有机肥对设施土壤硝态氮垂直分布的影响

以辽宁省新民市某设施蔬菜大棚为研究对象,研究在保护地栽培条件下不同有机肥施用量对不同施肥年限的设施土壤(0~120 cm土层)硝态氮累积和淋溶的影响。结果表明,土壤硝态氮的垂直分布与土壤的施肥年限和有机肥施用水平密切相关。在不同施肥处理条件下,施肥1年后各处理土壤剖面硝态氮累积和淋溶程度均很低;施肥2年后硝态氮累积迁移显著,尤其是高量有机肥的投入(处理M4),设施土壤0~120 cm土层都出现硝态氮淋洗现象。在不同施肥年限下,中高量有机肥处理都存在不同程度的硝态氮累积现象,硝态氮累积量随施肥量和施肥年限的增加而增加,随土壤深度的增加而降低,累积峰值集中在0~60 cm土层。     

应用Geoprobe对河北栾城土壤硝态氮含量进行计算

利用Geoprobe对土壤剖面取样,分析并计算了0~20.4m土层硝态氮的累积量,研究表明,施肥量的上升和地下水埋深的下降,使得多余的氮肥以硝态氮的形式存储在土壤剖面中,在传统的施肥制度下,0~20.4m剖面总累积的硝态氮量为1769kg hm-2,自地表至下,土壤硝态氮的分布存在三个累积层,分别为0~5.4m,7.2~12m,14.7~18.4m;而且三个层次累积的硝态氮量随深度呈递减的趋势。     

不同栽培模式及施氮对玉米-小麦轮作体系土壤肥力及硝态氮累积的影响

以在陕西关中土垫旱耕人为土区进行的连续6年定位试验为对象,研究了长期覆盖栽培及施氮量对玉米?小麦轮作体系下土壤有机质、全氮及土壤剖面硝态氮残留量和分布的影响。结果表明,不同栽培模式对土壤有机质和全氮含量的影响为覆草垄沟常规节水,其中覆草模式影响达显著水平。增施氮肥不同程度地提高了土壤有机质和全氮含量。经过12季玉米-小麦的轮作,不同栽培模式0～200cm土壤剖面硝态氮残留量为垄沟节水覆草常规,垄沟和节水栽培模式与常规栽培硝态氮累积量差异达显著水平。随种植年限和施氮量增加,0～200cm土壤中硝态氮累积量明显增加,施240kg·hm-2N(N240)处理0～200cm土壤硝态氮累积量显著高于施120kg·hm-2N(N120)处理。不同施氮量下硝态氮在0～200cm土壤剖面的分布存在差异,与不施氮(N0)和N120处理相比,N240处理下各栽培模式在120cm以下的土壤硝态氮含量随深度增加而显著增加。     

集约化种植条件下土壤硝态氮动态变化及累积特征研究

选取江阴市沿江平原地区的3种典型农业种植区,即大棚葡萄集约化种植基地、蔬菜集约化种植基地和常规种植农田为研究对象,通过田间现场采样分析的方法研究了不同种植方式下土壤剖面硝态氮含量的动态变化和累积特征.结果表明,葡萄种植基地0-100 cm各土层硝态氮含量随时间的变化波动较大,而蔬菜种植基地和常规种植农田的表层土壤硝态氮含量变化幅度大于深层土壤;3种典型种植区的土壤硝态氮含量均呈现随着土层深度的增加而逐渐减小的趋势,其中土壤硝态氮含量最大值出现在葡萄种植基地的20-40 cm土层中;葡萄种植基地各土层硝态氮平均累积量均高于蔬菜种植基地和常规种植农田,大棚葡萄集约化种植基地0-00 cm土层硝态氮平均累积总量高达400.96 kg/hm2,显著高于蔬菜集约化种植基地和常规种植农田的累积总量,这进一步表明不合理过量追肥导致土壤中硝态氮大量累积,增大了氮素淋失和地下水环境污染的风险.     

降雨对不同土地利用类型土壤水氮变化特征的影响

以2018年6—10月降雨条件下园地、林地、荒草地、坡耕地和裸地的标准径流小区为研究对象,裸地为对照,通过研究降雨对园地、林地、荒草地、坡耕地和裸地的土壤含水率、总氮、硝态氮和铵态氮含量与土层深度和时间的变化特征,经野外试验数据统计分析,提出降雨对园地、林地、荒草地、坡耕地和裸地土壤含水率、总氮、硝态氮和铵态氮含量与土层深度和时间变化特征的影响。结果表明:降雨增加园地、林地、荒草地、坡耕地和裸地土壤含水率,加速土壤总氮、硝态氮和铵态氮水解转化硝化和反硝化速度,影响土壤含水率、总氮、硝态氮和铵态氮含量,降雨与土壤含水率、总氮、硝态氮、铵态氮呈显著相关性(P0.05)。降雨条件下园地、林地、荒草地、坡耕地和裸地的土壤含水率随土层深度增大而增大,土层深度100 cm处土壤含水率最大,分别为30.34%,27.67%,24.98%,24.03%和21.95%,总氮随土层深度增大呈先增大后减小,在土层深度为60 cm土壤总氮含量最大,分别为1.02,0.99,0.90,0.86,0.75 g/kg,硝态氮和铵态氮含量随土层深度增大而减小,在土层深度为100 cm硝态氮和铵态氮含量均最小,其中硝态氮含量分别为9.01,7.89,7.25,6.10,5.22 mg/kg,铵态氮含量分别为9.41,9.14,6.40,5.38,4.37 mg/kg。土壤含水率随时间的延长先减小后增大又减小,呈正余弦变化趋势,8月土壤含水率最大,分别为22.97%,22.01%,19.87%,19.03%和17.98%,总氮随时间的延长先增大后减小,8月总氮最大,分别为1.09,1.01,0.94,0.84,0.76 g/kg,硝态氮和铵态氮含量随时间的延长而逐渐减少,6月硝态氮和铵态氮含量均最大,其中硝态氮含量分别为13.40,12.37,11.20,10.39,8.67 mg/kg,铵态氮含量分别为18.89,17.02,14.54,12.02,8.36 mg/kg。不同土地利用类型土壤含水率、总氮、硝态氮和铵态氮平均值与土层深度和时间关系由大到小依次为园地、林地、荒草地、坡耕地和裸地,研究结果为农田土壤水肥流失控制和养分利用提供理论技术支持。     

滴灌水肥一体化条件下番茄氮肥适宜用量探讨

利用田间小区7年定位试验,研究了滴灌水肥一体化条件下,不同化肥施氮量结合基施有机肥对番茄产量、品质、硝态氮累积、土壤电导率及土壤p H值的影响。结果表明:1)与不施氮相比,施肥可显著提高番茄产量,但过量施肥不仅不会提高番茄产量,还会降低番茄品质; 2)施氮量对土壤硝态氮的累积有较大的影响,随施氮量的增加,土壤剖面硝态氮累积量增加,其中对0～20 cm土层硝态氮累积量的影响最为显著; 3)土壤硝态氮含量与土壤电导率呈极显著相关关系,表明施氮量越高,电导率随之增加越显著,土壤的次生盐渍化风险越高; 4)除CK处理外,其它处理土壤硝态氮含量与p H值呈极显著负相关关系。综合考虑产量、品质与土壤环境质量,推荐华北温室秋冬茬番茄施用200 kg/hm~2有机N+250 kg/hm~2无机N,P2O575 kg/hm~2,K2O 450 kg/hm~2为宜。     

水肥耦合条件下保护地土壤硝态氮动态变化

采用二因素三水平完全设计,通过保护地低压节点渗灌番茄小区栽培试验,研究了灌溉上限和施肥量组合处理在灌溉追肥后第1、2、35、、7 d不同土层土壤硝态氮的动态变化。结果表明,较低灌溉上限,施肥量对不同时间土壤硝态氮影响不明显;提高灌溉上限,施肥量增加影响土壤剖面分异。灌溉上限和肥料对土壤硝态氮累积量的影响除第一天外均达到5%显著水平,作用由大到小分别为肥料,水分,水肥交互作用。不同采样时间0～20 cm土层硝态氮累积百分比平均在50%以上,低灌溉上限和高施肥量组合的硝态氮累积百分比最大,高灌溉上限和高施肥量组合硝态氮累积百分比最小。     

氮肥施用对黄土高原中部雨养农业区土壤硝态氮分布与累积的影响

黄土高原中部雨养农业区春小麦氮肥试验表明,氮肥施用量对土壤硝态氮的移动深度没有影响,但显著影响土壤硝态氮的含量与累积。连续施氮3年后第3季春小麦收获时,0～200cm土壤剖面中累积大量的硝态氮,其中48.96%～81.38%的总累积量和60.49%～122%的当年净累积量存在于0～110cm土层中。在确定春小麦适宜施氮量时应考虑到0～110cm土层中残留硝态氮的累积量。不施氮和氮磷比例为1:1时,连续施氮三年后土壤硝态氮总累积量最低,数量几乎相等;第3季春小麦收获后较播种时,土壤硝态氮发生亏缺。施氮量为52.5 kgN hm-2时土壤硝态氮的三年总累积率和第3季春小麦当年的净累积率居各处理之首(146.55%和138.21%)。合理的氮磷配比可有效减少土壤硝态氮的累积,不合理的氮磷配比下,低施氮量也会造成土壤硝态氮的大量累积。     

3种豆科作物与玉米间作对土壤硝态氮累积和分布的影响

为提高氮肥利用效率,减少过量施用氮肥对环境造成的污染,本文以甘肃省河西灌区为试验地点,在0和225kg（N）·hm^-2氮水平下,探讨了蚕豆、豌豆、大豆3种豆科作物与玉米间作对土壤硝态氮累积和分布的影响。研究表明：蚕宜收获后,间作的蚕豆、大豆、豌豆和玉米土壤硝态氮累积量在两个氮水平下均低于相应的单作,蚕豆、大豆、豌豆的间作土壤剖面硝态氮含量也低于相应的单作,但表现的土层深度各异。玉米收获后,蚕豆和豌豆的间作土壤硝态氮累积量低于单作;不施氮条件下,大豆间作土壤硝态氮累积量低于单作,与蚕豆、豌豆和大豆间作的玉米土壤硝态氮累积量均高于单作玉米;在225kg（N）·hm^-2氮水平下,与蚕豆和豌豆阔作的玉米土壤硝态氮累积量低于单作玉米,间作大豆和与大豆间作的玉米土壤硝态氮累积量高于相应的单作。玉米收获期,不施氮条件下3种豆科作物间作0～60cm土壤硝态氮含量均低于单作;225kg（N）·hm^-2氮水平下,蚕豆、豌豆间作0～60cm土壤硝态氮含量低于单作,而间作大豆0～100cm土壤硝态氮含量高于单作。对不同深度土壤硝态氮相对累积量分析表明,蚕豆收获期间作0～60cm土层相对累积量高于单作,而100～180cm土层则低于单作。     

旱作地区长期小麦连作和苜蓿连作土壤剖面的矿质氮研究

对不同施肥条件下23年小麦连作地和苜蓿连作地土壤矿质氮分布和累积进行研究,探讨种植浅根系和深根系植物对硝态氮淋溶的影响。结果表明,不施肥(CK)和单施磷(P)肥,小麦和苜蓿连作地土壤硝态氮主要集中在0—60 cm土层,0—60 cm土层以下硝态氮含量变化稳定并小于2 mg/kg。氮肥、磷肥和有机肥配施(NPM)时,小麦连作地土壤硝态氮累积在20—100 cm和140—320 cm土层,年累积速率可达42.12 kg/(hm2.a);苜蓿连作土壤硝态氮主要集中在0—60 cm土层,仅在200—300 cm土层出现轻微累积,年累积速率仅为1.01 kg/(hm2.a)。在不施肥和单施磷肥下,种植小麦或苜蓿对土壤硝态氮残留量影响不显著,而氮、磷和有机肥配施时,小麦连作地土壤硝态氮残留量迅速增加,并与不施肥、单施磷肥处理有显著差异;苜蓿连作地土壤硝态氮残留量虽有少量增加,但与不施肥、单施磷肥处理无显著差异。不施肥、单施磷肥和氮、磷和有机肥配施,小麦连作、苜蓿连作地土壤剖面铵态氮含量主要在10—20 mg/kg之间波动,在土壤剖面无明显的累积现象,铵态氮残留量受施肥和作物种类的影响不显著。     

Nitrification Inhibition in Iowa Soils Treated with Stay‐N 2000 as Affected by Temperature and Matric Potential

The effects of temperature and water potential on nitrification were investigated in two Iowa soils treated with Stay‐N 2000. The soils were incubated at 10, 20, and 30 °C after soil water potentials of ?1, ?10, or ?60 kPa were applied to each soil. A first‐order equation was used to calculate the maximum nitrification rate (K _max), duration of lag period (t′), period of maximum nitrification (Δt), and termination period of nitrification (t _s). The highest K _max were 18 and 24 mg kg^?1 d^?1 nitrate (NO₃ ^?)–nitrogen (N), respectively, at 30 °C and ?10 kPa in both the Nicollet (fine‐loamy, mixed, superactive, mesic Aquic Hapludoll) and Canisteo (fine‐loamy, mixed, superactive, calcareous, mesic Typic Endoaquoll) soils and reduced to 4 and 16 mg kg^?1 d^?1 NO₃ ^?‐N when Stay‐N 2000 was added. The extension of t′ due to the addition of Stay‐N 2000 was as high as 7 d in the Nicollet soil at 10 °C and ?1 kPa and as little as 2 d in the Canisteo soil at 20 °C and ?10 kPa.     

Kinetics of Nitrification in Selected Iowa Soils Treated with Stay‐N 2000

Abstract

The effectiveness of Stay‐N 2000 or reformulated nitrapyrin [2‐chloro‐6‐(tricholoromethyl) pyridine] was investigated in two Iowa soils representative of Clarion and Okoboji soils that differed in organic carbon, pH, and texture. A nonlinear regression was used to estimate kinetic parameters. The maximum nitrification rate (K _max) and the duration of lag period (t′) were derived from the equation to characterize the nitrification process in both soils. Stay‐N 2000 appeared to be a better inhibitor than nitrapyrin to extend t′ and as effective as nitrapyrin in reducing K _max. Stay‐N 2000 reduced K _max an appreciable amount in the Okoboji soil at the rate of 12 µg a.i. g^?1 soil or three times the recommended rate. Nitrification rates were affected by the rates of nitrogen (N) applied to both soils; the higher the N rates, the higher K_max, and the more the nitrate (NO₃ ^?)‐N accumulation.     

Low soil C:N ratio results in accumulation and leaching of nitrite and nitrate in agricultural soils under heavy rainfall

Nitrate (NO₃^-) and nitrite (NO₂^-) leaching threatens groundwater quality. Soil C:N ratio, i.e., the ratio of soil organic carbon to total nitrogen, affects mineralization, nitrification, and denitrification; however, its mechanism for driving soil NO₃^-and NO₂^-accumulation and leaching remains unclear. Here, a field investigation in a fluvo-aquic soil and a soil column experiment were performed to explore the relationships between soil C:N ratio and soil NO₃^-and NO₂^-leaching in three soil layers (0-20, 20-40, and 40-60 cm) under heavy rainfall (rainfall rate > 25 mm d^-1). The field investigation results showed that both soil NO₃^--N and NO₂^--N contents decreased exponentially (P < 0.001) with increasing soil C:N ratio in each soil layer. Furthermore, negative exponential relationships (P < 0.001) were found between soil C:N ratio and both NO₃^--N and NO₂^--N concentrations in soil solution in each soil layer under heavy rainfall. The soil column divided into three layers was leached with simulated heavy rainfall; the results confirmed negative exponential relationships (P < 0.05) between soil C:N ratio and both NO₃^--N and NO₂^--N concentrations in the leachate from each soil layer. A total of 18 soil samples obtained from three depths at six field sites during the rainy season were used to elucidate the microbial mechanisms induced by soil C:N ratio using high-throughput sequencing and real-time polymerase chain reaction. High abundances of ammonifying bacteria (Flavobacterium, Bacillu, and Pseudomonas), ammonia-oxidizing bacteria (Nitrosospira), and nirS/K gene were observed when soil C:N was low, concomitant with low abundances of NO₂^--oxidizing bacteria (Nitrospira) and narG gene. Partial least squares path modeling showed that the high NO₃^-and NO₂^-levels at low soil C:N ratio might be attributed to the inhibition of NO₃^-reduction (i.e., low narG gene) and NO₂^-oxidation (i.e., low Nitrospira) and thus the accumulation of soil NO₃^-and NO₂^-, respectively. Therefore, the leaching of NO₂^-and NO₃^-in low C:N soils requires more attention during the rainy season.     

华北山前平原典型厚包气带硝态氮分布累积规律

包气带是连接大气层和含水层水分和养分转换的纽带,也是农田NO_3~–-N分布和累积的重要场所和向含水层淋失的通道,因此研究包气带土壤中NO_3~–-N的分布累积规律对防止地下水NO_3~–-N污染至关重要。本文以中国科学院栾城试验站典型的厚包气带为对象,在无施肥处理(N0)和施氮肥600 kg/(hm~2·a)(N600)两种处理的多年试验田中,利用Geoprobe获取0~10.5 m深度土壤样品,研究厚包气带NO_3~–-N垂向分布、累积规律,并分析其影响因素。结果表明:N0中NO_3~–-N基本保持不变,长年施氮肥600 kg/(hm~2·a)使得NO_3~–-N淋溶至10.5 m,并在深层包气带中形成累积,累积的峰值由土壤的质地和含水量决定;NO_3~–-N的分布和累积主要受水分运移、土壤质地和反硝化作用影响。     

Equations to calculate the approximate duration and termination of the maximal rate phase of nitrification in soil

Abstract

Nitrification in soil is characterized by a sigmoidal curve with a delay, maximum rate and retarded phase. A model based on the Verhulst equation describes all three phases of the nitrification process excellent. Equations to calculate the maximum nitrification rate (K_mx) and the delay period (t') exist already. Equations to calculate the approximate duration (?t) and termination (t_s) of the maximal rate phase were also derived from the Verhulst equation and are reported. The duration of maximal nitrification when NH₄ ⁺ is oxidized at a maximal rate is the period from the end of the delay period until the retarded phase starts. The termination of the maximal rate phase gives an approximate time of when the retarded phase, due to a depletion of HH₄ ⁺, starts. At this stage in the nitrification process additional NH₄ ⁺ must be applied to prevent the minimum changes in the maximum nitrification rate of a soil. When first‐order kinetics is used, the course of nitrification can in future consequently be described quantitatively by four parameters K_mx, t’, ?t and t_s. Similar parameters can also be calculated from experimental data of other biological reactions which are characterized by sigmoidal curves.     

好氧条件下两种水稻土的氮素总转化速率比较

Although to date individual gross N transformations could be quantified by ~(15)N tracing method and models,studies are still limited in paddy soil.An incubation experiment was conducted using topsoil(0-20 cm) and subsoil(20-60 cm) of two paddy soils,alkaline and clay(AC) soil and neutral and silt loam(NSL) soil,to investigate gross N transformation rates.Soil samples were labeled with either ~(15)NH4_NO_3 or NH_4~(15)NO_3,and then incubated at 25 °C for 168 h at 60%water-holding capacity.The gross N mineralization(recalcitrant and labile organic N mineralization) rates in AC soil were 1.6 to 3.3 times higher than that in NSL soil,and the gross N nitrification(autotrophic and heterotrophic nitrification) rates in AC soil were 2.4 to 4.4 times higher than those in NSL soil.Although gross NO_3~- consumption(i.e.,NO_3~- immobilization and dissimilatory NO_3~- reduction to NH_4~+ rates increased with increasing gross nitrification rates,the measured net nitrification rate in AC soil was approximately 2.0 to 5.1 times higher than that in NSL soil.These showed that high NO_3~- production capacity of alkaline paddy soil should be a cause for concern because an accumulation of NO_3~- can increase the risk of NO_3~- loss through leaching and denitrification.     

DCD 在不同质地土壤上的硝化抑制效果和剂量效应研究

通过硝化抑制剂抑制土壤硝化作用是实现作物铵硝混合营养和提高氮肥利用率的重要途径之一。本试验采用室内模拟的方法, 在人工气候室(25 ℃)黑暗培养条件下, 应用新疆石灰性土壤研究了不同剂量的双氰胺(dicyandiamide, DCD)在砂土、壤土、黏土3 种不同质地土壤中对土壤硝态氮、铵态氮转化的影响及DCD 的剂量效应和硝化抑制效果。处理30 d 内, 各剂量DCD 处理对砂土的硝化抑制率为96.5%~99.4%(平均值为98.3%), 在黏土上为66.9%~85.6%(平均值为77.6%), 在壤土上为49.3%~79.4%(平均值为67.7%), 总体硝化抑制率表现为砂土>黏土>壤土。在砂土上DCD 的剂量效应不明显, DCD 用量从纯氮的1.0%增加到7.0%时, 土壤中硝态氮含量仅增加1.9~10.7 mg·kg^-1(培养30 d 时); 而在壤土和黏土中, 土壤硝态氮含量随DCD 浓度的增加而显著下降, 存在明显剂量效应。这说明施用DCD 可显著抑制新疆石灰性土壤的硝化作用过程, 在砂土、壤土、黏土中DCD 的最佳浓度分别为纯氮用量的6.0%、7.0%和7.0%, 并在培养30 d 内发挥显著作用。     

Importance of heterotrophic nitrification and dissimilatory nitrate reduction to ammonium in a cropland soil: Evidences from a 15N tracing study to literature synthesis

Future climate change is predicted to influence soil moisture regime, a key factor regulating soil nitrogen (N) cycling. To elucidate how soil moisture affects gross N transformation in a cultivated black soil, a ¹⁵N tracing study was conducted at 30%, 50% and 70% water-filled pore space (WFPS). While gross mineralization rate of recalcitrant organic N (N_rec) increased from 0.56 to 2.47 mg N kg⁻¹ d⁻¹, the rate of labile organic N mineralization declined from 4.23 to 2.41 mg N kg⁻¹ d⁻¹ with a WFPS increase from 30% to 70%. Similar to total mineralization, no distinct moisture effect was found on total immobilization of ammonium, which primarily entered the N_rec pool. Nitrate (NO₃⁻) was mainly produced via autotrophic nitrification, which was significantly stimulated by increasing WFPS. Unexpectedly, heterotrophic nitrification was observed, with the highest rate of 1.06 mg N kg⁻¹ d⁻¹ at 30% WFPS, contributing 31.8% to total NO₃⁻ production, and decreased with WFPS. Dissimilatory nitrate reduction to ammonium (DNRA) increased from near zero (30% WFPS) to 0.26 mg N kg⁻¹ d⁻¹ (70% WFPS), amounting to 16.7–92.9% of NO₃⁻ consumption. A literature synthetic analysis from global multiple ecosystems showed that the rates of heterotrophic nitrification and DNRA in test soil were comparative to the forest and grassland ecosystems, and that heterotrophic nitrification was positively correlated with precipitation, soil organic carbon (SOC) and C/N, but negatively with pH and bulk density, while DNRA showed positive relationships with precipitation, clay, SOC, C/NO₃⁻ and WFPS. We suggested that low pH and bulk density and high SOC and C/N in test soil might favor heterotrophic nitrification, and that C and NO₃⁻ availability together with anaerobic condition were crucial for DNRA. Overall, our study highlights the role of moisture in regulating gross N turnover and the importance of heterotrophic nitrification for NO₃⁻ production under low moisture and DNRA for NO₃⁻ retention under high moisture in cropland.     

氮施用量对夏玉米土壤水氮动态及水肥利用效率的影响

采用田间小区试验,监测夏玉米不同生长期土壤水分和硝态氮剖面含量变化,研究不同施氮量对其时空变化及籽粒产量、水肥利用效率的影响,探讨氮肥对水肥资源高效利用的调节作用。结果表明：不同施氮处理,土壤剖面水分和硝态氮随土壤深度的变化趋势基本一致,即表层50 cm土壤水分和硝态氮含量较高且呈降低态,50-110 cm相对较低且波动较小,灌浆期二者均达到最低值;各生长期表层50 cm土壤含水量呈不施氮处理均高于施氮处理,50-110 cm土层则相反;施氮能提高土壤硝态氮含量,土壤硝态氮运移受土壤水分状况和含量的影响,含量越高,向下移动越深;施氮能显著提高水分利用效率及籽粒产量,增产效果明显（增产28.52%-37.86%）,二者均以施氮240 kg/hm^2处理最高;随施氮量的增加籽粒产量及籽粒吸氮量和水分利用效率增幅均表现为先升高后降低之趋势,当施氮量超过240 kg/hm^2后,籽粒产量和水分利用效率提高并不显著;不施氮与施氮处理氮素生产力、氮肥利用率之间均存在极显著差异。在本试验条件下,从控制土壤硝态氮积累及取得较高的产量和氮素利用率综合考虑,夏玉米的适宜施氮量范围应控制在120-240 kg/hm^2较好。     

Heavy‐Metal Inhibition of Nitrification in Selected Iowa Soils Treated with Stay‐N 2000

Abstract

Heavy‐metal inhibition of nitrification in soils treated with reformulated nitrapyrin was investigated. Clarion and Okoboji soils were treated with ammonium sulfate [(NH₄)₂SO₄] and a nitrification inhibitor. Copper(II) (Cu), Zinc(II) (Zn), Cadmium(II) (Cd), or Lead(II) (Pb) were added to each soil. A first‐order equation was used to calculate the maximum nitrification rate (K _max), duration of lag period (t′), period of maximum nitrification (Δt), and the termination period of nitrification (t _s). In the Clarion soil, the K _max decreased from 12 mg kg^?1 d^?1 without the nitrification inhibitor to 4, 0.25, 0.86, and 0.27 mg kg^?1 d^?1, respectively, when the inhibitor and Cu, Zn, Pb, or Cd were applied. In the Okoboji soil, K _max decreased from 22 mg kg^?1 d^?1 with no inhibitor to 6, 3, 4, and 2 mg kg^?1 d^?1, respectively, when an inhibitor and Cu, Zn, Pb, or Cd were added. The t′ varied from 8 to 25 d in the Clarion soil and from 5 to 25 d in the Okoboji soil, due to addition of Cu, Zn, Pb, or Cd and the inhibitor.