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1.
以青木关岩溶槽谷区内代表性耕地型与林地型洼地小流域为研究对象,从洼地沉积物入手,探明各洼地沉积物剖面~(137)Cs比活度、六六六(HCHs)、有机质、黏粒含量及容重的深度分布特征;运用~(137)Cs示踪法,辅以HCHs进行沉积物断代,追溯流域近60年来的土壤侵蚀量演变特征及探讨其驱动因素。结果表明:(1)炮台院子耕地型洼地沉积物剖面~(137)Cs、HCHs仅有个别层位检出,无法利用~(137)Cs、HCHs深度分布进行沉积物断代,反映了发育的落水洞对其沉积物剖面影响大。(2)龙洞槽耕地型和劳动村林地型洼地小流域1963—1983,1984—2019年产沙模数分别为231.78,82.04 t/(km~2·a)和68.79,39.46 t/(km~2·a),表明流域生态环境得到明显改善。与1963—1983年时段相比,该地区1984—2019年时段年平均降水量无明显变化,2个小流域产沙模数均显著减小,表明近60年流域产沙强度主要受土地利用方式、水土保持措施等人类活动控制。(3)龙洞槽洼地剖面~(137)Cs、HCHs峰值,表层泥沙~(137)Cs、HCHs数值和不同时期流域产沙模数均明显大于劳动村洼地,主要是由2个洼地分别控制的耕地型与林地型小流域在人类活动影响下产沙强度的差异所致。另外,~(137)Cs和HCHs相结合的示踪方法可较好地用于评估西南岩溶流域产沙量的时间变化。  相似文献   

2.
基于~(137)Cs、~(210)Pb和CSLE的三峡库区小流域土壤侵蚀评估   总被引:1,自引:1,他引:0  
综合应用137Cs和210Pb技术和中国土壤流失方程CSLE(Chinese soil loss equation)进行三峡库区腹地工农沟小流域土壤侵蚀的定量评价研究,尝试基于核素示踪技术计算的土壤侵蚀模数评估CSLE在库区林地小流域的估算效果。结果表明:(1)借助210PbexCRS计年模式获得了工农沟塘库沉积柱芯不同质量深度的沉积年代,与137Cs 1963年断代结果相比基本一致,定年结果可靠;(2)基于核素示踪技术(137Cs和210Pb)计算的小流域2002—2014年土壤侵蚀模数为269.09t/(km2·a),侵蚀强度属于微度侵蚀,年土壤侵蚀量为22.87t/a;(3)依据CSLE和考虑沟蚀因子的CSLE估算的小流域2002—2014年土壤侵蚀模数分别为256.07t/(km2·a)和317.53t/(km2·a),年土壤侵蚀量分别为21.77t/a和26.99t/a;(4)与核素计算的结果相比,CSLE和考虑沟蚀因子的CSLE的估算精度均≥80%,说明采用CSLE估算库区林地小流域土壤侵蚀量结果合理。  相似文献   

3.
为查明"三北"防护林建设前后农耕地和退耕地土壤保持效益变化,利用137Cs和210Pbex双核素示踪技术,选择了防护林建设较为成功的张家口坝上地区(风力侵蚀区)作为典型区,研究了农耕地以及退耕地土壤137Cs和210Pbex的剖面变化规律及其示踪的土壤侵蚀变化。结果表明:1)由于耕作的混匀作用,农耕地土壤剖面中137Cs和210Pbex均呈均匀态分布;退耕地土壤剖面中137Cs和210Pbex则表现为表层(0~5cm)浓度最高、下层(5~25cm)浓度均相对较低且分布相对均匀的形态,这表明退耕后坡地土壤137Cs和210Pbex剖面形态均会发生一定变化,退耕驱动土壤137Cs和210Pbex剖面变化导致运用土壤核素估算侵蚀模型在该区域难以适用;2)基于土壤137Cs和210Pbex剖面变化规律,利用210Pbex质量平衡方程,提出了退耕地土壤210Pbex土壤侵蚀估算模型;3)利用137Cs比例模型估算退耕地土壤侵蚀速率为27.94±11.92 (t/hm2·a),农耕地侵蚀速率为29.11±14.42 (t/hm2·a),而利用修正后的210Pbex转换模型估算得到"三北"防护林区退耕地造林前平均侵蚀速率为82.16±14.36 (t/hm2·a),造林后平均侵蚀速率为-41.28±33.91 (t/hm2·a);农耕地造林前平均侵蚀速率为68.55±22.11 (t/hm2·a),造林后平均侵蚀速率-8.52±47.32 (t/hm2·a)。这表明137Cs示踪技术主要表征了1963年以来该区坡地土壤侵蚀和沉积的平均结果,而210Pbex示踪技术则可以较好地示踪防护林建成前后的土壤侵蚀变化。此外,研究结果也表明,相比于"三北"防护林建成之前,建成之后该区农耕地和退耕地的土壤侵蚀速率均呈显著下降趋势,且均由前期的风沙侵蚀转变成了风沙沉积。  相似文献   

4.
用3S技术对重庆忠县石宝寨的菱角塘小流域进行侵蚀单元的划分,通过137 Cs示踪技术配合GIS空间插值法,评估小流域1963年以来的地面侵蚀量;同时,以137 Cs定年法为主要研究手段,确定塘库不同层位的淤积泥沙的年龄,计算1963年以来小流域塘库泥沙淤积量,从而获得小流域以塘库入口为观测断面的泥沙输移比。研究结果表明:(1)不同土地利用类型的土壤侵蚀量差异明显,从1963-2013年这50年间,小流域侵蚀总量为7 240.5t,林地侵蚀总量为2 095t,坡耕地土壤侵蚀总量为5 145.5t,是林地侵蚀总量的2.45倍;(2)用137 Cs定年法进行计算得出小流域塘库淤积总量为1 927.5t,输出库外的泥沙643t;(3)计算菱角塘小流域1963年以来的泥沙输移比为0.36,小流域的低泥沙输移比说明流域内在坡面下方集中分布的水田以及修建的塘库能够很好拦蓄流域上部坡面的侵蚀产沙。  相似文献   

5.
三峡库区小流域修正通用土壤流失方程适用性分析   总被引:4,自引:0,他引:4  
土壤侵蚀量的定量研究可为国家生态环境建设和水土保持宏观决策的制定提供重要的依据。修正通用土壤流失方程(revised universal soil loss equation,RUSLE)是开展土壤侵蚀定量评价的主要手段。该文在地理信息系统(geographic information system,GIS)的支持下,依据中国土壤流失方程各因子的算法确定RUSLE模型各因子值,估算了三峡库区黄冲子小流域不同时期的土壤侵蚀量,并与基于泥沙平衡原理计算的土壤侵蚀量比较后分析RUSLE模型在库区小流域的适用性。结果表明,基于RUSLE模型估算的小流域1963-2000年(农地小流域)和2001-2014年(林地小流域)的年均土壤侵蚀模数分别为2246.09和868.3 t/(km2·a),其结果与采用137Cs和210Pb技术的塘库沉积物定年结果基本吻合,表明210Pb定年结果可靠。依据泥沙平衡原理计算的小流域1963-2000年和2001-2014年的年均土壤侵蚀模数分别为942.48和811.47t/(km2·a)。RUSLE模型估算小流域1963-2000年和2001-2014年的土壤侵蚀模数相对误差分别为138.32%和7.00%。因此RUSLE模型适用于库区林地小流域,而不适用于库区农地小流域;但是基于地形因子(LS因子)修正的RUSLE模型估算结果相对误差减少至8.14%,其适用于库区农地小流域。  相似文献   

6.
近100年喀斯特槽谷区洼地沉积速率与流域产沙强度   总被引:2,自引:1,他引:1  
首次尝试通过沉积物定年反演喀斯特洼地流域单元近100年尺度的侵蚀产沙历史,这有助于认识人类活动对喀斯特石漠化演化过程的影响。以喀斯特槽谷区典型洼地—常家洼洼地为研究对象,应用137Cs、210Pbex定年法分析了近100年的流域产沙强度特征。结果表明:(1)洼地平均沉积速率为1.00cm/a(1917—1963年)和0.25 cm/a(1963—2017年),流域的平均产沙模数为609t/(km^2·a)(1917—1963年)和152t/(km^2·a)(1963—2017年);(2)1917—1963年期间流域产沙强度远高于1963年以后,这与该地区民国至新中国建国初期强烈的人类活动有密切关系,尤其是上世纪50年代末大规模伐木;(3)1963年以来产沙强度明显减小,这是由于此前发生过较强侵蚀导致土壤变少,局部基岩出露,加之此间植被恢复、人类扰动强度降低和水土保持工程实施;(4)常家洼流域产沙强度高于西南其他喀斯特地区,与流域岩性和人为扰动有关。喀斯特石漠化并非仅是近50年人类活动的结果,也与近100年乃至更长时间尺度的人类活动有关。  相似文献   

7.
Purple soils are widely distributed in the Sichuan Hilly Basin and are highly susceptible to erosion, especially on the cultivated slopes. Quantitative assessment of the erosion rates is, however, difficult due to small size of the plots of the manually-tilled land, the complex land use, and steep hillslopes. 137Cs and 210Pbex (excess 210Pb) tracing techniques were used to investigate the spatial pattern of soil erosion rates associated with slope-land under hoe tillage in Neijiang of the Sichuan Hilly Basin. The 137Cs and 210Pbex inventories at the top of the cultivated slope were extremely low, and the highest inventories were found at the bottom of the cultivated slope. By combining the erosion rates estimates provided by both 137Cs and 210Pbex measurements, the weighted mean net soil loss from the study slope was estimated to be 3100 t km-2 year-1, which was significantly less than 6930 t km-2 year-1 reported for runoff plots on a 10°cultivated slope at the Suining Station of soil Erosion. The spatial pattern of soil erosion rates on the steep agricultural land showed that hoe tillage played an important role in soil redistribution along the slope. Also, traditional farming practices had a significant role in reducing soil loss, leading to a lower net erosion rate for the field.  相似文献   

8.
宁镇地区137Cs与210Pbex 坡面分布特征的地统计学分析   总被引:1,自引:0,他引:1  
为更加深入地揭示核素示踪土壤侵蚀的内在机理,在Arcgis Geostatistics模块的支持下,运用地统计学方法研究了宁镇地区137Cs与210Pbex的空间异质性及其坡面分布特征。研究结果表明:(1)核素所特有的理化性质决定了137Cs与210Pbex的空间异质性及其坡面分布格局的与众不同。137Cs与210Pbex较大的块金值说明了土壤侵蚀及耕作活动等随机性因素对其空间分布的决定性影响,这正是它们能够示踪土壤侵蚀的原因所在。(2)137Cs属中等程度的空间自相关,其坡面分布格局能够较好地反映出地形这一结构性因素在其中所施加的影响,示踪土壤侵蚀的结果也应更为全面、合理,并具有宏观性。210Pbex的空间相关性很弱,说明其对随机性因素的影响有着更为敏感的响应,在揭示坡面侵蚀的细部特征方面应能做得更好。(3)137Cs与210Pbex坡面分布格局存在较大的差异,这一方面说明两者在初始沉降布局、部分理化性质,以及对各种变异影响因素的响应等诸多方面还存在着不小的差异;另一方面也在提示,两者示踪土壤侵蚀进程的结果很难通过数学模型的调整而达成一致。  相似文献   

9.
农耕地土壤~(210)Pb_(ex)含量对侵蚀速率变化的响应模型   总被引:1,自引:0,他引:1  
论文在分析了农耕地土壤侵蚀速率改变后土壤中210Pbex含量变化的基础上,检讨了现行的计算农耕地土壤侵蚀速率210Pbex法存在的问题误区。根据质量平衡原理建立了农耕地土壤210Pbex含量对侵蚀速率变化的响应模型,证明长期以来普遍认为的"210Pbex法测定值为100a或200a以来的较长期的平均土壤侵蚀速率"的看法是不正确的。并用模型模拟计算了侵蚀速率变化后农耕地210Pbex含量的响应过程,结果表明农耕地土壤侵蚀速率发生变化后,土壤的210Pbex面积活度迅即响应,随着时间的增加呈指数变化。侵蚀速率增大的,土壤中210Pbex面积活度降低;减小的,210Pbex面积活度增加。210Pbex可以替代137Cs用于农耕地土壤侵蚀速率的测定。210Pbex不但可以测定持续耕种100a以上农耕地的侵蚀速率,也可以用于调查近期土地利用变化的土壤侵蚀响应。  相似文献   

10.
Evaluation of soil erosion in agricultural fields is valuable to develop conservation practices for reducing agricultural nonpoint source pollution.Soil erosion rates were quantified using the fallout radionuclide tracer technique in Mojiagou Basin located on the outskirts of Changchun in Northeast China.The calculated soil erosion rates in the study area were 1.99 and 1.85 mm year-1 using 137Cs and excess 210Pb(210Pbex)measurements,respectively.Both fallout radionuclides showed a similar tendency at downslope sites.All measured sites have experienced net erosion during the past 50 to 100 years.137Cs and 210Pbex measurements were useful to quantify soil erosion rates on field and small basin scales.At this rate of erosion,the current fertile topsoil layer would be entirely removed within 70 years.  相似文献   

11.
In order to assess its potential for estimating soil redistribution rates, the naturally occurring fallout radionuclide 210Pbex has been used in parallel with 137Cs, derived from the atmospheric testing of nuclear weapon testing in the 1950s to 1970s, to estimate rates of soil redistribution on a sloping field with traditional erosion control measures located near Jiajia Village, Jianyang County, in the Sichuan Hilly Basin of China. The local 210Pbex reference inventory of 12,860 Bq m− 2 is higher than those reported for many other areas of the world and may reflect the influence of cloudy weather in preventing 210Pb released to the atmosphere across the local region moving up into the upper troposphere, where is would be more widely dispersed. The mean 210Pbex and 137Cs inventories measured in cores collected from the upper part of the field with an average slope of 10° were 8028 Bq m− 2 and 993 Bq m− 2, respectively, and the equivalent values for the lower part of the field, where the slopes are steeper (20°) were 11,388 Bq m− 2 and 1299 Bq m− 2. The pattern of post-fallout 210Pbex and 137Cs redistribution on the sloping field reflects not only the effects of water erosion and redistribution by tillage, but also the local traditional practice of “Tiaoshamiantu”, whereby sediment trapped in the ditches is returned to the fields by the farmer. The estimates of annual rates of soil loss provided by the 210Pbex measurement are closely comparable with those derived from the 137Cs measurements and are consistent with existing knowledge for the study area. The results obtained from this study confirm the potential for using 210Pbex measurement to estimate soil erosion rates over medium-term timescale of 50–100 years. By combining the estimates of erosion rates provided by the 210Pbex and 137Cs measurements, the weighted mean net soil loss was estimated to be 48.7 t ha− 1 year− 1 from the upper subfield and 16.9 t ha− 1 year− 1 from the lower subfield. These rates are considerably lower than the erosion rates obtained from runoff plot measurements in the local area. It is suggested that the traditional erosion control practices and the practice of “Tiaoshamiantu” have a significant effect in reducing soil loss and conserving valuable cultivated soil on sloping fields in the Sichuan Hilly Basin.  相似文献   

12.
Annual soil losses in southern Italy can exceed 100–150 t ha− 1 year− 1. Where erosion on agricultural land is particularly severe, land use change and afforestation are frequently seen as the most appropriate means of reducing erosion risk. However, the overall effectiveness of afforestation in reducing soil erosion remains uncertain, due to the poor development of the forest cover in some areas, leading to significant areas with sparse tree cover, and the erosional impact of forest harvesting, which commonly involves clearcutting. The study reported here addresses this uncertainty and focuses on two small catchments (W2 and W3) located in Calabria, southern Italy, for which measurements of suspended sediment yield are available. Both the catchments originally supported a rangeland vegetation cover and they were planted with eucalyptus trees in 1968. Currently, only catchment W3 supports a continuous forest cover. In catchment W2 the forest cover is discontinuous and there is a significant area of the catchment (ca. 20%) where the tree cover is sparse and the vegetation cover is dominated by natural grasses. Two additional erosion plots were established within catchment W2 in 1991, in order to explore the effect of the density of the tree cover on soil erosion. Information on the sediment yields from the two catchments and the plots for 10 storm events that occurred during the period December 2005–December 2006 and associated information on the 137Cs and excess 210Pb of the sediment, have been used to investigate the effectiveness of afforestation in reducing sediment mobilisation and net soil loss from the catchments involved. The results demonstrate that the areas of greatest soil loss are associated with the slopes where the tree cover is discontinuous, and that forest harvesting by clearcutting causes significant short-term increases in sediment mobilisation and sediment yield. These findings, which are consistent with previous work undertaken within the same area, emphasize the importance of vegetation cover density in influencing rates of soil loss in the study catchments. The study also provided a useful demonstration of the potential for using measurements of the 137Cs and 210Pbex content of sediment, in combination with more traditional sediment monitoring, to investigate sediment sources and to compare the sediment dynamics of catchments subjected to different land management practices.  相似文献   

13.

Purpose

Approximately 74 % of agricultural soils in Tunisia are affected by water erosion, leading to the siltation of numerous human-made reservoirs and therefore a loss of water storage capacity. The objective of this study was to propose a methodology for estimating the relative contributions of gully/channel bank erosion and surface topsoil erosion to the sediment accumulated in small reservoirs.

Materials and methods

We tested an approach based on the sediment fingerprinting technique for sediments collected from a reservoir (which has been in operation since 1994) at the outlet of a catchment (Kamech, 2.63 km2). Sampling concentrated on the soil surface (in both cropland and grassland), gullies and channel banks. A total of 17 sediment cores were collected along a longitudinal transect of the Kamech reservoir to investigate the origin of the sediment throughout the reservoir. Radionuclides (particularly caesium-137, 137Cs) and nutrients (total phosphorus, total nitrogen and total organic carbon (TOC)) were analysed as potential tracers.

Results and discussion

The applications of a mixing model with 137Cs alone or 137Cs and TOC provided very similar results: The dominant source of sediment was surface erosion, which was responsible for 80 % of the total erosion within the Kamech catchment. Additionally, we showed that the analysis of a single composite core provided information on the sediment origin that was consistent with the analysis of all sediment layers in the core. We demonstrated the importance of the core sampling location within the reservoir for obtaining reliable information regarding sediment sources and the dominant erosion processes.

Conclusions

The dominance of surface erosion processes indicates that conservation farming practices are required to mitigate erosion in the agricultural Kamech catchment. Based on the results from 17 sediment cores, guidelines regarding the number and location of sampling cores to be collected for sediment fingerprinting are proposed. We showed that the collection of two cores limited the sediment source apportionment uncertainty due to the core sampling scheme to <10 %.  相似文献   

14.

Purpose

The science of sediment fingerprinting has been evolving rapidly over the past decade and is well poised to improve our understanding, not only of sediment sources, but also the routing of sediment through watersheds. Here, we discuss channel–floodplain processes that may convolute or modify the sediment fingerprinting signature of alluvial bank/floodplain sources and explore the use of nonconservative tracers for differentiating sediment derived from surface soil erosion from that of near-channel fluvial erosion.

Materials and methods

We use a mathematical model to demonstrate the theoretical effects of channel–floodplain exchange on conservative and nonconservative tracers. Then, we present flow, sediment gauging data, and geochemical measurements of long- (meteoric beryllium-10, 10Be) and short-lived (excess lead-210 and cesium-137, 210Pbex and 137Cs, respectively) radionuclide tracers from two study locations: one above, and the other below, a rapidly incising knick zone within the Maple River watershed, southern Minnesota.

Results and discussion

We demonstrate that measurements of 10Be, 210Pbex, and 137Cs associated with suspended sediment can be used to distinguish between the three primary sediment sources (agricultural uplands, bluffs, and banks) and estimate channel–floodplain exchange. We observe how the sediment sources systematically vary by location and change over the course of a single storm hydrograph. While sediment dynamics for any given event are not necessarily indicative of longer-term trends, the results are consistent with our geomorphic understanding of the system and longer-term observations of sediment dynamics. We advocate for future sediment fingerprinting studies to develop a geomorphic rationale to explain the distribution of the fingerprinting properties for any given study area, with the intent of developing a more generalizable, process-based fingerprinting approach.

Conclusions

We show that measurements of conservative and nonconservative tracers (e.g., long- and short-lived radionuclides) can provide spatially integrated, yet temporally discrete, insights to constrain sediment sources and channel–floodplain exchange at the river network-scale. Fingerprinting that utilizes nonconservative tracers requires that the nonconservative behavior is predictable and verifiable.  相似文献   

15.
Analysis of sediment sources is an important component in the development of catchment sediment budgets and in determining links between erosion from sources and sediment delivery to catchment outlets. In this study 137Cs and 210Pbex were used to determine surface and sub-surface source contributions of fine sediment in a small upland headwater catchment (1.6 km2) in south-eastern Australia. The findings from this analysis are employed in an adjustment procedure to better differentiate sediment source erosion processes by utilising channel survey and erosion pin data. This improved the precision of estimates of sediment-source erosion-process contributions from hillslopes and channel/gully walls. A mean of 74% of in-channel deposits and suspended sediment exiting the study catchment was derived from sub-surface sources and when adjusted for erosion process this increased to 81%, which may be attributed to channel and gully wall erosion alone. Net erosion of the channel floor was low and constitutes only a small part of the total channel source input to sediment flux. Variability in sediment source contributions within the catchment was high, with rapid transition from hillslope to channel source dominance of sediment flux with distance downstream in the study catchment.  相似文献   

16.
Sediment budgets have been established for two small (<4 km2), lowland, agricultural catchments, by using 137Cs measurements, sediment source fingerprinting and more traditional monitoring techniques to quantify the individual components of the budget. The gross and net erosion rates for the fields on the catchment slopes were estimated using 137Cs measurements within selected fields, which encompassed a representative range of slope angles, slope lengths and land use. These estimates were extrapolated over the entire catchment, using a simple topographically driven soil erosion model (Terrain-Based GIS, TBGIS) superimposed on a DEM, to derive catchment average gross and net erosion rates. Suspended sediment yields were measured at the catchment outlets and sediment source fingerprinting techniques were used to establish the relative contributions from the catchment surface, subsurface tile drains and eroding channel banks to the sediment yields. In-channel and wetland storage were quantified using both direct measurements and 137Cs measurements. The sediment budgets established for the catchments highlighted the importance of subsurface tile drains as a pathway for sediment transfer, accounting for ca. 60% and 30% of the sediment output from the two catchments. Erosion from channel banks contributed ca. 10% and 6% of the sediment output from the two catchments. Although the suspended sediment yields from these catchments were considered high by UK standards (ca. 90 t km−2 year−1), the sediment delivery ratios ranged between 14% and 27%, indicating that a major proportion of the mobilised sediment was stored within the catchments. In-field and field-to-channel storage were shown to be of similar magnitude, but storage of sediment in the channel system and associated wetlands was relatively small, representing <5% of the annual suspended sediment yield.  相似文献   

17.
Intensive farming is a primary cause of increased sediment and associated nitrogen (N) and phosphorus (P) loads in surface water systems. Determining their contributing sources, pathways and loads present major challenges in the high-intensity agricultural catchments. Herein, we quantify the sediment sources and magnitude of sediment total N and total P from different sources using a novel application of compound-specific stable isotope (CSSI) and fallout radionuclides (FRNs) of 137Cs and 210Pbex in an intensive agricultural catchment in North China. Sediment sources from surface and sub-surface soils were estimated from FRNs fingerprint and accounted for 62 ± 7% and 38 ± 7% respectively, while surface soil from land uses that originated from hillslope were identified by CSSI fingerprint. Using a novel application of FRNs and CSSI sediment fingerprinting techniques, the dominant sediment source was derived from maize farmland (44 ± 0.1%), followed by channel bank (38 ± 7%). The sedimentation rate (13.55 ± 0.30 t ha−1 yr−1) was quantified by the 137Cs cores (0–60 cm) at the outlet of this catchment. The total N and total P in sediment were both mostly derived from maize farmland and least from channel banks. The channel banks are significant sediment sources but contribute little to the input of sediment N and P for eutrophication. It implies that chemically-applied farmlands are the main hotspots for catchment erosion control and pollution prevention. The novel application of FRNs and CSSI techniques cost-effectively quantified sediment N and P loads from different sources with a single visit to the catchment, enabling rapid assessment for optimizing soil conservation strategies and land management practices. Keywords: Sediment sources, Land use, N and P loads, Compound-specific stable isotope, Fallout radionuclides.  相似文献   

18.
In industrial areas, heavy metals may accumulate in forest soil organic horizons, affecting soil microorganisms and causing changes in the chemical composition of the accumulated organic matter. The objectives of this study were to test the ability of near-infrared spectroscopy (NIRS) to detect heavy metal effects on the chemical composition of forest soil O horizons and to test whether NIRS may be used to quantitatively determine total and exchangeable concentrations of Zn and Pb (Znt, Pbt, Znex, Pbex) and other chemical and microbial properties in forest soil O horizons polluted with heavy metals. The samples of O horizons (n = 79) were analyzed for organic C (Corg), total N and S (Nt, St), Znt, Pbt, Znex, Pbex, basal respiration (BR), microbial biomass (Cmic) and Cmic-to-Corg ratio. Spectra of the samples were recorded in the Vis-NIR range (400–2,500 nm). To detect heavy-metal-induced changes in the chemical composition of O horizons principal components (PC1–PC7) based on the spectral data were regressed against Znt + Pbt values. A modified partial least squares method was used to develop calibration models for prediction of various chemical and microbial properties of the samples from their spectra. Regression analysis revealed a significant relationship between PC3 and PC5 (r = −0.27 and −0.34, respectively) and Znt + Pbt values, indicating an effect of heavy metal pollution on the spectral properties of the O horizons and thus on their chemical composition. For quantitative estimations, the best calibration model was obtained for Corg-to-Nt ratio (r = 0.98). The models for Corg, Nt, and microbial properties were satisfactory but less accurate. NIRS failed to accurately predict St, Corg-to-St, Znt, Pbt, Znex, and Pbex.  相似文献   

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