不同亚铁矿物对As(Ⅲ)和As(Ⅴ)的表面吸附特征及机制比较研究

为探明稻田土壤还原条件下不同亚铁矿物对砷的修复潜力,本研究对比研究了磁铁矿、菱铁矿、黄铁矿三种亚铁矿物在不同 pH 条件下（pH 3.00、5.00、7.00）对 As（Ⅲ）、As（Ⅴ）的吸附特征,并以电位滴定法探究了导致三种亚铁矿物吸持 As（Ⅲ）、As（Ⅴ）能力差异的表面电荷性质。等温吸附平衡实验结果表明,Langmuir模型能较好描述三种亚铁矿物对As（Ⅲ）、As（Ⅴ）的吸附过程。弱酸条件（pH=5.00）下,亚铁矿物对As（Ⅲ）、As（Ⅴ）的吸附容量依次为：磁铁矿[As（Ⅲ）：23.38 mg·g^-1,As（Ⅴ）：71.33 mg·g^-1] >菱铁矿[As（Ⅲ）：11.63 mg·g^-1,As（Ⅴ）：21.69 mg·g^-1]>黄铁矿[As（Ⅲ）：10.72 mg·g^-1,As（Ⅴ）：7.75 mg·g^-1],在弱酸性（pH=5.00）条件下三种矿物中磁铁矿对As（Ⅲ）和As（Ⅴ）吸附容量最高。在中性（pH=7.00）条件下黄铁矿对As（Ⅲ）、菱铁矿对As（Ⅴ）吸附容量相对较高。供试pH条件下磁铁矿、菱铁矿对As（Ⅲ）的吸附强度较高,黄铁矿则对As（Ⅴ）的吸附强度较高。电位滴定实验测得亚铁矿物的电荷零点和总可变电荷量依次为：磁铁矿（pH 9.76;1.025 mol·g^-1）>菱铁矿（pH 7.52;0.240 mol·g^-1）>黄铁矿（pH 4.03;0.084 mol·g^-1）,表面活性位点密度依次为：黄铁矿（90.59 site·nm^-2）>菱铁矿（42.77 site·nm^-2）>磁铁矿（7.94 site·nm^-2）,亚铁矿物对As（Ⅲ）、As（Ⅴ）的吸附容量受溶液pH、总可变电荷量及其电荷零点影响。非专性吸附和专性吸附是磁铁矿和菱铁矿吸附As的主要方式,而黄铁矿则以专性吸附为主。研究表明,不同pH条件下不同亚铁矿物对稻田土壤砷的修复潜力不同,酸性条件下磁铁矿对As（Ⅲ）和As（Ⅴ）有较好修复潜力,中性条件下黄铁矿对As（Ⅲ）、菱铁矿对As（Ⅴ）有较好修复潜力。     

An Experimental Research on Coal base Reducing Poor Siderite to Sponge Iron

A series of experiments were carried out in the department laboratory and showed that using fixed bed jar method the coal base reduction of poor siderite can produce reduction ore.by ball milling and magnetic separation the sponge iron(TFe>80%,SiO 2<6%) was obtained.Thereby the scientific basis for developing and utilizing the low grade siderite were provided.     

Elemental affinity for siderite found in a Japanese paddy subsoil

ABSTRACT

Siderite (FeCO₃), a type of carbonate mineral, is very occasionally recognized as a nodule in anoxic soils and sediments. During siderite formation, elements are expected to be accumulated or excluded between siderite and bulk soil. Therefore, we verified the affinity of 40 elements for siderite found in the gley horizon of a smectite-rich paddy field in northeastern Japan from the elemental concentration of the soil and the siderite dissolved in 2.88 mol L^?1 hydrochloric acid (10% HCl). The concentration ratio of the target element of the soil to the siderite was expressed by the product of the dimensionless R₀ value and ratio of titanium (Ti) concentration of the soil to the siderite (C_siderite /C_soil) = R₀ (Ti_siderite /Ti_soil). The affinity of each element for the siderite was analyzed by comparing the R₀ values. In comparison with Ti used as the reference element, P, Cr, Co and Mo were accumulated (R₀ > 1.0), and alkali metals, such as Li, Na and K, and chalcophile elements, such as Cu, Zn, Cd and Pb, tended to be equal or excluded from the siderite (R₀ ≦1.0). Of the group 2 elements, Ca, Sr and Ba were accumulated, while Mg was excluded. The affinity of Mn for siderite exceeded that of Fe as the main component of the siderite, which reflects the fact that siderite was formed in a fresh water condition. The siderite size did not influence the elemental affinity. Observation of micromorphology using a scanning electron microscope showed that the siderite nodules were aggregations of siderite particles and clays, suggesting that the siderite grew by taking in clay around it. The rare earth element (REE) distribution pattern showed a tendency not to increase linearly but to increase with forming a concave curve at the intervals of the four elements with the increase of atomic number (i.e. tetrad effects). Although these findings are from the lower horizons of anoxic soils, the elemental affinity for siderite of this study is useful in order to elucidate the complex elemental dynamics in the anoxic environment.     

Study on the Properties on Beneficiation and Sintering of WeiYuan Siderite

Roasting,beneficiation,sintering and metallurgical propertiess of WeiYuan siderite are experimentally studied in the Lab,and all knds of the utilizing circuits and methods which can be choosed for WeiYuan siderite are posed.