Extractives relating to heartwood color changes in sugi (<Emphasis Type="Italic">Cryptomeria japonica</Emphasis>) by a combination of smoke-heating and UV radiation exposure

 Sugi green logs with red or black heartwood were smoke-heated, and the changes in the color of the heartwood after ultraviolet (UV) (λ = 365 nm) radiation exposure were then observed. After UV radiation exposure, the redness and yellowness increased in both the red and black heartwoods, whereas the brightness decreased. In the black heartwood, the resulting color turned from yellowish white to reddish brown. Reddening in black heartwood after exposure to a combination of smoke heating and UV radiation is thought to be due to a decrease in brightness and an increase in both redness and yellowness. However, the degree of change in heartwood color by UV radiation exposure was not greatly affected by smoke-heating treatments of various lengths. When methanol extracts were fractionated and exposed to UV radiation, the yellowness increased in the n-hexane-soluble portion and the redness increased in the acetone-soluble fractions from the n-hexane-insoluble portion. These results suggest that the n-hexane-soluble fraction contains the substances that allow heartwood color to change to yellow after UV radiation exposure, and the acetone-soluble-fraction from the n-hexane-insoluble portion contains the substances that allow it to change to red. Received: November 14, 2001 / Accepted: June 3, 2002 Acknowledgment This research was supported in part by a Grant-in-Aid for Scientific Research from the Japan Society for the Promotion of Science. This study was presented in part at the 51st Annual Meeting of the Japan Wood Research Society, Tokyo, April 2001 Correspondence to:N. Yoshizawa     

Power spectrum density and experimental modal analysis of wide belt sander applied in domestic wood industry

This paper took the upper-lower wide belt sander B229 with four-feet wide belts, manufactured in China, as the study target. By means of framework dynamic design, we study its vibration characteristics by commencing from the place having horizontal defects and used experimental modal analysis (EMA) and power spectrum density (PSD) to observe the sanding parts and the whole machine, respectively. In the modal test, we mainly adopted the cross spots testing method to get the frequency response function of the fixed spots to every excitation vibration spot, then applied the SISO frequency response function and the frequency response function fitting method to identify and complete parameter recognition, respectively. The typical frequency response function chart of the whole machine and its sanding parts, as well as its second-order mode charts of contacting roller, were obtained. Through PSD analysis, we can get the amplitude-frequency spectrum and drive frequency. Translated from Scientia Silvae Sinicae, 2005, 41(6): 132–137 [译自: 林业科学]     

Wood Moisture Content Measurement by X-Ray Exposure Method

lNTRoDUCTIONTheon-sitcnon-dcstructit'cmcasurcl11cntofu.oodmoisbocontcntattTactsgrcatintcrcsts.Itpla3'simpor-tantpartsinthescicntificrcscarchsucl1asonthchcatandmasstransportproccssesint"ooddri'ing.thcim-pregnationofliquidinxt'ood.thcmoisturccontcntdistri-b…     

Crack formation due to weathering of radial and tangential sections of pine and spruce

The development of cracks and changes in appearance have been investigated on radial and tangential sections of pine (Pinus sylvestris L.) and spruce (Picea abies Karst.) after exposure outdoors for 61 months. The degradation of the sections has also been studied at the micro-level. The annual ring orientation was the most important factor affecting crack development on weathering. After 61 months of outdoor exposure, the tangential sections of spruce had 1.7-2.2 times greater mean total crack length per area unit than the corresponding radial sections. In pine, the total crack length per area unit on the tangential sections was 2.2-2.6 times greater than that on the radial sections. Tangential and radial sections show the same colour change as a result of weathering. Tangential sections have more and deeper cracks than radial surfaces. The cracks on the tangential sections occur frequently in both earlywood and latewood. On radial sections, cracks occur primarily at the annual ring borders, but to a certain extent also in the earlywood. Decomposition of the cell wall takes place in both radial and tangential cell walls, and cracks tend to follow the fibril orientation in the S2-layer of the cell wall. The radial cell wall of the earlywood has a large number of pits which are degraded at an early stage.     

Lignin Characterization of Triploid Clones of Populus tomentosa Carr.

In order to understand the structural characteristics of lignin in triploid clones ofPopulus tomentosa and its changes in the processes of pulping and bleaching, milled wood lignin （MWL）, lignin carbohydrate complex （LCC） and the residual lignin from kraft pulp （KP） and sulfite pulp （SP） were isolated and analyzed by Fourier transform infrared （FTIR） spectrum and ^13C nuclear magnetic resonance （NMR）. The most diagnostic peaks were assigned and the differences were discussed. The spectral patterns reveal that triploid P tomentosa shows the specific features of hardwood from temperate areas, but in the spectrum of FTIR, the strength ratio orAl270 cm^-1 to A1226 cm^-1 is 0.88, higher than the average of hardwood from temperate areas, which will make the lignin delignification more difficult during pulping and bleaching. The LCC from triploid P tomentosa is mainly composed of xyloglucan and glucuronic acid, and other glucides have much lower ratio. In LCC FTIR, there are three peaks at 1 427, 1 329 and 1 046 cm^-1, indicating that both semi-cellulose and cellulose could exist in LCC, and that there might be relationships between cellulose and lignin. Compared with the residual lignin from KP and SP, the condensed structure in KP is more than that in SP.     

国产人造板宽带砂光机功率谱密度和试验模态分析

以国产B229型四四砂架人造板双面宽带砂光机为研究对象,从易产生横纹缺陷入手,对其砂架部件、整机等分别采用试验模态分析(EMA)及功率谱密度法(PSD)来开展振动动态特性研究。在模态试验中,采取测量点固定、改变激振点的跑点测量方法,得到固定测量点对各激振点频响函数,并应用SISO频响函数识别法,通过频响函数曲线拟合来完成模态参数识别,获到典型的整机、砂架部件的频响函数图和接触辊的二阶振型图。通过PSD分析,获得砂光机的PSD图谱和激励频率等。     

杠杆压铊张紧系统带锯空转振动特性的分析

本文对杠杆压铊张紧系统带锯产生振动的原因,进行了试验和理论研究。用2034型频谱分析仪试验表明,带锯条振动属于复杂周期信号的离散型频谱,是由多个简谐振动叠加而成;同时理论考察分析表明,带锯条杠杆压铊张紧系统不同于秤量重物的“平衡秤”,不可能达到“静平衡”,而是在锯轮参数激振作用下形成周期性受迫振动。锯轮参数激振和杠杆压铊张紧系统位移激振之间交互作用,是使带锯条产生周期振动并引起张紧力发生变化的重要原因。     

乙酰化处理对樟子松木材耐光性和热稳定性的影响

【目的】探讨乙酰化处理对人工林木材耐光性和热稳定性的影响,为木材颜色调控技术及高耐光染色木材的研发提供理论依据。【方法】以樟子松木粉为试样,加入乙酸酐和二甲苯溶液,在120℃条件下分别反应5,10,20,40,60 min,测试乙酰化处理时间对木粉增重率的影响;分别称取1 g经不同时间乙酰化处理的木粉和未处理木粉,置于 UV老化试验箱内辐射100 h,利用红外光谱分析 UV辐射前后乙酰化木粉化学官能团的变化,通过热重和扫描电镜分析乙酰化木粉的热稳定性及其形貌变化。【结果】随着乙酰化处理时间的延长,樟子松木粉的增重率呈现先增加后降低的趋势,在处理40 min 时木粉增重率最大;乙酰化木粉在1741 cm －1和1385 cm －1处的CO,C—H特征吸收峰强度均大于原木粉,处理时间40 min 时木粉的吸收峰强度最大;UV 辐射后,乙酰化木粉在1508 cm －1处木质素苯环特征吸收峰强度明显大于原木粉,处理时间40 min 时木粉的吸收峰强度最大,表明木粉经乙酰化处理后光稳定性得到提升;热重分析显示,经乙酰化处理后,木粉热分解所需的温度明显提高,表明乙酰化木粉的热稳定性好于原木粉;扫描电镜分析表明,乙酰化处理可增强木粉微观构造抵抗光劣化的能力。【结论】乙酰化处理能有效抑制樟子松木材的光降解反应并提升其热稳定性。     

42%氟啶草酮复配33%二甲戊灵乳油对棉田杂草的防效、杀草谱及安全性评价

【目的】研究复配33%二甲戊灵乳油(200 mL/667m²)的42%氟啶草酮悬浮剂的最佳剂量,杂草的杀草谱以及对棉花安全评价。【方法】采用田间与室内结合方法,在不同浓度42%氟啶草酮悬浮剂复配33%二甲戊灵乳油(200 mL/667m²)条件下,分析其对棉田杂草防效、杀草谱以及对棉花出苗率、株高、产量等的影响。【结果】42%氟啶草酮悬浮剂对龙葵、反枝苋、灰藜、马齿苋有较高的杀草活性,EC₅₀分别为17.58、17.68、16.87和16.44 mL/667m²。药剂的最佳组合为42%氟啶草酮悬浮剂(35~40 mL/667m²)+33%二甲戊灵乳油(200 mL/667m²);42%氟啶草酮悬浮剂用量高于35 mL/667m²时对阔叶杂草的防效达到90%以上,且要优于禾本科杂草,该组合对苘麻和田旋花的防效低于59%;42%氟啶草酮悬浮剂复配33%二甲戊灵乳油(200 mL/667m²)对棉花的株高、鲜重、果枝数、单铃重、籽棉产量没有影响,出苗率在42%氟啶草酮悬浮剂(40~200) mL/667m²+33%二甲戊灵乳油的药剂下下降到90%以下。【结论】复配药剂的最佳浓度是42%氟啶草酮悬浮剂(35~40 mL/667m²)复配33%二甲戊灵乳油(200 mL/667m²);42%氟啶草酮悬浮剂单剂用量高于35 mL/667m²时对棉田主要阔叶杂草龙葵,反枝苋、灰藜、马齿苋具有良好的防效,有较高的杀草活性,防效达到90%以上;复配药剂中42%氟啶草酮悬浮剂浓度在40 mL/667m²以上时棉花出苗率下降到90%以下,但是对棉花产量,株高、鲜重没有影响。     

扰动扩散流动分析法测定土壤氮、磷技术研究

随着国家对农业面源氮、磷污染防治力度的加大,土壤氮、磷测定技术迫切需要改善。本研究在对常规的扩散对流（Dispersion convection）和强迫对流（Forced convection）流动分析方法基础上,提出了扰动扩散（Perturbation diffusion）流动分析方法,以实现土壤氮、磷全自动化快速测定与分析。扰动扩散流动分析方法是将样品和试剂定量化后集中在化学反应腔中进行反应,然后程序控制蠕动泵对化学反应腔中反应物进行反复扰动,待化学反应完全稳定后流入光电探测单元完成土壤氮、磷含量测定。采用取自湖北潜江的土壤样品对扰动扩散流动分析方法进行了系统验证,实验结果表明,本研究提出的方法与常规紫外可见分光光度法对氮、磷测定相比,基于硫酸钠和碳酸氢钠联合浸提的土壤铵态氮测量值相关系数为0.915 5,基于氯化钙浸提的土壤铵态氮、硝态氮和水溶性磷测量值相关系数分别为0.998 5、0.990 1和0.991 1。铵态氮、硝态氮和水溶性磷的检出限分别为0.055 4、0.020 3 mg·L^-1和0.008 4 mg·L^-1,相对标准偏差（RSD,n=7）分别为1.8%、4.8%和1.0%。