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1.
Field experiments were carried out to study the effect of different seed‐zinc (Zn) content on grain yield and grain Zn concentration in a bread wheat cultivar Atay 85 grown in a severely Zn‐deficient soil under rainfed and irrigated conditions for two years. Three groups of seeds with Zn contents of 355, 800, and 1,465 ng Zn seed‐1 were obtained through different number of foliar applications of ZnSO4.7H2O in the previous crop year. Experiments were carried out with 23 kg Zn ha‐1 (as ZnSO4.7H2O) and without Zn fertilization to the soil. Grain yield from seeds with 800 and 1,465 ng Zn seed‐1 content was significantly higher than that from low seed‐Zn, especially under rainfed conditions. In the first year, under rainfed and Zn‐deficient conditions, yield of plants grown from the highest seed‐Zn content was 116% higher than the yield of plants grown from the low seed‐Zn content. However, in the first year soil‐Zn application combined with low‐Zn seed resulted in a yield increase of 466% compared to nill Zn treatment with low‐Zn seed, indicating that higher seed‐Zn contents could not compensate for the effects of soil Zn application. Soil Zn application significantly increased Zn concentrations in shoot and grain. However, the effect of different seed Zn contents on Zn concentrations of plants was not significant, probably due to the dilution of Zn in tissues resulting from enhanced dry matter production. The results presented show that wheat plants grown from seed with high Zn content can achieve higher grain yields than those grown from the low‐Zn seed when Zn was not applied to the soil. Therefore, sowing seeds with higher Zn contents can be considered a practical solution to alleviate Zn deficiency problem, especially under rainfed conditions in spite of it being insufficient to completely overcome the problem.  相似文献   

2.
Abstract

Zinc (Zn) adsorption in mollisols conformed to the linear form of Freundlich equation. The log K values were positively correlated with silt, clay, and carbonate contents and soil pH, but negatively correlated with sand content. Sequential desorption of adsorbed Zn in 0.05M Ca(NO3)2, 0.1M Mg(NO3)2, 0.005M DTPA, and 0.1M HCl revealed that weakly and specifically bound fractions of added Zn, which could easily equilibrate with soil solution, were low and decreased with silt and carbonate contents and soil pH. Weakly bound fraction increased with sand content. Strongly bound and complexed fraction of applied Zn was the maximum and increased with clay, soil organic carbon and carbonate contents and specific surface area, but decreased with sand content. The mineral bound fraction of applied Zn was intermediate and increased with silt, clay and carbonate contents, and soil pH and specific surface area. Zinc uptake due to added Zn fertilizer by rice crop (Y) negatively correlated with log K, but positively related to Zn content in the equilibrium soil extract and Zn desorbed in 0.05M Ca(NO3)2. Both log K and l/n values together explained 59.5% of the total variation in Y, while Zn content in the equilibrium soil extract, Zn desorbed in 0.05M Ca(NO3)2, 0.005M DTPA and 0.1M HCl collectively accounted 79.6% of the total variation in Y.  相似文献   

3.
Abstract

The variability in corn yield responses to applications of Zn fertilizer appears to be associated with several complex soil and climatic factors that affect the availability of endogenous soil Zn to the crop under specific conditions. Among the soil chemical properties that influence availability of endogenous Zn are soil pH, organic matter content, and extractable P. Over a period of several years, soil and plant analysis data were collected from 54 field experiments, field trials, and diagnostic visits to producer's fields. These data were subjected to multiple regression analysis, resulting in an equation: Znleaf = 37.14 + 1.513 Znst ‐4.04 pHst ‐ 1.791 ln(Pst/100) where Znst, pHst, and Pst were 0.1N HC1 extractable soil Zn (kg/ha), 1:1 soil‐water pH, and Bray's 1 extractable soil P (kg/ha), respectively. These factors accounted for 67% of variation in leaf Zn, which was a large portion of the variability in Znleaf considering that climatic conditions, management levels, and varietal differences were uncontrolled in most instances. Using the previously published critical level in the leaf opposite and below the ear as 17 μg Zn/g, these data can be used to set required soil test levels of Zn at different levels of extractable P and soil pH. Inadequate levels of extractable Zn would range from 2.5 (at pH 6.0, P = 70 kg/ha) to, 9.5 kg/ha (at pH 7.5, P = 420 kg/ha).  相似文献   

4.
To examine the effect of zinc (Zn) application method on the utilization of phosphorus (P) from applied P fertilizer, a field experiment was conducted on basmati rice–wheat rotation with combinations of Zn levels (0, soil application of 2.5 kg Zn ha 1 and two foliar applications of 2.0 kg Zn ha 1) and P levels (0, soil application of 8.7, 17.5 and 26.2 kg P ha 1). The highest pooled grain yields of basmati rice and wheat were obtained with soil application of 17.5 kg P ha 1 and foliar applications of 2 kg Zn ha 1. Foliar applications of Zn increased the P concentration in grain and straw and the total P uptake by basmati rice and the P concentration in flag leaves of wheat significantly, while soil or foliar application of Zn increased the total P uptake of wheat. Phosphorus application increased the Zn concentration in flag leaves, grain and straw of basmati rice and in grain and straw of wheat and the total Zn uptake of both crops. Phosphorus levels up to 17.5 kg P ha 1 increased utilization efficiency of soil or foliar application of Zn. Zinc application increased the P utilization efficiency of basmati rice and wheat up to 17.5 kg P ha 1 level; foliar Zn application was more effective in a wheat crop than a rice crop.  相似文献   

5.
The effect of six different zinc (Zn) application methods on grain yield and concentrations of Zn in whole shoots and grain was studied in wheat cultivars (Triticum aestivum, L. cvs. Gerek‐79, Dagdas‐94 and Bezostaja‐1 and Triticum durum, Desf. cv. Kunduru‐1149) grown on severely Zn‐deficient calcareous soils (DTPA‐extractable Zn: 0.12 mg‐kg‐1 soil) of Central Anatolia which is the major wheat growing area of Turkey. Zinc application methods tested were: a) control (no Zn application), b) soil, c) seed, d) leaf, e) soil+leaf, and f) seed+leaf applications. Irrespective of the method, application of Zn significantly increased grain yield in all cultivars. Compared to the control, increases in grain yield were about 260% with soil, soil+leaf, and seed+leaf, 204% with seed and 124% with leaf application of Zn. In a similar manner, biomass production (dry weight of above‐ground parts) was increased by Zn treatments. The highest increase (109%) was obtained with the soil application and the lowest increase (40%) with the leaf application. Significant effects of Zn application methods were also found on the yield components, i.e., spike number.m‐2, grain number‐spike‐1, and thousand kernel weight. Spike number.m‐2 was affected most by Zn applications, particularly by soil and soil+leaf applications. Concentrations of Zn in whole shoots and grain were greatly affected by different Zn treatments. In plants without added Zn, concentrations of Zn were about 10 mg‐kg‐1 both in shoots and grain and increased to 18 mg‐kg‐1 dry weight (DW) by soil application of Zn, but not affected by seed application of Zn. Soil+leaf application of Zn had the highest increase in concentration of Zn in shoot (82 mg‐kg‐1 DW) and grain (38 mg‐kg‐1 DW). Soil application of Zn was economical and had long‐term effects for enhancing grain yield of wheat grown on Zn deficient soils. When high grain yield and high Zn concentration in grains are desired, soil+leaf application of Zn was most effective method of Zn application.  相似文献   

6.
Abstract

A greenhouse experiment was carried out to study severity of the zinc (Zn) deficiency symptoms on leaves, shoot dry weight and shoot content and concentration of Zn in 164 winter type bread wheat genotypes (Triticunt aestivum L.) grown in a Zn‐deficient calcareous soil with (+Zn=10 mg Zn kg?1 soil) and without (‐Zn) Zn supply for 45 days. Tolerance of the genotypes to Zn deficiency was ranked based on the relative shoot growth (Zn efficiency ratio), calculated as the ratio of the shoot dry weight produced under Zn deficiency to that produced under adequate Zn supply. There was a substantial difference in genotypic tolerance to Zn deficiency. Among the 164 genotypes, 108 genotypes had severe visible symptoms of Zn deficiency (whitish‐brown necrotic patches) on leaves, while in 25 genotypes Zn deficiency symptoms were slight or absent, and the remaining genotypes (e.g., 31 genotypes) showed mild deficiency symptoms. Generally, the genotypes with higher tolerance to Zn deficiency originated from Balkan countries and Turkey, while genotypes originating from the breeding programs in the Great Plains of the United States were mostly sensitive to Zn deficiency. Among the 164 wheat genotypes, Zn efficiency ratio varied from 0.33 to 0.77. The differences in tolerance to Zn deficiency were totally independent of shoot Zn concentrations, but showed a close relationship to the total amount (content) of Zn per shoot. The absolute shoot growth of the genotypes under Zn deficiency corresponded very well with the differences in tolerance to Zn deficiency. Under adequate Zn supply, the 10 most Zn‐ inefficient genotypes and the 10 most Zn‐efficient genotypes were very similar in their shoot dry weight. However, under Zn deficiency, shoot dry weight of the Zn‐efficient genotypes was, on average, 1.6‐fold higher compared to the Zn‐inefficient genotypes. The results of this study show large, exploitable genotypic variation for tolerance to Zn deficiency in bread wheat. Based on this data, total amount of Zn per shoot, absolute shoot growth under Zn deficiency, and relative shoot growth can be used as reliable plant parameters for assessing genotypic variation in tolerance to Zn deficiency in bread wheat.  相似文献   

7.
This research was conducted to correct the ion of zinc (Zn) deficiencies and to examine the efficiency of foliar Zn application on pear groves along with iron and boron. The treatments consisted of control, soil and foliar applications. Every foliar applied Zn elevated considerably Zn contents of the leaves. But, increases in fruit Zn contents were rather limited as compared to Zn contents of the leaves. It is thought that accumulation of Zn in the fruits was due to movement of Zn from the leaves well-supplied with Zn to the fruits. Therefore, foliar application of Zn should be conducted at least four times at the rate of 0.1% to increase Zn contents in the fruits in terms of human's daily Zn intake. Foliar applications of Zn alone and combined Zn + Fe, Zn + B and Zn + Fe + B applications significantly increased Zn, Fe and B concentrations, respectively, in the pear trees, as well.  相似文献   

8.
Abstract

Blackgram (Vigna mungo L.) plants were grown in glasshouse earthen pot experiment. Zinc (Zn) was applied to the soil at different concentrtions. Plant leaf samples were analysed at the age of 30, 45, and 65 days after sowing. The accumulation of Zn in the plant increased with the applied Zn concentration to the soil. Also a variation in the uptake of Zn by the plant with age has been observed. The excess accumulation of Zn in the plant induced a reduction in the content of some macro‐ [calcium (Ca), magnesium (Mg), potassium (K), and sodium (Na)] and micro‐elements [iron (Fe), manganese (Mn), and copper (Cu)] in the plant leaves. Furthermore, the Ca: Zn ratio decreased with increasing Zn concentration which clearly indicates a toxic Zn effect on blackgram plants.  相似文献   

9.
The present study was carried out on Kinnow mandarin trees (Citrus reticulata Blanco) to study the effect of urea, zinc (Zn) and boron (B) foliar sprays either alone or in combinations on fruit yield and quality. Trees were grown in alkaline sandy loam soil at Dirab, Riyadh, Saudi Arabia. All trees were sprayed twice: before full bloom (February) and after fruit set (April) during two growing seasons. The obtained results showed a significant increase in tree yield and enhancement in fruit physical characteristics (fruit weight, pulp, juice, volume, length and diameter), as well as fruit chemical characteristics [soluble solids content, acidity, pH, total sugars and ascorbic acid] by all foliar treatments in comparison with the control (water only) in both seasons. Spraying urea in combinations with B and Zn resulted in higher fruit yield and better physico-chemical characteristics as compared with urea only, urea + B or urea + Zn.  相似文献   

10.
Abstract

A field investigation was conducted to compare the efficacy of plowed‐down and disked‐in Zn as ZnSO4.H2O in correcting Zn deficiency of corn (Zea mays L.). The soil, Buchanan fine sandy loam, was nearneutral in pH and contained 0.7 ppm of EDTA‐extractable Zn and 1.4 ppm of dilute HCl‐H2SO4 extractable P. Application of 6.72 kg Zn/ha as ZnSO4.H2O corrected Zn deficiency of corn plants on the soil. Corn grain yields and Zn concentrations in tissue samples indicated that the plowed‐down and disked‐in Zn were about equally effective in correcting Zn deficiency where the level of Zn application was 6.72 kg/ha.  相似文献   

11.
Background, Aim and Scope.  The compositional study of suspended matter in water from rivers of different latitudes and climates has revealed that the fine fraction reflects both substrate lithology from source areas or topsoil composition along the course. Metal distribution patterns are also strongly related to the clay mineral fate in fluvial aquatic systems. For the particular case of the coastal area of the Río de la Plata estuary in South America, previous studies have, on the one hand, focused on the analysis of distribution patterns of heavy metals in bottom river sediments and, on the other hand, on the assessment of metal contents in topsoils. The present study was conducted to evaluate the Cu, Pb and Zn distribution in soils and sediments from four drainage basins crossing two differentiated geomorphologic units composed of unconsolidated materials and to understand the metal behaviour. Methods  Data used included the existent, self-produced soil and sediment data sets (grain size, organic matter and Cu, Pb and Zn contents from 124 samples). Analyses were performed by using standardised methods: grain size analysis by sieving and settling; organic matter content based on the reduction of dichromate ion followed by titration; metal content by atomic absorption spectrophotometry following acid digestion. Results and Discussion. The average (% w/w) clay and organic matter content were 45.9 ± 17.1 and 1.5 ± 1.7 for sediments and 32.0 ± 19.8, and 7.5 ± 7.6 for soils, respectively. The raw mean metal concentrations (mg-kg-1 dry weight) for sediments and soils were: Cu: 28.02 ± 27.28, 32.08 ± 21.64; Pb: 32.08 ± 46.94, 68.44 ± 69.25 and Zn: 83.09 ± 150.33, 118.22 ± 74.20, respectively. A good correlation for each clay-normalised metal concentration was found between soil and sediments using regression analysis considering average data for each basin sampling site (r > 0.89, p < 0.05). A comparison between metal concentration levels taking into account geomorphologic units by a t independent sample test showed significant differences for the normalised soil-sediment metal data (p < 0.001), responding to differences in grain size, clay mineralogy, organic matter and neoformed Fe-Mn oxide composition. Conclusion, Recommendation and Outlook  A clear parenthood between the topsoils and the bottom sediments in the study area was found. The Argiudolls from the inner zone are frequently affected by rainwater erosion, which washes the fine materials with sorbed metals and carries them to the streams. These watercourses reach the flat coastal plain, where soil flooding and bottom sediment depositional processes predominate. Here, both soils and bottom sediments are enriched in clay, organic matter and metals. The topography and lithology, under the environmental conditions of a temperate and humid climate control the fate of metals within these small basins. The influence of the physical media on the distribution and fate of pollutants should not be minimised in the understanding of the governing processes from natural systems.  相似文献   

12.
Laboratory and greenhouse investigations were carried out with 65Zn-labeled sources to study the kinetics of desorption, transformation, and availability of Zn applied to soil as zinc-enriched biosludge from distillery molasses (ZEMB) or as zinc sulfate heptahydrate (ZSH). Desorption (0.5 to 72 h) of added Zn by the column method followed a biphasic kinetics with an initial (up to 12 h) faster phase followed by a slower desorption phase. The desorption rate coefficient (K) of the latter phase and the amount of Zn desorbed during 12 to 72 h were significantly higher with ZEMB than with ZSH. Sequential extraction of Zn added as ZEMB and ZSH showed that Zn added as ZEMB was present in higher proportion as water soluble + exchangeable, carbonate bound, organically bound, and reducible fractions than Zn applied as ZSH, which showed a higher proportion of residual fraction. Under greenhouse conditions, dry matter yield (35 days) and total Zn uptake by rice fertilized with ZSH applied at 5 kg Zn ha−1 were statistically similar to those of rice treated with 2.5 kg Zn ha−1 supplied as ZEMB. The highest Zn uptake (167.08 μg pot−1) by rice was recorded in the treatment with 5 kg Zn ha−1 as ZEMB. For wheat plants grown after the harvest of rice, significantly higher dry matter yield over control was recorded in the treatment with ZEMB applied at 5 kg Zn ha−1 to rice. Total Zn uptake by wheat was statistically similar for both ZEMB and ZSH treatments at 5 kg Zn ha−1 dose. Both zinc derived from fertilizer and the percent utilization of fertilizer Zn by rice and by the subsequent wheat crop were significantly higher with ZEMB than with ZSH. Patent filed No. 757/MUM/2007 dated 19.04.2007  相似文献   

13.
Abstract

Investigations have examined the effects of extraction period and soil:solution ratio on the extraction of zinc from some New Zealand soils by EDTA, DTPA, HCl, Ca(NO3)2 and CH3COONH4. A high proportion of the zinc extracted by EDTA, DTPA, HCl, and Ca(NO3)2 was extracted rapidly, within the first 0.5 h, followed by small increases over the next 15 h. An exception occurred with a soil containing iron/manganese concretionary material. In this soil, with both EDTA and DTPA, there were significant increases in the amount of zinc extracted between 1 and 8 h. The amounts of zinc extracted by CH3COONH4 increased gradually with the time of extraction up to approximately 4 h.

Substantial increases in the amounts of zinc extracted with HCl, Ca(NO3)2 and CH3COONH4 were obtained by increasing the soil:solution ratio from 1:2.5 to 1:10. However, soil:solution ratio has little effect on the amounts of zinc extracted by EDTA or DTPA.  相似文献   

14.
Abstract

Chemical fractions of copper (Cu) and zinc (Zn) in the organic‐rich particles collected from filtered aqueous extracts (<20 μm) of an acid soil were determined. A sequential extraction procedure was used to partition the particulate Cu and Zn into four operationally defined chemical fractions: adsorbed (ADS), iron (Fe) and manganese (Mn) oxides bound (FeMnOX), organic matter bound (OM) and residual (RESD). Total extractable concentrations of Cu and Zn in the fine particles were higher than their total concentrations in the original bulk soil. The concentration of particulate Cu was usually much higher than that of particulate Zn. Addition of lime stabilized sewage sludge cake and/or inorganic metal salts markedly increased the concentrations of particulate Cu and Zn in aqueous extracts, especially from limed soil. The proportional distributions of particulate Cu and Zn were quite similar. The two particulate metals were present predominantly in the ADS and FeMnOX fractions, with less (about 20%) in the OM and RESD fractions. Some of the ADS metal fraction was associated with dissolved organic substances. The concentrations of particulate Cu and Zn in the various extractable fractions were significantly affected by the application of lime, lime stabilized sewage sludge cake, or inorganic metal salts.  相似文献   

15.
Abstract

The recovery of applied zinc (Zn) by plants is relatively small. Coupled with lack of leaching, this leads to accumulation of Zn in topsoil which may result in unfavorable growth conditions for the subsequent plants. Different extractants may be used for assessing the Zn status of soils previously treated with Zn sources. The extractability of retained Zn is influenced by soil properties. This experiment was conducted to study the influence of selected properties of calcareous soils on extractability of Zn by three popular Zn soil tests. Twenty samples from surface horizons (0–20 cm) of highly calcareous soils of southern Iran (pH 7.9 to 8.5; calcium carbonate equivalent 16 to 58%) previously treated with three levels of Zn (0, 10, and 20 mg Zn kg‐1 soil as ZnSO4#lb7H2O) in triplicate and under one crop of corn (Zea mays L.) were extracted with DTPA, EDTA‐(NH4)2CO3 and Na2‐EDTA. Extractability (EXT) in a particular extractant was defined as the slope of the regression line, relating extractable Zn of each soil to the rate of applied Zn, multiplied by 100. The EXT values of soils ranged from 24.9 to 73.0% for DTPA, 47.2 to 84.4% for EDTA‐(NH4)2CO3, and 28.2 to 56.7% for Na2‐EDTA. Stepwise regression equations showed that cation exchange capacity (CEC) and calcium carbonate equivalent (CCE) followed by clay content were the most influential soil properties in EXT of retained Zn of highly calcareous soils. The EXT values decreased with increase in CEC, and CCE but increased with increase in clay.  相似文献   

16.

Purpose

This study investigated the extent of metal accumulation by plants colonizing a mining area in Yazd Province in Central Iran. It also investigated the suitability of these plants for phytoextraction and phytostabilization as two potential phytoremediation strategies.

Materials and methods

Plants with a high bioconcentration factor (BCF) and low translocation factor (TF) have the potential for phytostabilization, whereas plants with both BCFs and TFs >1 may be appropriate for phytoextraction. In this study, both shoots and roots of 40 plant species and associated soil samples were collected and analyzed for total concentrations of trace elements (Pb, Zn, and Ag). BCFs and TFs were calculated for each element.

Results and discussion

Nonnea persica, Achillea wilhelmsii, Erodium cicutarium, and Mentha longifolia were found to be the most suitable species for phytostabilization of Pb and Zn. Colchicum schimperi, Londesia eriantha, Lallemantia royleana, Bromus tectorum, Hordeum glaucum, and Thuspeinantha persica are the most promising species for element phytoextraction in sites slightly enriched by Ag. Ferula assa-foetida is the most suitable species for phytostabilization of the three studied metals. C. schimperi, L. eriantha, L. royleana, B. tectorum, M. longifolia, and T. persica accumulated Ag, albeit at low level.

Conclusions

Our preliminary study shows that some native plant species growing on this contaminated site may have potential for phytoremediation.
  相似文献   

17.
Abstract

Equilibrium adsorption experiments on zinc (Zn), cadmium (Cd), copper (Cu), and lead (Pb) were conducted in three horizons of two Ultisols and one Oxisol with and without liming, from Viçosa‐MG (Brazil). Equilibrium solutions were applied as a “cocktail”; containing 700 mg L‐1 of Zn, 20 mg L#lb1 of Cd, 200 mg L‐1of Cu, and 300 mg L‐1 of Pb and its dilutions of 1:5 and 1:20. After shaking, the mixture was centrifuged, the supernatant collected and the pH and the concentrations of metals in the mixture were determined. Soil order, soil horizon, and liming had significant effects on the metal adsorption. Some important changes in the adsorption characteristics of the metals, especially in Zn and Cd, were observed due to competition between the different cations present in the solution. Also, desorption of Zn and Cd was observed with an increasing concentration of the solution. The adsorption data for Zn and Cd did not fit the linear, Langmuir, Freundlich, and Temkin isotherm equations for most situations, as these equations do not consider the possibility of a decrease in the amount of metal adsorbed with increasing metal competition for the adsorption sites. Due to the competition with other metals, the equations, which offered the best fit for Zn and Cd, were quadratic polynomial models. On the other hand, for Cu and Pb, the equations, which showed the best fit were linear, Langmuir, and Temkin, for different situations. The reasons for this behavior were related to the strong competitive forces for the adsorption sites presented by these two metals.  相似文献   

18.
In order to prioritise interventions for micronutrient deficiencies in China, the populations affected by iron and zinc deficiencies were assessed based on data from the 2002 China National Nutrition and Health Survey. The costs and cost-effectiveness of supplementation, food diversification and food fortification were estimated using the standard World Health Organization ingredients approach. Results indicated that 30% of children (60 years), pregnant and lactating women, and 20% of women of reproductive age were anaemic, some 245 million people. Approximately 100 million people were affected by zinc deficiency (zinc intake inadequacy and stunting), the majority living in rural areas. Among interventions on iron and zinc deficiency, biofortification showed the lowest costs per capita, I 0.01 (international dollars), while dietary diversification through health education represented the highest costs at I 1148(international dollars). The cost-effectiveness of supplementation, food fortification and dietary diversification for iron deficiency alone was I 179(international dollars) , I 66 and I 103 (international dollars) per disability-adjusted life-year (DALY), respectively. Data for biofortification were not available. For zinc deficiency, the corresponding figures were I 399(international dollars), I 153(international dollars) and I 103(international dollars) per DALY, respectively. In conclusion, iron and zinc deficiencies are of great public health concern in China. Of the two long-term intervention strategies, i.e. dietary diversification and biofortification with improved varieties, the latter is especially feasible and cost-effective for rural populations. Supplementation and fortification can be used as short-term strategies for specific groups.  相似文献   

19.
Abstract

The fractionation of heavy metals in previously sludge‐amended soil is important to evaluate their behavior in the environment in terms of mobility and availability to crop plants. A surface soil that received two types of sludges at two different rates, plus fertilizer only and no treatment (control), having been fallow for nine years, was used in this study. The contents of cadmium (Cd), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn) fractions in previously sludge‐amended soils were governed by the total content of these metals in the sludges applied and by the rate of sludge application. The contents of these metals were higher for soils that received the Chicago sludge as compared to that receiving the Huntsville sludge. Furthermore, soils that received 20 Mg/ha/yr of sludge for five years generally had higher levels of these metals than those receiving a single dose at the 100 Mg/ha application rate. The percentage of the total content in the water soluble and exchangeable forms was very low (≤1%) regardless of sludge application. The application of sludges tended to reduce the residual fraction and to increase the organic and carbonate fractions. Overall, the predominant forms of the metals in the sludges were as the Cd‐, Ni‐, Pb‐, and Zn‐carbonate and Cu‐organic fractions.  相似文献   

20.
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