Potential of semiconductor sensor arrays for the origin authentication of pure Valencia orange juices.

Sensor array is a new method used in aroma analysis. This technique was employed for the differentiation of 49 pure Valencia orange juices from 5 different origins representative of the main culture areas of citrus according to their volatile organic fractions. An experimental design was used to set analytical factors, which control the generation of the static headspace; therefore, the preliminary optimization of analytical conditions allows the evaluation of the potential of such an apparatus in this kind of survey. Results obtained were then statistically treated by multivariate analyses such as principal component analysis and factorial discriminant analysis. Sensor arrays performed a good discrimination of the whole juices in classing them according to the origin of Valencia oranges used. A calibration of the sensors was then performed to build a database aiming to classify the juices according to the origin of oranges involved. New supplementary samples were then analyzed to assess the efficiency of the database. This technique coupled with other ones such as high-pressure liquid chromatography and gas chromatography may be a new tool for the investigation of adulteration detection due to the authentication of the origin of raw materials employed in the orange juice processes.     

Simulation of chromium transport in the unsaturated zone for predicting contaminant entries into the groundwater

Heavy metal contaminations in the top‐soil layers can impose serious threats to groundwater quality. A seepage water prognosis of probable future contaminant entries at the groundwater surface has to take into account the emission characteristics of the source zone and the reactive transport of the contaminated leachate through the unsaturated zone. Here, a possible approach is presented, exemplarily for a site contaminated with chromium, encompassing batch elution experiments, unsaturated soil column leaching experiments with flow interruption, soil monolith lysimeter experiments, and numerical modeling of non‐equilibrium solute transport. The prognosis provides a long‐term prediction of Cr concentrations at the groundwater surface. It must be emphasized, that the modeling results are uncertain, because several of the parameters in the simulations can be determined only with significant errors. Additionally, the approach is not applicable routinely for every hazardous waste site. Our study reveals, however, that reactive contaminants can possibly reach the groundwater at hazardous concentrations within very short time.     

The causes of glaucoma in cats

The cause of glaucoma in 131 enucleated eyes from 128 cats was determined in a retrospective histologic study. Obliteration of the ciliary cleft by diffuse iridal melanoma (38 eyes), or other neoplasms (14 eyes), or by the presence of idiopathic lymphocytic-plasmacytic anterior uveitis (53 eyes) were the most frequent lesions likely to explain the development of glaucoma. Secondary changes of inner retinal atrophy, optic disc cupping, scleral thinning with megaglobus, and atrophy of ciliary processes were similar to those described in dogs and human beings with chronic glaucoma. In light of the duration and severity of the glaucoma, the degree of inner retinal atrophy was often less than expected. Diffuse corneal edema and breaks in Descemet's membrane, changes typical of glaucoma in other species, were rarely detected. Eyes with chronic uveitis and glaucoma had collapsed ciliary clefts, iridoscleral adhesions, and posterior displacement of the iris. We were unable to determine whether these changes were consequences of the uveitis and thus responsible for the development of glaucoma, or if they were merely the result of the chronic glaucoma itself.     

Central corneal dermoid in a Labrador retriever puppy

An eight-week-old, male Labrador retriever puppy was presented with an abnormal appearance of the left cornea, observed after the eyelids opened in the second week of life. Ocular examination showed a large central dermoid of the left cornea. The dermoid was excised by superficial keratectomy, and healing was uneventful. The dermoid was classified as a Mann's second type. To the authors' knowledge, a Mann's second type corneal dermoid has not previously been reported in a dog.     

Geochemical and Microbial Processes in Sediments and at the Sediment-Water Interface of Acidic Mining Lakes

Water, Air, &; Soil Pollution -     

Adenocarcinoma of the gland of the third eyelid in seven dogs

Adenocarcinoma of the gland of the third eyelid developed as a smooth, pink nodule on the bulbar aspect of the third eyelid of seven 10- to 16-year-old dogs. Tumors recurred in 4 dogs. One dog, which initially had the most infiltrative-appearing tumor among those studied, was euthanatized 7 months after the first excision, because of extensive local recurrence and suspected metastasis. Tumors did not recur after removal of the entire third eyelid as the initial or follow-up procedure. We recommend removal of the entire third eyelid to prevent local recurrence of the tumor.