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71.
72.
Chih-Shen Chuang Kuang-Chung Tsai Yi-Chung Wang Ming-Kuang Wang Chun-Han Ko 《Journal of Wood Science》2010,56(3):208-215
Emulsion resins are widely used in wood-based materials for indoor furnishings. Previous studies have demonstrated that the
ability of a material to retard flame arises from the interactions between four major components: i.e., binder resin (BR);
carbonizing substrate (CS); foam-producing substance (FPS); and dehydrating agent (DA). Fire performance as influenced by
wetting and drying cycle (WDC) treatment has not yet been reported. This study aimed to compare the fire performance of materials
coated with EVAc (ethylene vinyl acetate copolymer) and PVAc (polyvinyl acetate copolymer) emulsion resins of differing BR/CS
ratios, subjected to investigation by cone calorimeter. Intumescent formulation significantly enhanced the fire retardancy
of painted plywood by exhibiting lower peak heat release rates (PHRR) and longer time to reach peak release rates. Additionally,
lower BR content in the fire retardant systems further enhanced flame retardancy. The fire retardancy decreases with increasing
the WDC treatment, caused by the weight loss of the coating materials. Infrared (FT-IR) analysis demonstrated that lower BR
content extends the survival duration of the phosphorcarbonaceous structure of chars. The findings in this study enhance the
state-of-the-art understanding of the effect of the intumescent. 相似文献
73.
The formation of a complex with aluminum by low molecular weight compounds and saponified ozone-treated kraft lignins was
evaluated based on the decrease in pH of their solutions on the addition of 0.1 M AlCl3. Decreases in pH were observed with the solutions containing compounds having adjacent carboxyl groups (oxalic acid), carboxyl/alcoholic
hydroxyl groups (glycolic acid), carboxyl/formyl groups (glyoxylic acid), and phenolic hydroxyl groups (protocatechuic acid)
on the addition of 0.1 M AlCl3. The malonic and phthalic acids, having two carboxyl groups, were also effective. These results show that the compounds were
effective in forming complexes with aluminum. This finding corresponds to the fact that aluminum toxicity is reduced by formation
of a complex with aluminum, except in phthalic acid. The chemical structures stated above in ozone-treated kraft lignins contribute,
at least partly, to the complex with aluminum. The pH of solutions containing saponified ozone-treated kraft lignins and alkaline-treated
kraft lignin decreased more than that without modified kraft lignins on the addition of 0.1 M AlCl3, showing that they were effective in forming a complex with aluminum. The high molecular weight part of saponified ozone-treated
kraft lignin was effective in forming a complex with aluminum and in reducing its toxicity. 相似文献
74.
Bock-Gie Jung Sun-Ju Cho Jae-Hyung Ko Bong-Joo Lee 《Journal of veterinary science (Suw?n-si, Korea)》2010,11(3):213-220
Interleukin (IL)-10 exerts potent anti-inflammatory effects by suppression of both T-help (Th) 1 and Th2 cells. Previous studies have reported that IL-10 can ameliorate various inflammatory disorders. The present study was performed to examine whether IL-10 plasmid DNA could suppress development of atopic dermatitis (AD)-like skin lesions in NC/Nga mice, as an initial step towards the development of an appliance for use in dogs with AD. Intradermal injection of IL-10 plasmid DNA markedly inhibited the development of AD-like skin lesions, as evidenced by a marked decrease in skin symptoms and reduced inflammation within the skin lesions. Efficacy was confirmed by significant decreases in eosinophil ratio and serum IgE concentration, and a reduction in the number of Staphylococcus aureus recovered from the ear. Moreover, relative mRNA expression levels of IL-4 and interferon-γ in the skin lesions of mice injected with IL-10 plasmid DNA were also decreased compared with those of control mice. Of note, higher serum IL-10 levels in mice injected with IL-10 plasmid DNA were maintained compared with those in control mice. Taken together, the results indicate that IL-10 plasmid DNA can suppress the development of AD-like skin lesions by suppressing both Th1 and Th2 cell responses. Beneficial effects of IL-10 plasmid DNA may be expected in dogs with AD. 相似文献
75.
Philip Y. Lam Po Yee Chiu Hoi Yan Leung Na Chen Pou Kuan Leong Kam Ming Ko 《Fitoterapia》2010,81(8):1239-1245
The effect of schisandrin B (Sch B) on long-term ethanol-induced oxidative stress in various rat tissues was investigated. Long-term ethanol treatment increased reactive oxygen metabolites (ROM) level in plasma. The ethanol-induced oxidative stress was assessed by mitochondrial glutathione and α-tocopherol levels, antioxidant enzyme activities, malondialdehyde (mtMDA) production and heat shock protein (Hsp) 25/70 levels. Liver was most susceptible to oxidative stress with a significant increase in mtMDA production. Long-term Sch B treatment enhanced mitochondrial antioxidant status in a tissue non-specific manner. Sch B co-treatment ameliorated the alterations in plasma ROM levels, mtMDA production and Hsp 25/70 expression in rat tissues. 相似文献
76.
Han XQ Chung Lap Chan B Dong CX Yang YH Ko CH Gar-Lee Yue G Chen D Wong CK Bik-San Lau C Tu PF Shaw PC Fung KP Leung PC Hsiao WL Han QB 《Journal of agricultural and food chemistry》2012,60(17):4276-4281
A polysaccharide (GSP-6B) with a molecular mass of 1.86 × 10? Da was isolated from the fruiting bodies of Ganoderma sinense . Chemical composition analysis, methylation analysis, infrared spectroscopy, and nuclear magnetic resonance spectroscopy were conducted to elucidate its structure. GSP-6B contains a backbone of (1→6)-linked-β-D-glucopyranosyl residues, bearing branches at the O-3 position of every two sugar residues along the backbone. The side chains contain (1→4)-linked-β-D-glucopyranosyl residues, (1→3)-linked-β-D-glucopyranosyl residues, and nonreducing end β-D-glucopyranosyl residues. An in vitro immunomodulating activity assay revealed that GSP-6B could significantly induce the release of IL-1β and TNF-α in human peripheral blood mononuclear cell (PBMC) and showed no toxicity to either PBMC or a human macrophage cell line THP-1. GSP-6B could also activate dendritic cells (DC) by stimulating the secretion of IL-12 and IL-10 from DC. 相似文献
77.
Ko JA Kim YM Ryu YB Jeong HJ Park TS Park SJ Wee YJ Kim JS Kim D Lee WS 《Journal of agricultural and food chemistry》2012,60(24):6210-6216
Rubusoside (R) is a natural sweetener and a solubilizing agent with antiangiogenic and antiallergic properties. However, currently, its production is quite expensive, and therefore, we have investigated nine commercially available glycosidases to optimize an economically viable R-production method. A stevioside (ST)-specific β-glucosidase (SSGase) was selected and purified 7-fold from Aspergillus aculeatus Viscozyme L by a two-step column chromatography procedure. The 79 kDa protein was stable from pH 3.0 to pH 7.0 at 50-60 °C. Hydrolysis of ST by SSGase produced R and steviol monoglucosyl ester as determined by (1)H and (13)C nuclear magnetic resonance (NMR). Importantly, SSGase showed higher activity toward ST than other β-linked glucobioses. The optimal conditions for R production were 280 mM ST and 16.6 μL of SSGase at pH 5.1 and 63 °C. This is the first discussion detailing the production of R by enzymatic hydrolysis of ST and is useful for the food additive and pharmaceutical industries. 相似文献
78.
The self-assembly of asymmetric ABC triblock copolymers in the ordered structure is investigated using an isothermal-isobaric
molecular dynamics simulation. Unlike symmetric ABC triblock copolymers, more fascinating morphologies are observed in asymmetric
ones because of a larger difference of incompatibility between the components. Various modes of self-assembly in assymmetric
ABC triblock copolymers are also observed depending on the block composition. When the composition of block A is changed from
0.125 to 0.25 at the samef
B
=0.25, the morphological transition from the “cylinder in cylinder” to “cylinders at cylinder” structure is observed in the
simulation. In the case of ABC triblocks withf
B
=0.5, a lamellar-type structure is changed to a cylinder-type structure with increasing the length of block A. When the mid-block
length increases further tof
B
=0.625, the “spheres on cylinder” structure is observed in both the A10B50C20 and A20B50C10 triblocks. From these results, the phase diagram of ABC triblock copolymers can be constructed.
Dedicated to Professor Won-Jei Cho on the occasion of his retirement. 相似文献
79.
Ishida A Ohno K Fukushima K Nakashima K Takahashi M Goto-Koshino Y Fujino Y Tsujimoto H 《The Journal of veterinary medical science / the Japanese Society of Veterinary Science》2011,73(9):1127-1132
High-mobility group box 1 (HMGB1), a nonhistone chromosomal protein, has recently been suggested as a late mediator of the inflammatory cascade. Blood HMGB1 levels are increased in a number of human diseases, and HMGB1 has been suggested to be a useful marker for disease severity and prognosis. The objective of this study was to assess the clinical usefulness of HMGB1 in dogs. Plasma HMGB1 levels, as well as C-reactive protein (CRP), a typical canine inflammatory marker, were measured in dogs with various diseases, especially systemic inflammatory response syndrome (SIRS), and dogs that had undergone surgery. HMGB1 gradually increased and attained a maximum level 72 hr after surgery, whereas CRP increased rapidly, peaking at 24 hr. Although both HMGB1 and CRP levels were significantly increased in dogs with various diseases compared with the control dogs, no correlation was found between the HMGB1 and CRP values. HMGB1 levels in the SIRS group were significantly elevated compared with those in the non-SIRS group. However, the increase in HMGB1 levels above the reference range was not indicative of SIRS. Instead, the presence of increased HMGB1 and CRP levels above the reference ranges significantly affects the poor outcome of SIRS. The present study indicates that HMGB1 is a novel canine inflammatory marker and is distinct from CRP. However, the additional clinical value of HMGB1 measurement remains unclear, and further studies are warranted. 相似文献
80.
Lee JE Lee BJ Hwang JA Ko KS Chung JO Kim EH Lee SJ Hong YS 《Journal of agricultural and food chemistry》2011,59(19):10579-10585
The dependence of global green tea metabolome on plucking positions was investigated through (1)H nuclear magnetic resonance (NMR) analysis coupled with multivariate statistical data set. Pattern recognition methods, such as principal component analysis (PCA) and orthogonal projection on latent structure-discriminant analysis (OPLS-DA), were employed for a finding metabolic discrimination among fresh green tea leaves plucked at different positions from young to old leaves. In addition to clear metabolic discrimination among green tea leaves, elevations in theanine, caffeine, and gallic acid levels but reductions in catechins, such as epicatechin (EC), epigallocatechin (EGC), epicatechin-3-gallate (ECG), and epigallocatechin-3-gallate (EGCG), glucose, and sucrose levels were observed, as the green tea plant grows up. On the other hand, the younger the green tea leaf is, the more theanine, caffeine, and gallic acid but the lesser catechins accumlated in the green tea leaf, revealing a reverse assocation between theanine and catechins levels due to incorporaton of theanine into catechins with growing up green tea plant. Moreover, as compared to the tea leaf, the observation of marked high levels of theanine and low levels of catechins in green tea stems exhibited a distinct tea plant metabolism between the tea leaf and the stem. This metabolomic approach highlights taking insight to global metabolic dependence of green tea leaf on plucking position, thereby providing distinct information on green tea production with specific tea quality. 相似文献