影响黏性土分散性的化学因素及机理分析

【目的】分析影响黏性土分散性的化学因素和机理。【方法】采用针孔试验、碎块试验,研究了蒙脱石种类、Na+和pH等化学因素对黏性土分散性的影响,并对其作用机理进行了分析。【结果】蒙脱石对分散性的影响与其离子基团有关,钙基蒙脱石具有抑制黏性土分散性的作用,钠基蒙脱石含量与分散化程度呈正相关。土体中的Na+含量越高,土体分散性越强;pH越高,土体分散性亦越强。【结论】同时具备高pH和高含量Na+是黏性土具有分散性的本质原因,土的分散性与矿物成分无关。     

Interrelationships between soil magnesium forms

Abstract

A second order equation best described the relationship between exchangeable Mg and both total and acid‐soluble Mg in select temperate and tropical soils. The relationship between acid‐soluble and total Mg was linear. Soil types differ in their Mg contents. On a per unit weight of material bases the finer soil particles contained more than 95 percent of the total soil inorganic magnesium. In tropical soils, as in temperate soils, the total Mg content of surface horizons tends to decrease with severe weathering, soil erosion and movement of soil colloidal particles down the profile.     

Phytotoxicity of organic acids as influenced by montmorillonite,hydroxy‐Al montmorillonite and phosphate fertilization

Abstract

The germination and growth of wheat seedlings were studied at pH 5.5 in liquid growth media with organic acids in concentrations ranging from 800 to 1200 ppm, before and after interaction of the organic acids with montmorillonite and hydroxy‐Al montmorillonite. Germination was not affected by the organic acids, but subsequent growth was dependent on the kind and concentration of organic acid in the growth medium. Acetic acid was more inhibitory than citric acid. Gallic acid polymerized at pH 5.5 and was phytotoxic at 1200 ppm. Interaction of organic acids with montmorillonite and hydroxy‐Al montmorillonite reduced the concentration of organic acids in solution by adsorption. Despite this reduction in concentration the phytotoxicity of the growth media was enhanced after the interaction. This was caused by the dissolution of surface Al and the effect was more pronounced in cases where hydroxy‐Al interlayered montmorillonite was the adsorbent. Additions of P as KH₂PO₄ alleviated the phytotoxicity of organic acids but not the associated Al toxicity. The amount of P lost by adsorption or precipitation was dependent on the form of Al in the growth media.     

石灰岩发育的乔木林下土壤团聚体形成的影响因素

将采集的喀斯特地区纯石灰岩发育的林下土壤,全部进行干筛分为>5、5—2、2—1、1—0.5、0.5—0.25 mm五个粒级,再将五个粒级的土壤分别湿筛,烘干后收集为>5、5—2、2—1、1—0.5、0.5—0.25 mm五个粒级。对五个粒级的土壤分别进行碳水化合物、胡敏酸、游离氧化铁铝、非晶质氧化铁铝和钙、镁的提取和测定,迅速将提取过胶体的土壤进行湿筛测定分解的各级团聚体含量,以此来分析土壤团聚体稳定性与各因子间的关系。研究结果表明:土壤经干筛后,团聚体含量高,团聚体以大粒径为主,小粒级含量低;土壤经湿筛后,团聚体含量减少不是很明显,组成也是以大粒径为主;胡敏酸对<2 mm粒级的团聚体的稳定性作用最大,游离氧化铁、铝对大团聚体(>5 mm)稳定性的作用最大;0—5cm土层土壤团聚体稳定性总体上好于5—20 cm土壤层;有机胶体对小粒级团聚体稳定性的影响很大。     

纳米蒙脱石抑菌性能研究

本文采用快速分散、研磨、高速离心的方法对高纯蒙脱石进行分级,研究普通蒙脱石和纳米蒙脱石抑制黄曲霉菌的效果。结果表明:蒙脱石在水中分散后,逐步由悬浮液转变为凝胶体,当中位径为3.9μm时,抑菌效果较差;中位径为0.92μm时,抑菌效果明显提高;中位径为0.26μm时,抑菌效果最好。     

ζ电位在纳米二氧化硅-纯丙乳液体系稳定性研究中的应用

通过测量纳米二氧化硅水体系、纯丙乳液-纳米二氧化硅混合体系的ζ电位，确定了在纯丙乳液中加入纳米二氧化硅的最佳pH值条件，即pH值为6，29～7．49，通过红外光谱证实了在混合体系中纳米二氧化硅与纯丙乳液发生了接枝交联，从而提高了混合乳液的储存稳定性和成膜性能。文中还以纳米二氧化硅增强的纯丙乳液制备了高性能的建筑涂料。     

磷-铅-柠檬酸在红壤胶体上相互作用机理初探

以红壤胶体为对象,通过等温平衡试验,研究了柠檬酸对红壤胶体吸附磷的影响,以及吸附磷和柠檬酸后弃去上清液(次级吸附)和保留上清液(共吸附)两种方式对红壤胶体固定铅的影响。结果表明,柠檬酸对红壤胶体磷吸附产生抑制作用,且随着柠檬酸浓度增加而抑制作用增强;用Langmuir方程拟合时,红壤胶体对磷的吸附反应常数K、最大吸附量X m均随柠檬酸初始浓度增加而降低。吸附磷和柠檬酸后,两种处理方式对铅的固定量影响有明显差异,总体上,次级吸附试验中铅的固定量低于共吸附;且两种方式中铅的固定量均随磷初始浓度及磷吸附量的增加而增加,随柠檬酸浓度升高而降低。共吸附中铅固定量在柠檬酸初始浓度为0.1 mmol L-1和磷初始浓度小于0.4 mmol L-1时达到较高值,说明在此浓度下磷和柠檬酸的共同存在促进了红壤胶体对铅的固定。     

Structure and characterization of Chinese fir (Cunninghamia lanceolata) wood/MMT intercalation nanocomposite (WMNC)

With water-soluble phenol-formaldehyde resin as an intermediate, Chinese fir (Cunninghamia lanceolata) wood/montmorillonite nanocomposite (WMNC) was prepared through vacuum impregnation and characterized with XRD, SEM, FTIR and TG-DTA analyses. The XRD analysis indicated that the wood crystallinity of WMNC decreased, the MMT exfoliated and some nano silicate layers entered into the non-crystallized microfibrillar region of the wood cell wall. Wood structure is anisotropic and its impregnation is anisotropic. Due to the nonuniformity of the MMT organic modification, PF intercalation and wood impregnation, the MMT configuration and distribution in wood were diverse. The SEM graphs of WMNC showed that some silicate grains were blocked in the wood cell lumen, some silicate layers adhered to the inner surface of the wood cell wall, and some exfoliated MMT layers even penetrated the wood cell wall. The obtained hydroxyl of WMNC increased and its ether linking decreased. It was considered that MMT and wood interacted not only with hydroxyl bonds, but also involved some chemical linking. Compared with untreated wood and the PF-impreg, the pyrolysis process of WMNC changed; its starting decomposing temperature decreased and its pyrolysis weight loss at high temperatures greatly decreased. The WMNC indicated certain nanoeffects of the composition of the inorganic MMT nanolamellae. __________ Translated from Journal of Beijing Forestry University, 2007, 29(1): 131–135 [译自: 北京林业大学学报]     

新疆棕漠土无机胶体对Cu2+的吸附特征研究

选用采自新疆阿克苏地区典型的棕漠土壤,用模拟吸附方法研究棕漠土无机胶体在不同阴阳离子作用下对Cu2 的吸附特征,得出:棕漠土无机胶体对铜的等温吸附曲线可以用Langmuir等温方程式拟合,解吸后,铜在胶体内的残余量与加入溶液的浓度呈很好的一次函数关系;随着加入支持电解质浓度的增加,胶体对铜的吸附量逐渐减少;不同电解质溶液对土壤无机胶体吸附铜的影响不一样,在Cl-存在下,对铜竞争吸附的影响K >NH4 >Na ;当支持电解质阳离子浓度相同时,阴离子对胶体吸附铜的影响都为SO42->Cl-     

亲水胶体抗馒头老化效果的研究

馒头的老化是制约馒头工业化进程的一个关键问题。采用单因素试验和正交试验,研究3种亲水胶体(黄原胶、海藻酸钠、卡拉胶)对馒头制品在温度4℃贮存下的抗老化效果。试验结果表明,黄原胶、海藻酸钠和卡拉胶对馒头均有一定的抗老化效果。通过正交试验,得到抗馒头老化效果较好的3种胶体复配比例为:黄原胶添加量为0.15%,海藻酸钠添加量为0.05%,卡拉胶添加量为0.15%。