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1.
模拟酸雨对红壤铝形态的影响   总被引:13,自引:0,他引:13  
用动态淋洗试验,研究了不同pH的模拟酸雨对红壤中铝形态和性质的影响。结果表明,酸雨淋洗引起红壤中盐基离子的淋失和土壤铝的溶出。随着酸雨溶液,PH的降低,盐基淋失量和铝溶出量增加,酸雨淋洗影响土壤铝形态的转化,使红壤中交换态铝上升,吸附态羟基铝有所下降。这说明在酸雨长期作用下,羟基铝溶解,并转化为交换态铝和引起铝的溶出,使铝进入环境,危害生态系统。  相似文献   

2.
为了探明降水酸度对植物根际环境中铝形态的影响,以马尾松为例,采用根箱栽培、配制不同pH值的模拟酸雨以室外模拟酸雨喷淋法研究马尾松根际及非根际土壤中铝形态的特征及规律.研究结果表明:酸雨对土壤中铝化合物具有溶蚀作用,可促进土壤里活性铝离子(Al3+)溶出,并且酸雨pH值越低,活性铝离子累积溶出量越大,溶出的铝所形成的铝形态在马尾松根际土壤与非根际土壤以及根际不同土层之间存在一定差异,马尾松根际pH值和根系分泌物协同影响铝形态的动态变化.根际土壤中有机铝结合态含量增加.交换态铝含量则稍稍下降.  相似文献   

3.
模拟酸雨对赤红壤磷素及Ca2+,Al3+,Fe2+淋失特征的影响   总被引:2,自引:0,他引:2  
本研究通过室内土柱试验,研究了不同强度和持续时间的模拟酸雨淋溶下,赤红壤磷素淋失量及部分阳离子(Ca2+、Al3+、Fe2+)的释放程度和特征。结果表明:经pH 2.0、pH 3.0、pH 4.0、pH 5.0模拟酸雨持续淋溶 34 d后,淋溶液pH值变化并不明显(>0.05 ),而对Ca2+、Fe2+的溶出有显著的促进作用,Ca2+、Al3+、Fe2+ 溶出量均随 pH 值的降低而升高,Al3+ 和 Fe2+ 淋失量在pH 2.0时均有骤增现象。随淋溶时间的增加,土壤可溶态磷的淋失量表现为先增加后逐渐降低;随着pH值的降低,土壤磷淋失总量也表现为先增加后降低,pH4.0的酸雨有助于促进土壤磷的释放,pH<4.0时土壤磷的淋失减少。相关分析发现淋溶液中磷淋失总量与Al3+和Fe2+溶出量均呈显著负相关(r1=0.6531, r2=0.5107),和Ca2+总溶出量相关关系不显著(r3=0.1287),表明高强度酸雨降低了土壤磷淋失量可能与酸雨作用导致活性铁、铝的大量释放,增加了磷的活性吸附点位,从而增加了对磷酸根离子配位吸附与固定有关。  相似文献   

4.
模拟酸雨对土壤重金属镉形态转化的影响   总被引:11,自引:2,他引:9  
在模拟酸雨作用下,研究了酸雨对不同Cd污染程度下土壤重金属Cd释放和形态分布、转化规律的影响.结果表明,模拟酸雨浸泡土壤后,土壤pH值高于酸雨浸泡前的土壤pH值和模拟酸雨的pH值,表明土壤表面存在质子的消耗,这可能与硫酸根的专性吸附释放羟基和矿物表面的质子化有关.酸雨浸泡土壤能增加土壤活性态Cd的含量,酸雨酸度越大,土壤Cd含量越高,Cd的活化能力越大.当昆山土壤pH值平均由7.20下降到6.42时,Cd的活化率增加了0.34% ~ 3.29%,因此,在昆山土壤酸化严重的背景下,其土壤重金属Cd的活化趋势明显,由重金属Cd释放而对人类和生物造成的风险较大.  相似文献   

5.
pH对酸性土壤中铝的溶出和铝离子形态分布的影响   总被引:59,自引:5,他引:54       下载免费PDF全文
徐仁扣  季国亮 《土壤学报》1998,35(2):162-171
PH对酸性土壤中铝的溶出和土壤溶液中铝离子形态分布的影响的研究结果表明,土壤中铝的溶出量随PH降低而增加,PH对不同土壤中铝的溶出的影响不同,三种土壤中铝的溶出量受PH影响的大小顺序是:红壤〉赤红壤〉砖红壤,说明不同类型土壤中铝的溶出对外来酸的敏感和程度不同。  相似文献   

6.
[目的]针对赣南稀土矿区周边农田存在严重的重金属铅污染情况,研究该地区农田土壤中重金属铅迁移转化规律,旨在为矿区铅污染治理提供依据。[方法]采用模拟酸雨淋滤试验土柱观察重金属铅的淋出量变化,结合响应曲面分析试验结果。[结果]随时间的推移,铅淋出量呈现出快速下降和慢速下降两个阶段。随着pH值的减小,淋滤强度的上升使得铅淋出量呈现先上升后减小的情况。当外源铅浓度增加时,pH值的减小和淋滤强度的上升都会时铅淋出量增加。响应曲面软件对试验数据进行多元回归拟合,交互项中pH值与培养铅浓度较为显著。[结论]铅的污染程度与铅的析出呈正相关,酸雨pH值对污染农田中铅的析出有重要影响。  相似文献   

7.
李平  王兴祥 《土壤》2006,38(4):441-447
采用50cm原状土柱进行模拟淋溶实验,比较研究了模拟酸雨和几种低分子量有机酸对红壤Al、Si及盐基离子淋失的影响。结果表明,模拟酸雨淋洗后土壤中有极少量的Al和一定量的Si及盐基离子淋出。与去离子水对照相比,pH3.5和pH4.5模拟酸雨处理Si的淋出总量分别增加了6.52%和3.26%;K 、Na 、Ca2 和Mg2 等盐基离子淋出量增加了2.41%~96.80%。100μmol/L的柠檬酸、苹果酸和草酸处理Al、Si的淋出量与模拟酸雨处理相差不大,而10mmol/L的柠檬酸、苹果酸和草酸处理则比模拟酸雨处理有显著的增加。有机酸淋洗后淋出液中各盐基离子含量均要高于模拟酸雨处理,盐基离子淋出总量是模拟酸雨处理的1.58~9.27倍。实验结果说明低分子量有机酸在酸化土壤方面比酸雨有更大的威胁。由于盐基离子的大量淋失,模拟酸雨和有机酸淋洗后淋出液pH均要高于原淋洗液pH。  相似文献   

8.
模拟酸雨对果园土壤主要形态酸变化的影响研究   总被引:1,自引:0,他引:1       下载免费PDF全文
采用室内淋溶的方法研究了模拟酸雨对果园土壤pH(H2O)、pH(KCl)、交换性酸(EA)、交换性铝(EAl)、可滴定酸度(BNC)等各形态酸的变化影响,并依据淋溶前后各形态酸的含量评价了土壤酸度的变化。试验结果表明:以土壤pH(H2O)值作为供试土壤酸化指标,pH≤4.5的模拟酸雨淋溶促进了土壤酸化,而pH≥5.5的酸雨淋溶缓冲了土壤的酸化;以土壤pH(KCl)值、交换性酸(EA)、交换性铝(EAl)或可滴定酸度(BNC)作为土壤酸化的指标,pH2.5的酸雨淋溶促进了土壤酸化,而pH≥3.5的淋溶处理缓冲了土壤的酸化,土壤酸度减弱。  相似文献   

9.
施用稻草对酸性红壤活性铝的动态影响   总被引:1,自引:0,他引:1  
酸性红壤区土壤活性铝含量的变化,对作物生长有重要影响。通过室内培养试验研究了施用不等量稻草对酸性红壤水溶性有机碳、pH值和土壤交换性铝和有机络合态铝的动态变化。结果表明,土壤水溶性有机碳在第一天达到最大值,之后开始下降直至趋于平衡。土壤pH值在前10天内快速提高,添加的稻草量越大,提高的幅度也越大,之后缓慢下降至第30天渐趋平衡;土壤交换性铝则是先降低,10天后逐渐增加至稳定状态。有机络合态铝在可溶性有机碳和有机酸等小分子化合物的联合作用下,先增加而后降低。在稻草分解的前10天,土壤水溶性碳、小分子化合物和土壤pH值对铝形态的影响均较大,而到实验后期,土壤pH值发挥着主导作用。  相似文献   

10.
几种低分子量有机酸淋溶对土壤pH和交换性铝的影响   总被引:14,自引:4,他引:10  
李平  王兴祥 《土壤》2005,37(6):669-673
采用原状土柱进行模拟淋溶实验,比较研究了模拟酸雨和几种低分子量有机酸对红壤pH和交换性Al的影响。结果表明,与去离子水CK相比,pH3.5和pH4.5模拟酸雨淋洗后0~10cm土层pH分别降低了0.27、0.44和0.08、0.18个单位,土壤交换性Al含量分别增加了4.43%和2.38%;而10~50cm土层pH没有显著变化。柠檬酸、苹果酸和草酸淋洗后0~10cm土层pH比模拟酸雨淋洗后高0~0.3个单位,土壤交换性Al含量则要低0.08~0.75cmol/kg。与模拟酸雨相比,100μmol/L柠檬酸、苹果酸和草酸淋洗后10~50cm土层pH降低幅度基本上<0.1个单位,交换性Al含量增加了6.99%~12.82%;而10mmol/L柠檬酸、苹果酸和草酸淋洗后10~50cm土层pH降低幅度达0.02~0.83个单位,交换性Al含量增加了22.45%~34.66%。这意味着低分子量有机酸或许比酸雨在加速土壤酸化方面有更大的威胁。  相似文献   

11.
The effects of simulated acid rain retained in soil on the properties of acid soil and its diminishing by application of ground phosphate rock were investigated by using the sorption method.Results show as follows:(1)For yellow brown soil,the effect of simulated acid rain on the properties of soil with a pH value of 5.9 was relatively small,except a great quantity of acid rain deposited on it.(2) for red soil,the effect of simulated acid rain on the properties of soil was significant.With the increase of the amount of acid deposition,the pH value of soil was declined,but the contents of exchangeable H^ ,Al^3 and Mn^2 and the amount of SO4^1- retention were increased.(3) Many properties of acid soils could be improved by applying ground phosphate rock.For example,pH value of soils and the amounts of available P and exchangeable Ca^2 and Mg^2 were increased,and the amounts of exchangeable H^ and Al^3 and SO4^2- retained was reduced.The application of ground posphate rock could effctively diminish the pollution of acid rain to soil.  相似文献   

12.
模拟酸雨对太湖地区水稻土铜吸附—解吸的影响   总被引:29,自引:0,他引:29       下载免费PDF全文
以太湖地区三种典型的水稻土(黄泥土、白土、乌泥土)为例,利用模拟-培养试验,着重研究模拟酸雨对土壤的铜吸附解吸能力的影响,研究结果表明:与未淋溶土壤相比,经模拟酸雨淋溶的三种土壤对铜的吸附量有所增加,随着淋溶液pH的降低,增幅减小:易解吸态铜的解吸量则随淋溶液pH的降低而增大,模拟酸雨降低了土壤对重金融污染的缓冲能力;虽然黄泥土、乌泥土对铜的吸附量远大于白土,但模拟酸雨对乌泥土的吸附-解吸能力的影响速度也大于白土。  相似文献   

13.
三种植物物料对两种茶园土壤酸度的改良效果   总被引:8,自引:4,他引:4  
王宁  李九玉  徐仁扣 《土壤》2009,41(5):764-771
用室内培养实验研究了稻草、花生秸秆和紫云英在 5、10 和 20 g/kg 的加入量水平下对茶园黄棕壤和茶园红壤酸度的改良效果.结果表明:除了黄棕壤加入紫云英处理会降低土壤的 pH 外,其余所有加入植物物料的处理均使土壤 pH 有不同程度的增加,使土壤交换性酸和交换性Al的数量减小,使土壤交换性盐基阳离子和盐基饱和度增加.有机物料对土壤酸度的改良效果与有机物料灰化碱和N含量有关,灰化碱和有机N的矿化使土壤 pH 升高,NH4+-N的硝化使土壤 pH 降低.3种植物物料中花生秸秆对土壤酸度的改良效果优于紫云英和稻草.加入植物物料使红壤中有毒形态Al的浓度显著减小,说明植物物料能够缓解红壤中Al对植物的毒害.  相似文献   

14.
李平  王兴祥 《土壤》2006,38(3):322-327
采用原状土柱进行模拟淋溶实验,比较研究了模拟酸雨和几种低分子量有机酸对红壤交换性盐基的影响。结果表明:与去离子水对照相比,pH 3.5和pH 4.5模拟酸雨淋洗后,0-20 cm土层土壤交换性K 、Na 、 Ca2 和Mg2 含量增加了5.19%-14.65%,而这种增加主要发生在10-20 cm土层。100 μmol/L和10 mmol/L的柠檬酸、苹果酸和草酸淋洗后,0-20 cm土层土壤交换性K 、Na 、Ca2 和Mg2 含量与模拟酸雨淋洗后的结果相差不大,有的层次甚至还要稍低;而在20-50 cm土层则增加了10.42%-96.41%。有机酸淋洗后,土壤交换性盐基的增加受矿物溶解和盐基迁移两方面的影响,而下层的增加可能主要是盐基迁移的影响,由此可见有机酸或许加快了盐基离子向下迁移的速度和土壤酸化过程。  相似文献   

15.
土壤中铅、镉、砷可能直接通过人的口部无意摄入进入人体,危害人体健康,而各研究者评价土壤重金属对人体健康风险所用的实验参数有别,结果缺乏可比性,因此探讨不同评价方法对结果的影响具有重要意义。以污染的棕钙土和红壤为研究对象,应用in vitro方法研究分析胃肠阶段不同土液比、pH以及土壤性质对铅、镉、砷生物可给性的影响。结果表明,重金属的生物可给性与in vitro系统中的pH、土液比、土壤类型以及重金属本身有关。在胃阶段,随着土液比升高,3种重金属生物可给性趋于降低;不同土液比处理下,红壤中铅生物可给性大于棕钙土,而砷则相反,红壤和棕钙土中镉的生物可给性差异不明显。在肠阶段,随着土液比升高,3种重金属生物可给性也趋于降低(除了红壤镉以外),土液比1∶100的3种重金属生物可给性均显著大于1∶10。不同pH处理下,铅的生物可给性随pH的升高逐渐降低,而pH对镉和砷的生物可给性的影响与土液比有关。因此,肠胃实际吸收的重金属可能与摄入水量、食物成分与组成以及食物摄入引起的肠液pH变化有关。  相似文献   

16.
Radish was grown in 46 garden plots in England and Wales. Some of the gardens had been contaminated by heavy metals from lead mining. The soils were analysed for pH, organic content and cation exchange capacity; also for Cd, Cu, Pb, and Zn (total, organic bound, exchangeable and specifically sorbed). Acetic acid-soluble P and exchangeable K, Mg and Zn were also determined. Radish bulbs and leaves were analysed for heavy metals. The results were interpreted using linear and multiple linear correlation and regression analysis. Acetic acid satisfactorily predicted Cd uptake and Pb uptake was best predicted by total soil Pb. These regressions were not improved by including other soil properties. Zinc uptake was best modeled using exchangeable Zn and the predictive power of the regression was improved by including pH. However, the pH term was positive suggesting that raising soil pH would increase uptake. A poor relationship between total and exchangeable Zn was changed to a highly significant relationship by including cation exchange capacity and pH. The latter term was strongly negative. Uptake of Cu was not satisfactorily predicted.  相似文献   

17.
Forms of heavy metal compounds in soils of the steppe zone   总被引:1,自引:0,他引:1  
A parallel scheme of extractions was used for determining heavy metal compounds in uncontaminated and artificially contaminated soils of Rostov oblast. A method for calculating the contents of complex and specifically adsorbed metal compounds from the difference in their concentrations in different extracts was suggested. It was found that the portion of firmly fixed metal compounds decreases and the portion of potentially mobile (exchangeable, complex, and specifically adsorbed) metal compounds increases with an increase in the degree of contamination of chernozems and chestnut soils with lead, copper, and zinc over a one-to two-year-long observation period. This was due to the capacity of heavy metal ions to substitute for the exchangeable cations in the exchange complex of the studied soils, to form complexes with the soil organic matter, and to participate in the specific adsorption. Some differences in the behavior of different metals were found.  相似文献   

18.
Synergism and antagonism of cadmium(Cd),copper (Cu) and selenium (Se) to biological toxicities in red soil,yellow brown soil and black soil were evaluated by MICROTOX method.The relation between forms of the tested metals in soil and the synergism or antagonism between them was also studied.Results showed that owing to the difference of soil chemical properties,toxicity of these metals in soils was different.In red soil with acid reaction and low in cation exchange capacity,antagonism occurred significantly between metals when they coexisted at high concentrations,while synergism occurred only under low concentrations.It is indicated that in red soil,toxicity of metals affected by synergism or antagonism depends on concentration of the metals present.For yellow brown soil and black soil with larger cation exchange capacity and lower exchangeable aluminium(Al),no toxicity of metals was observed even if metals were added to soil in high concentrations.Synergism and antagonism between Cd,Cu and Se were controlled by the forms of metals present.The amount of water-soluble metals was the most important factor in determining synergism and antagonism. In this paper,comparisons of synergism and antagkonism between metals in soils and in water solutions were made.There occurred the synergism of metal toxicity in water solutions when the concentration of coexisting metals was high.This is just opposite to the case in soils.  相似文献   

19.
五氯酚在酸性土壤表面的吸附-解吸特征研究   总被引:21,自引:5,他引:16  
卞永荣  蒋新  王代长  赵振华  孙磊  陈亮  周道斌 《土壤》2004,36(2):181-186
本实验研究五氯酚在江西红壤和南京黄棕壤表面的吸附-解吸特征,结果表明:Freundlich和Langmuir等温吸附方程均能较好地描述PCP在两种土壤表面的吸附,且黄棕壤表面的最大吸附量大于红壤。用动力学方程对PCP在红壤中的吸附过程进行拟合,Elovich方程、双常数方程和一级动力学方程均得到较好的结果,其相关系数(R2)在0.96 ~ 0.99之间,达到极显著水平。Elovich方程反映出PCP在土壤表面吸附的能量非均质分布;而抛物线扩散方程不能描述PCP的吸附过程,其相关系数0.46 ~ 0.48。PCP在土壤中的解吸率与有机质含量和pH值相关,随有机质含量增加,PCP解吸率降低,即黄棕壤表土<黄棕壤底土,红壤表土<红壤底土;随模拟酸雨的pH值降低,土壤因对PCP的吸附能力增加,其解吸率降低。  相似文献   

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