Present Status and Development of Synthesis Technologies for TiC,TiN,Ti(C, N) Powders

The preparation technologies of TiC?TiN?Ti(C, N) powders used home and abroad in recent years are reviewed, and the technical processes and characteristics are analysed. The existing problems and development trends of these technologies are also discussed. By seeking cheaper raw materials and achieving new high temperature technologies by plasma, microwave, laser, and electric arc and combining SHS and MA the low-cast and large-scale preparation of high quality TiC, TiN, Ti(C, N) powders are becoming one of the hot research topics. With the development of research and the improvement of preparation techniques, more convenient, more economic and more efficient preparation techniques will provide TiC, TiN, Ti(C,N) powder a broader prospective application.     

The Study on Smelting Ti-Si Ferroalloy by DC Electrothermal Process Using PISC Blast Furnace Titaniferous Slag

The new process for semiting Ti-Si ferroalloy using Panzhihua Iron & Steel Company (PISC) blast furnace titaniferous slag is introduced. The reduction and impoverishment law of TiO2 in slag and the effects of DC on smelting Ti-Si ferroalloy are studied when smelting Ti-Si ferroalloy by electrosilicothermal method,Ti-Si ferroalloy containing about 20% Ti can be produced by electrosilicothermal method. and Ti recovery rate is less than 60 %. And then, electrosilicoaluminothermal method is developed, by which Ti-Si ferroalloy containing Ti more than 30% and Si less than 35 % can be produced, and Ti recovery rate is higher than 80%. Ti-Si ferroalloy can replace TiFe martially in steelmaking,and residue slag can be used to make cement.     

PHASE ANALYSLS OF LOW-VALENCE TITANIUM IN SLAG CONTAINING HIGH TITANIUM

Hcl is used to remove MF4, Fe2O3 and part of FeO. The residue is dissolved by H2SO4-HF-H3PO4. Then, NH4Fe(SO4)2 is added to oxidate low-valence titanium and the standard solution of K2Cr2O7 is used to titrate Fe2+. The amount of total iron minus the amount of iron which has been removed, so that the amount of residue Fe2+ can be adjusted. This method has many advantages such as simplicity, rapidity repeatability.     

掺镍TiO2的微波合成及催化降解有机废水

以氯化镍和硫酸钛为原料,以十二烷基硫酸钠为表面活性剂,通过直接投料微波合成了掺镍二氧化钛(Ni2+TiO2).以催化降解甲基橙为模型来考察其可见光光催化活性,研究了Ni的掺杂量、热处理温度、双氧水投加量、溶液酸度及掺Ni2+TiO2光催化剂用量等因素对光催化性能的影响.结果表明,当Ni2+/TiO2复合物的直接投料摩尔比为0.8％,在500℃的温度下热处理2h,催化剂用量为1.0 g/L,H2O2投加量为3 mL/L,溶液pH 5的条件下,可见光催化效果最好,此时2 mg/L的甲基橙溶液经光催化降解40min后,降解率达到94.5％.     

Influence of soil pH and application of zinc on the yield and uptake of selected nutrient elements by rice

Abstract

Rice grown on a recently water‐leveled Crowley silt loam that contained less than 1.8 μg g^‐1 of 0.1 N HCl‐extractable Zn with pH levels ranging from 6.8 to 7.7, responded to Zn application. Each kg ha of applied Zn as Zn chelate, 14.2 % Zn, resulted in increases of +673, +477, and +2026 kg rice ha^‐1 at pH 6.8, 7.3, and 7.7, respectively. There was a critically low concentration of Zn in rice plants at the midtillering, first joint, and panicle differentiation stages of plant development when no Zn was applied. A yield response to applied Zn was obtained when the concentration of Zn in rice tissue was less than 15 μg g^‐1.

Application of Zn resulted in a significant increase in the uptake of N by rice plants at each of the three stages of plant development. Application of Zn also resulted in relatively large and significant increases in the uptake of Zn from the soil irrespective of soil pH. The uptake of Zn by rice plants at each of the growth stages showed a two‐ to three‐fold increase following Zn application when soil pH was 6.8 and 7.3. Also, the uptake of Zn by rice plants following Zn application showed a four‐fold increase at midtillering, a five‐fold increase at first joint, and a six‐fold increase at panicle differentiation, respectively, when soil pH was 7.7.     

微量元素氨基酸络合物在猪营养中的应用

微量元素氨基酸络合物是化学性质稳定，吸收和利用功能特殊的新型微量元素添加剂。近年来的一些研究表明，微量元素氨基酸络合物有利于提高母猪的繁殖性能，促进仔猪和生长肥育猪的生长，增加采食量，在较低水平下能够满足猪的需要，降低微量元素从粪中的排泄量。但在目前的推广应用中尚存在一些亟待解决的问题。     

大蒜超氧化物歧化酶的分离纯化及其性质的研究

以壳聚糖为基质的金属螯合亲和层析法纯化大蒜SOD ,得到比活为 1191U/mg的酶蛋白 ,回收率为 71% ,纯化倍数为7.2 9。实验表明 ,经 8mol/L的尿素处理后大蒜SOD活性不发生变化 ,并且可耐 6 0℃高温 1h而活性不下降     

多元螯合与多重螯合微量元素的理论及其在饲料业中的应用

本文针对有机微量元素存在的问题,特别是许多有机微量元素产品实际是少量螯合物和大量无机和有机微量元素的混合物等情况,根据有机微量元素中无机微量元素与有机物结合的螯合率、转化率、螯合常数、螯合强度的机理,应用系统动物营养学原理,提出有机微量元素多元螯合和多重螯合的理论.多元螯合是指在同一反应体系中,一种有机物与多种无机元素分别结合的工艺.多重螯合是指在同一反应体系中,一种无机金属元素与多种有机物分别结合的工艺.研究和开发单一螯合、多元螯合和多重螯合等系列产品,可以满足饲料业与养殖业不同目的的需要.     

复合氨基酸螯合锌、锰对肉鸡生产性能的影响

选用1200只7日龄商品代AA肉用仔鸡,随机分成6个处理,每个处理4个重复,每个重复50只鸡,用3D复合氨基酸螯合锌、锰分别替代基础日粮中相应无机元素水平的0%,20%,40%,60%,80%,100%,研究其对肉用仔鸡生产性能、腿病发生率和死亡率的影响以及适宜替代比例。试验结果表明:饲粮添加复合氨基酸螯合锌、锰对肉仔鸡生产性能、腿病发生率和死亡率有一定的改善作用,与相应无机元素相比,饲养全期和相对增长率提高,其中试验组4(60%)和试验组5(80%)的体重增长率明显提高(P<0.05),其饲料转化率分别较对照组增加11.8%和11.0%。从本试验各项指标综合考虑,肉仔鸡饲料中3D复合氨基酸螯合锌、锰替代相应无机微量元素的适宜比例为60%。