固液反应球磨制备Fe-Zn和Fe-Sb系金属间化合物

采用一种固液反应球磨专利技术制备了Fe-Zn和Fe-Sb系列金属间化合物粉末，考察了金属液体中加入与磨球成分相同的金属粉末对反应速度的影响，并分析讨论了该技术制备金属间化合物的机理和特点．     

Experiments on the preparation of Mn-Al master alloy by self-propagating high-temperature synthesis

Self-propagating high-temperature synthesis（SHS） is applied to produce Mn-Al master alloy for the first time. The thermodynamic data of Mn-Al master alloy are estimated, and the adiabatic temperature is calculated by Miedema model and two-parameter model of intermetallics. The reaction product is investigated by using chemical titration optical microscope,X-ray diffraction analysis, in which Mn2O3, Mn3O4 and CaO are taken as raw materials and Al as a reductive agent. Theoretical calculation and experimental results show that the adiabatic temperature is 3 160 K,and the feasibility of the SHS reaction is determined consequently. The content of manganese in master alloy is up to 78%,which broadens the methods of producing Mn-Al master alloy in practice.