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31.
As a new use of bamboo, bamboo cubes may be useful as a shot-blast material for surface treatments. However, a suitable processing
technique for bamboo cubes has not been established. In this study, to obtain basic knowledge regarding the processing technology
for bamboo cubes, we installed shearing blades (upper and lower blades) in a universal testing machine to test cross-sectional
shearing of bamboo. The shearing force generated in this shearing was composed of a vertical component (F
v), a forward component (F
f), and a side component (F
s). This shearing force (F
v, F
f, and F
s) and the machining accuracy were investigated under various processing conditions. The shearing force became larger as the
thickness of bamboo increased. In particular, F
v showed a tendency to increase rapidly. Changes in the shear angle of the upper blade had a remarkable influence on F
v. This result suggests that the shearing force could be greatly decreased by adjusting the shear angle. The shearing force
within bamboo of 3mm in thickness was almost unaffected by the blade angle, and the change of shearing force with increasing
clearance was almost indiscernible. It was clearly demonstrated that a large number of bamboo cubes could be made when the
shear angle was large and cross-sectional shearing was performed from the bark side. However, a consequence of a large shear
angle is that burr area increases.
Part of this article was presented at the 53rd Annual Meeting of the Japan Wood Research Society, Fukuoka, March 2003 相似文献
32.
Nattaya Lourith Takeshi Katayama Kimiko Ishikawa Toshisada Suzuki 《Journal of Wood Science》2005,51(4):379-386
To investigate the biosynthesis and stereochemistry of syringylglycerol-8-O-4′-(sinapyl alcohol) ether (SGSE), a syringyl 8-O-4′ neolignan, feeding experiments and enzyme assays using Eucommia ulmoides were carried out. Diastereoselective formation of erythro-SGSE was found. When [8-14C]sinapyl alcohol was administered to excised shoots of E. ulmoides, 14C was incorporated into free SGSE and SGSE glucosides. In stems, incorporation into (+)-erythro-[14C]SGSE (0.037%) with 9.1% enantiomeric excess (% e.e.) was found; incorporation into the threo isomer was not detectable. Erythro-[14C]SGSE glucosides (0.047%) dominated over threo forms (0.007%) with 74.0% diastereomeric excess (% d.e.); both diastereomers were levorotatory with 32.0% e.e. and 18.3% e.e., respectively. In leaves, higher incorporation into (−)-erythro-[14C]SGSE (0.500%, 15.9% e.e.) than into the threo isomer (0.206%, 7.4% e.e.) was observed (41.6% d.e.). (−)-Erythro-[14C]SGSE glucosides (1.692%, 25.0% e.e.) were produced at higher rates than threo isomers (0.177%, 16.4% e.e.) with 81.0% d.e. In incubations of a mixture of [8-14C]sinapyl and [8-14C]coniferyl alcohols with an insoluble enzyme preparation from stems of E. ulmoides, erythro-SGSE was preferentially produced. The highest % d.e. (82.8) was observed at 60 min with the (+)-erythro isomer (21.4% e.e.) and the (−)-threo form (4.3% e.e.).Part of this report was presented at the 52nd Annual Meeting of the Japan Wood Research Society, Gifu, April 2002, and the 47th Lignin Symposium, Fukuoka, October 2002 相似文献
33.
Variations in the composition of low boiling point (LBP) monoterpenes emitted from needle samples of 150 hinoki (Chamaecyparis obtuse) trees (30 strains, each with five clones) native to Shimane Prefecture, Japan, were investigated using a headspace technique.
The assays revealed considerable proportional variations especially in the amount of sabinene, which ranged from 24% to 78%
of the total LBP monoterpenes. The proportions of α-pinene, myrcene, and limonene negatively correlated with that of sabinene overall. In particular, the proportion of limonene
showed clear negative correlation with that of sabinene (r = −0.98). Differences in the proportion of sabinene among five
clones in each strain were less than 15% in 22 out of 30 strains, indicating that monoterpene composition is constitutively
steady in most strains. In a few strains, however, considerable variation in the composition was observed among clones. 相似文献
34.
Due to a processing error, first author's name is missing in the HTML version of this article abstract page. The correct authors
are given below:
Jun Mu, Tohru Uehara, Takeshi Furuno
The online version of the original article can be found at 相似文献
35.
36.
Takashi Masaki Shigeta Mori Takuya Kajimoto Gaku Hitsuma Satoshi Sawata Masuo Mori Katsuhiro Osumi Shobu Sakurai Takeshi Seki 《Journal of Forest Research》2006,11(4):217-225
The individual growth of tree diameter at breast height (dbh) is analyzed in an even-aged plantation of Cryptomeria japonica from stand age of 45 to 94 years, to examine how the growth of individual trees has been affected by the changes in spacing
resulting from thinning operations. At any age, a significant proportion (0.37–0.46) of the variation in dbh growth during
a 5–11-year period was explained by dbh at the beginning of the period, probably due to greater leaf mass of larger trees.
Next, either one-sided or two-sided competition was added to the model, by calculating the basal area (BA) of neighboring
trees around each tree within a given radius or BA for trees having larger dbh than the focal tree within the radius. After
preliminary analyses, a radius of 8 m was selected as the critical range for tree competition. Although both types of competition
explained a significant proportion (0.09–0.43) of growth variation, one-sided competition was not significant at ages greater
than 54 years. Based on the model at 45 years of age, the initial deviation of growth rate for each tree from the predicted
rate was calculated and added to the models as a third variable. This raised the coefficient of determination up to 0.50–0.74.
These findings have practical significance for forest plantation management, particularly for controlling the growth of standing
trees via thinning, to produce high-quality timber in the future. 相似文献
37.
Two new amino acid-type amphoteric surfactants — disodiumN-(2-fatty acyl amino) ethyliminodiacetate and disodiumN-(2-fatty acyl amino) ethyl-N,N-bis[3-(2-hydroxy) propylsulfonate] amine — were synthesized using tall oil fatty acids as the raw material. Suitable processing conditions for synthesizing the intermediates and final products were probed. In addition, the chemical structures of the intermediates and the final products were identified by infrared spectroscopy, hydrogen nuclear magnetic resonance spectroscopy, and elemental analysis. 相似文献
38.
Stereochemistry and biosynthesis of guaiacylglycerol-8-O-4′-(sinapyl alcohol) ether (GGSE), an 8-O-4′ neolignan, which consists of coniferyl and sinapyl alcohol moieties, in Eucommia ulmoides were investigated. Four 8-O-4′ neolignans, GGSE, syringylglycerol-8-O-4′-(coniferyl alcohol) ether (SGCE), guaiacylglycerol-8-O-4′-(coniferyl alcohol) ether (GGCE), and syringylglycerol-8-O-4′-(sinapyl alcohol) ether (SGSE), were synthesized. Their erythro and threo diastereomers were separated through acetonide derivatives, intermediates of the synthesis, and identified by means of nuclear magnetic resonance (NMR) spectroscopy. All of the erythro-acetonide derivatives have larger coupling constants (ca 9 Hz) for the C7-H resonances than those of the threo ones (1.5–2 Hz). In the case of the four 8-O-4′ neolignans, the C7-H coupling constants of the threo-isomers are not smaller than those of the erythro ones. GGSE isolated previously from this plant was identified as the erythro isomer by comparison of the 13C-NMR data with synthetic erythro-GGSE and threo-GGSE and the other 8-O-4′ neolignans mentioned as above. Administration of a mixture of [8-14C]coniferyl alcohol and [8-14C]sinapyl alcohol to excised shoots of E. ulmoides was carried out and the incorporation of 14C into erythro-[14C]GGSE was found to be higher than that in threo-[14C]GGSE. The occurrence of diastereoselective formation of erythro-GGSE by cross coupling of coniferyl and sinapyl alcohols is suggested.Part of this paper was presented at the 47th Lignin Symposium, Fukuoka, October 2002 and the 53rd Annual Meeting of the Japan Wood Research Society, Fukuoka, April 2003 相似文献
39.
In order to understand the structural characteristics of lignin in triploid clones ofPopulus tomentosa and its changes in the processes of pulping and bleaching, milled wood lignin (MWL), lignin carbohydrate complex (LCC) and the residual lignin from kraft pulp (KP) and sulfite pulp (SP) were isolated and analyzed by Fourier transform infrared (FTIR) spectrum and ^13C nuclear magnetic resonance (NMR). The most diagnostic peaks were assigned and the differences were discussed. The spectral patterns reveal that triploid P tomentosa shows the specific features of hardwood from temperate areas, but in the spectrum of FTIR, the strength ratio orAl270 cm^-1 to A1226 cm^-1 is 0.88, higher than the average of hardwood from temperate areas, which will make the lignin delignification more difficult during pulping and bleaching. The LCC from triploid P tomentosa is mainly composed of xyloglucan and glucuronic acid, and other glucides have much lower ratio. In LCC FTIR, there are three peaks at 1 427, 1 329 and 1 046 cm^-1, indicating that both semi-cellulose and cellulose could exist in LCC, and that there might be relationships between cellulose and lignin. Compared with the residual lignin from KP and SP, the condensed structure in KP is more than that in SP. 相似文献
40.
Takeshi Katayama Jyoji Tsutsui Kazuo Tsueda Takao Miki Yasuhiro Yamada Murao Sogo 《Journal of Wood Science》2000,46(6):458-465
When (±)--oxo-guaiacylglycerol--(vanillic acid) ether (1) is degraded byFusarium solani M-13-1, the-ketone is initially reduced to giveerythro andthreo guaiacylglycerol--(vanillic acid) ethers (2), arylglycerol--aryl ethers, both of which are enantiomerically pure. The absolute configuration in each2 was determined by Mosher's method; the products were converted to,-di-(R)--methoxy--trifluoromethylphenylacetates (MTPA esters) (3) oferythro (-)- andthreo (+)-veratrylglycerol--(methyl vanillate) ethers (3), whose1H nuclear magnetic resonance (NMR) spectra were examined and compared with those of four di-(R)-MTPA ester (3) diastereomers from chemically synthesizederythro (±)-3 andthreo (±)-3. To assign the- and-MTPA-OCH3 peaks, the1H NMR scans of several compounds that have substructures of 3 and their 3,4,5-trimethoxyphenyl analogues were examined. When a racemic alcohol reacts with (R)-MTPA to give a pair of (R)-MTPA ester diastereomers, the value was defined as the absolute value of the difference in the1H chemical shifts of the peak between the diastereomers. It was found that the values of-MTPA-OCH3 were larger than those of-MTPA-OCH3 owing to a shielding effect of the veratryl ring located on the-MTPA-OCH3, and that the-MTPA-OCH3 peaks in the 3,4,5-trimethoxyphenyl compounds shifted downfield relative to those in the veratryl compounds. On the basis of the1h NMR data of (R)-MTPA esters, the absolute configuration of the four chemically prepared diastereomers (3) were determined. The catabolicerythro
3 [fromerythro (-)-3] andthreo
3 [fromthreo (+)-3] were identical to (R, S, R)-erythro
3 and (R, S, S)- threo
3, respectively. An hydrogen species in the fungal reduction would attack the-ketone fromre-face of both (R)-1 and (S)-1, givingerythro (S, R)-2 andthreo (S, S)-2, respectively.Part of this paper was presented at the 33rd Lignin Symposium, Tsukuba, November 1988 相似文献