associated with clean-tillage production systems of maize. The present study evaluates the performance of silage maize (Zea mays L.) under several cultivation methods: CC (conventional cropping system, i.e., maize was sown into the bare, autumn-ploughed soil); LGS/CK (maize was planted into a living Italian ryegrass (Lolium multiflorum Lam.) sod which was subsequently herbicidally killed); and LGS/MR (similar to LGS/CK, but the ryegrass was mechanically regulated). The research was conducted in the midlands of Switzerland on a fertile sandy loam under humid conditions during three cropping seasons. With 110 kg N ha⁻¹ (fertilizer nitrogen plus mineral nitrogen of the soil at maize planting), the CC system was much more productive than were the LGS/CK and LGS/MR systems in terms of dry matter and nitrogen yields of maize. Increasing the nitrogen supply to 250 kg N ha⁻¹ considerably reduced the yield advantage of CC over the LGS/CK and LGS/MR systems, indicating that nitrogen was the most limiting factor for maize yield in the mulch seeding systems. With 250 kg N ha⁻¹, the LGS/CK and LGS/MR systems produced greater total yields of digestible organic matter (maize plus ryegrass) than did the CC system, whereas the total nitrogen yield was similar for all cropping systems. The whole-shoot concentrations of nitrogen were highest under CC, irrespective of the level of nitrogen supply. With 110 kg N ha⁻¹, concentrations of phosphorus and magnesium were clearly higher for the mulch seeding systems. There were only minor differences among the cropping methods in the concentrations of potassium and calcium in the whole shoot. When 250 kg N ha⁻¹ were applied, there were no significant variations among the cropping systems in the concentrations of minerals. Changes in the botanical composition of the cover crop sod and in the time and method of cover crop control may help to reduce the competition for nitrogen between maize and the living mulch.     

Evaluation of elemental depletion weathering rate estimation methods on acid-sensitive soils of north-eastern Alberta, Canada

Immobile element-based weathering estimation methods assume that Zr (or Ti) is an immobile element, and that weathering rates of other elements can be estimated according to the enrichment of Zr in weathered horizons relative to an unweathered parent material. This approach was used to estimate base cation weathering rates for 33 soil profiles on acid-sensitive terrain in north-eastern Alberta. Zirconium generally showed enrichment within the rooting zone, but the deepest (subsoil) samples were not always associated with the lowest Zr concentrations. Weathering rates estimated with the Zr depletion and Pedological Mass Balance (PMB) methods were generally low (ranges: 0-51 and 0-58 mmol_c m^− 2 yr^− 1, respectively); however, low base cation oxide concentrations and heterogeneity within soil profiles complicated weathering rate calculations and net base cation gains were calculated for several (six) sites. Evaluation of the Zr depletion and PMB weathering estimates against those calculated with the process-oriented PROFILE model at a subset (n = 9) of the sites indicated the estimates were poorly related, with PROFILE rates typically being higher. The effects-based emissions management strategy for acid precursors in this region requires spatial coverage of soil properties (including weathering rates) across a large area, but the apparent limitations associated with the immobile element based methods in this region: identifying representative parent soils and deriving weathering rate estimates comparable to more robust methods are arguments against their candidacy for future use.