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1.
水稻子实对不同形态重金属的累积差异及其影响因素分析   总被引:3,自引:0,他引:3  
在分析成都平原核心区土壤重金属(Cd、Cr、Pb、Cu、Zn)全量、各形态含量及相应点位种植的水稻子实重金属含量的基础上,通过统计分析、空间插值及线性回归方程的模拟,研究了土壤Cd、Cr、Pb、Cu、Zn全量的空间分布状况、各形态重金属含量统计特征,以及水稻子实对重金属各形态的累积差异及其影响因素。结果表明,成都平原水稻土重金属污染较轻,除Cd外,均低于国家土壤环境质量二级标准。土壤中重金属的可交换态含量均较低,Cd主要以铁锰氧化态存在,Cr、Cu、Zn、Pb主要以残渣态存在。水稻子实对5种重金属的累积效应顺序为:Cd>Zn>Cu>Pb>Cr。与水稻重金属累积关系密切的重金属活性形态(可交换态、碳酸盐结合态、铁锰氧化物结合态和有机物结合态)主要有:Cd的碳酸盐结合态、Cr的可交换态、Pb的有机物结合态和Cu的碳酸盐结合态含量;Zn各活性形态对水稻子实含量的影响不明显。土壤理化性质对不同活性形态重金属元素的影响效应各不相同。活性态Cd主要受有机质、pH和容重的影响;活性态Cr与pH、有机质、CEC和容重密切相关;活性态Pb与有机质、容重、中细粉粒、砂粒等均有密切的关系;Cu的活性主要受粘粒、有机质含量的影响;Zn的有效性主要受pH、有机质、砂粒、容重的影响。总的看来,对土壤Cd、Cr、Pb、Cu、Zn各活性形态含量影响效应较强的是有机质、pH、容重,而与土壤吸附性能密切相关的颗粒组成、CEC的影响不甚明显。  相似文献   

2.
在分析成都平原核心区土壤重金属(Cd、Cr、Pb、Cu、Zn)全量、各形态含量及相应点位种植的水稻籽实重金属含量的基础上,通过统计分析、空间插值及线性回归方程的模拟,研究了土壤Cd、Cr、Pb、Cu、Zn全量的空间分布状况、各形态重金属含量统计特征,以及水稻籽实对重金属各形态的累积差异及其影响因素。结果表明,成都平原水稻土重金属污染较轻,除Cd外,均低于国家土壤环境质量二级标准。土壤中重金属的可交换态含量均较低,Cd主要以铁锰氧化态存在,Cr、Cu、Zn、Pb主要以残渣态存在。水稻籽实对5种重金属的累积效应顺序为:Cd>Zn>Cu>Pb>Cr。与水稻重金属累积关系密切的重金属活性形态(可交换态、碳酸盐结合态、铁锰氧化物结合态和有机物结合态)主要有:Cd的碳酸盐结合态、Cr的可交换态、Pb的有机物结合态和Cu的碳酸盐结合态含量;Zn各活性形态对水稻籽实含量的影响不明显。土壤理化性质对不同活性形态重金属元素的影响效应各不相同。活性态Cd主要受有机质、pH和容重的影响;活性态Cr与pH、有机质、CEC和容重密切相关;活性态Pb与有机质、容重、中细粉粒、砂粒等均有密切的关系;Cu的活性主要受粘粒、有机质含量的影响;Zn的有效性主要受pH、有机质、砂粒、容重的影响。总的看来,对土壤Cd、Cr、Pb、Cu、Zn各活性形态含量影响效应较强的是有机质、pH、容重,而与土壤吸附性能密切相关的颗粒组成、CEC的影响不甚明显。  相似文献   

3.
沈阳南部沿城乡梯度土壤铅时空分布研究   总被引:2,自引:0,他引:2  
对沈阳南部沿城乡梯度土壤铅含量的分布特征进行了研究。结果表明,全量Pb沿城乡梯度显著降低,但不同土层之间无显著差异。有效态Pb含量沿城乡梯度具有显著降低,并且在城市土壤中呈现较明显的季节性变化。另外,土壤有效态Pb含量在夏季郊区样品和秋季城市样品的层次之间也有显著变化。相关性分析表明,土壤理化性质如土壤质地、pH和CEC对全量及有效态Pb含量产生了一定影响,而人为等因素是影响土壤全量及有效态重金属的主要因素。  相似文献   

4.
沿海滩涂区土壤重金属含量分布及其有效态影响因素   总被引:2,自引:1,他引:1  
为揭示沿海地区土壤重金属含量的空间分布特征及其与自然、人为因素的关联,以近年来围垦开发强度较大的江苏沿海某滩涂区为研究对象,采用经典统计与地统计相结合的方法研究了表层土壤主要重金属Pb、Cr、Cd、As全量与有效态含量状况及其空间分布,分析了沿海滩涂区土地利用方式对重金属含量的影响,探讨了重金属有效态含量与土壤理化性质的相关性。结果表明:目前研究区土壤环境质量状况良好,土壤Pb、Cr、Cd、As均呈累积趋势但基本都低于土壤环境质量一级标准值;土地利用方式不同程度地影响了Pb、Cr、Cd全量与有效态含量,As全量与有效态含量受土地利用方式影响较小;研究区土壤Pb、Cr、Cd全量与Pb、Cr有效态含量具有明显的趋势效应,且研究区土壤重金属全量与有效态含量的空间分布受大尺度的潮汐作用与小尺度的人为因素的共同控制;土壤Pb、Cr、Cd有效态含量与黏粒含量、阳离子交换量和p H显著负相关,与有机质呈显著正相关,土壤As有效态含量仅与土壤p H显著正相关。本研究为沿海滩涂区土壤重金属源头减量、活性钝化、污染消减与风险防范提供科学依据。  相似文献   

5.
昆山市农业土壤基本性质与重金属含量及二者的关系   总被引:12,自引:2,他引:12  
陈凤  濮励杰 《土壤》2007,39(2):291-296
研究了昆山市农业土壤基本性质和土壤中的重金属含量,并对二者的相关关系进行了分析。结果表明:昆山市农业土壤基本全为壤土,土壤pH值平均为6.50,土壤有机质平均含量为30.53g/kg,土壤CEC平均值为17.51cmol/kg,且各区之间变幅不大;昆山市主要污染重金属Cd、Pb和Hg全量大小排序基本为黄泥土>青泥土>青紫土>乌栅土;土壤重金属含量和土壤理化性质间的关系复杂,如全量As与pH值、有机质含量和全N含量呈极显著负相关,而全量Hg与土壤中有机质含量、全N含量、碱解N含量、CEC呈极显著正相关。  相似文献   

6.
为探究气候变化背景下周期性冻融对土壤性质及重金属的影响,采用模拟试验,探讨冻融频次对棕壤微团聚体、pH值、电导率(EC)、有机质(OM)、阳离子交换量(CEC)、PO3-4、酶活性以及Pb赋存形态的影响,分析了周期性冻融下Pb赋存形态与土壤理化性质间的相关性。结果表明:周期性冻融导致2~0.25 mm颗粒含量降低,0.25~0.05 mm颗粒含量增加,微团聚体稳定性被破坏。随着冻融频次的增加,棕壤pH值,EH,OM,CEC,URE活性升高,PO3-4,CAT活性降低。冻融频次增加时,弱酸提取态Pb含量增加(p<0.05),可还原态Pb含量先增后降,残渣态Pb含量先降后增,可氧化态Pb含量呈波动式; 弱酸提取态Pb与PO3-4呈显著负相关(p<0.05),残渣态Pb与PO3-4呈显著正相关(p<0.05),可还原态Pb与土壤pH值呈显著正相关(p<0.05),可氧化态Pb与土壤OM呈显著正相关(p<0.05)。综上,冻融会通过改变土壤的理化性质从而导致Pb生态毒性增强,从而在一定程度上增加了Pb对深层土壤及地下水的环境风险。  相似文献   

7.
通过现场采样及室内分析方法,研究了Cd、Pb严重污染的土壤中蛋白酶、酸性磷酸酶和脱氢酶活性的变化及其与土壤Cd、Cu、Pb、Zn含量和土壤基本性质之间的关系。通径分析表明,影响蛋白酶活性主要直接因素为土壤有效Cd、土壤有效Zn、砂粒和黏粒,其中土壤有效Zn刺激了酶活性而土壤有效Cd抑制了酶活性;影响酸性磷酸酶活性主要直接因素为碱解氮、速效磷、pH值,土壤有效Cu、土壤有效Cd、土壤有效Pb、土壤有效Zn对酸性磷酸酶的直接影响较小;影响脱氢酶活性主要直接因素为土壤有效Cd、土壤有效Zn、土壤速效钾,其中土壤有效Cd抑制了酶活性而土壤有效Zn刺激了酶活性。总体而言,4种重金属有效态对酶活性毒性大小依次为:Cd〉Cu〉Pb〉Zn。综合简单相关分析结果可知,总体上Cu、Cd、Pb、Zn复合污染刺激了蛋白酶活性,抑制了脱氢酶活性,对酸性磷酸酶活性影响不大,脱氢酶可作为上述土壤重金属复合污染的指标。3种土壤酶活性变化是重金属与土壤理化性质综合作用的结果。  相似文献   

8.
施用生物有机肥对红壤水稻土中重金属及微生物量的影响   总被引:5,自引:1,他引:4  
研究了施用生物有机肥对红壤性水稻土中重金属含量、养分含量以及微生物量碳、氮的影响,以期为改善红壤性水稻土重金属污染状况提供科学依据。通过田间小区定位试验,一次性施入不同量的生物有机肥为:0、10、20、30和40 t·hm-2,于2017年9月水稻成熟期采集各处理表层土壤,研究土壤养分和重金属含量及微生物生物量的变化。施用生物有机肥可以提高土壤养分含量和微生物量碳、氮含量,降低土壤中全量Cd、DTPA-Cd和DTPA-Pb含量,而对土壤全量Pb则没有显著的影响。相关分析表明,在红壤性水稻土中施用生物有机肥后,土壤中的CEC、pH和全氮以及有效磷含量这4种养分显著影响土壤全量Cd、DTPA-Cd以及DTPA-Pb的含量;而通径分析则表明,土壤DTPA-Cd与土壤全氮关系最为密切,土壤有效磷对土壤DTPA-Pb含量的影响为最大。施用生物有机肥可以改善土壤重金属污染的状况,提升土壤肥力。  相似文献   

9.
为了了解长期灌溉猪场废水对农田土壤Pb、Cd和As(简称重金属)的影响,采集了河北省京安猪场周边农田的清洁区和灌溉8年猪场废水的污灌区耕层(0~20 cm)共52个土壤样品,并测定了样品中重金属的全量和有效态含量,应用GIS结合地统计学方法对重金属进行了空间结构和分布特征分析,探讨规模化猪场周边农田土壤重金属积累的影响因子及其贡献.结果表明,重金属全量和有效态含量的变异函数均很好地符合球状模型,其中全铅、有效铅、全砷、全镉和有效砷受随机性因素和结构性因素共同影响,有效镉主要受结构性因素影响.根据背景调查、重金属与pH值和土壤养分的相关性分析以及重金属变异函数分析,土壤中Cd和As污染来源为猪场废水和化肥,Pb的污染来源为化肥.富集因子分析表明,污灌猪场废水对土壤Cd和As富集效应很小,施用化肥对Pb富集有较大贡献.灌溉猪场废水会降低土壤pH值而增加重金属有效态含量,因此,需注意施用猪场废水带来重金属污染风险.  相似文献   

10.
不同钝化剂对Cu、Cr和Ni复合污染土壤的修复研究   总被引:8,自引:2,他引:8  
利用盆栽试验研究了不同钝化剂(沸石、牡蛎壳、鸡蛋壳、硅藻土和聚丙烯酰胺(PAM))对生长在重金属污染土壤上的青菜(Brassica chinensis L.)生物量、重金属吸收以及超氧化物歧化酶的活性(SOD)和丙二醛(MDA)含量的影响,同时,通过对土壤p H和土壤重金属提取态的分析,探讨了钝化剂影响青菜生物量和重金属吸收的可能原因。结果表明:钝化剂加入可显著降低青菜地上部分Cu、Zn、Ni和Cd的含量及其氧化性损伤和脂膜损伤(SOD和MDA指标显著降低)。施入钝化剂后,土壤p H显著提高,重金属提取态Cu、Zn、Pb、Ni和Cd普遍降低(硅藻土处理除外)。相关性分析表明,土壤p H与提取态重金属Pb、Zn、Ni和Cd呈显著的负相关,而青菜中的重金属Zn、Ni和Cd的含量与土壤提取态含量呈显著正相关。综合考虑,单一钝化剂牡蛎壳和沸石+牡蛎壳+鸡蛋壳(FMJ)组合对降低青菜重金属吸收的效果尤为显著,可推荐作为重金属复合污染土壤的改良剂。本研究为重金属中轻度污染菜地的土壤修复提供了一种新方法。  相似文献   

11.
The influence of selected factors on Cd levels in soils and in grain of oats and winter wheat was investigated. Soil and grain were sampled at sites randomly distributed over Sweden. Organic soils generally had higher Cd contents and lower pH levels than mineral soils, and plants growing in organic soils tended to have higher Cd contents than plants growing in mineral soils. In mineral soils the amount of soil Cd extractable in 2M HNO3 was positively correlated with the pH and the contents of organic matter and clay. The studied variable best correlated with the Cd content of oat grain grown on mineral soils was the pH (negative correlation). Soil contents of organic matter, clay, HNO3-extractable Cd and Zn were also found to be significantly related to the Cd content in a stepwise regression analysis. In winter wheat grain, Cd content was best correlated with the HNO3-extractable Cd (positive correlation). Additional significant factors were pH, grain yield and contents of organic matter, clay and HNO3-extractable Zn. In winter wheat the presence of Zn reduced Cd uptake, and vice versa; no such mutually antagonistic relationship was apparent in oats. In oats, but not in wheat, it was possible to predict most of the differences in grain Cd content, caused by the factors described above, based on the variation in CaCl2-extractable soil Cd. Analysis of samples from field trials indicated that there were differences in Cd content between varieties of both crops. Variation in factors described generally explained most of the differences in soil- and grain Cd levels between regions.  相似文献   

12.
Soil soluble organic nitrogen (SON) is one of the most active components in soil nitrogen pools; however, limited information is available with regard to its driving factors, as well as their pathways and degrees of influence. In this study, structural equation modeling was used to analyze the driving factors, their significance, and pathways that affected SON dynamics in a waterlogged experiment of two typical paddy soils incubated for 80 d after green manure application. Soil pH, Eh, microbial biomass, enzyme activity, and SON dynamics were used to construct the structural equation model. Results showed that soil microbial biomass carbon (MBC), protease, glutamine, and initial organic matter (OM) directly and significantly affected soil SON with path coefficients corresponding to 0.405, 0.547, 0.523, and -0.623 (P < 0.01), respectively. Soil microbial biomass carbon and initial OM affected the SON dynamics indirectly through protease and glutamine activity. In addition, pH indirectly affected SON dynamics by glutamine activity. It is implied that soil MBC, protease, glutamine, and initial OM are the key factors affecting SON dynamics in the waterlogged paddy soils after green manure application. Our research indicated that structural equation modeling could provide an effective method to clearly recognize the impact, significance, and pathways of multiple factors on SON dynamics in paddy soils.  相似文献   

13.
The roles of fine-earth materials in the cation exchange capacity (CEC) of especially homogenous units of the kaolinitic and oxyhydroxidic tropical soils are still unclear. The CEC (pH 7) of some coarse-textured soils from southeastern Nigeria were related to their total sand, coarse sand (CS), fine sand (FS), silt, clay, and organic-matter (OM) contents before and after partitioning the dataset into topsoils and subsoils and into very-low-, low-, and moderate-/high-stability soils. The soil-layer categories showed similar CEC values; the stability categories did not. The CEC increased with decreasing CS but with increasing FS. Silt correlated negatively with the CEC, except in the moderate- to high-stability soils. Conversely, clay and OM generally impacted positively on the CEC. The best-fitting linear CEC function (R2, 68%) was attained with FS, clay, and OM with relative contributions of 26, 38, and 36%, respectively. However, more reliable models were attained after partitioning by soil layer (R2, 71–76%) and by soil stability (R2, 81–86%). Notably FS's contribution to CEC increased while clay's decreased with increasing soil stability. Clay alone satisfactorily modeled the CEC for the very-low-stability soils, whereas silt contributed more than OM to the CEC of the moderate- to high-stability soils. These results provide new evidence about the cation exchange behavior of FS, silt, and clay in structurally contrasting tropical soils.  相似文献   

14.
Chinese cabbage and surface soil samples (0–20 cm) from a periurban market garden in Yunnan Province (P.R. China) were collected to determine variations of cadmium (Cd) and zinc (Zn) contents in Chinese cabbage and the influence of soil factors. Mean Cd content was 0.49 mg kg?1 dry materials (DM) in Chinese cabbage, ranging between 0.23 and 1.34 mg kg?1 DM (n = 21 samples). Mean Zn content was 51.2 mg kg?1 DM, ranging from 34.9 to 157.5 mg kg?1 DM (n = 21 samples). The soil factors best predicting Chinese cabbage Cd and Zn contents were total and available Cd and Zn contents and cation exchange capacity (CEC). Soil samples and corresponding Chinese cabbage samples were divided into two groups: soils with low pH (<6.5, n = 10) and soils with high pH (>6.5, n = 11). Positive correlation between CEC with pH > 6.5 and Cd and Zn contents in Chinese cabbage were observed. Available trace element contents and CEC explained 77% and 69% of variation of Cd and Zn contents in Chinese cabbage, respectively. AEC (enrichment coefficient related to trace element availability) and BCF (bioaccumulation factors) could be used to understand Cd and Zn accumulation in Chinese cabbage.  相似文献   

15.
Soil test indicators are needed to predict the contribution of soil organic N to crop N requirements. Labile organic matter (OM) fractions containing C and N are readily metabolized by soil microorganisms, which leads to N mineralization and contributes to the soil N supply to crops. The objective of this study was to identify labile OM fractions that could be indicators of the soil N supply by evaluating the relationship between the soil N supply, the C and N concentrations, and C/N ratios of water extractable OM, hot‐water extractable OM, particulate OM, microbial biomass, and salt extractable OM. Labile OM fractions were measured before planting spring wheat (Triticum aestivum L.) in fertilized soils and the soil N supply was determined from the wheat N uptake and soil mineral N concentration after 6 weeks. Prior to the study, fertilized sandy loam and silty clay soils received three annual applications of 90 kg available N (ha · y)?1 from mineral fertilizer, liquid dairy cattle manure, liquid swine manure or solid poultry litter, and there was a zero‐N control. Water extractable organic N was the only labile OM fraction to be affected by fertilization in both soil types (P < 0.01). Across both test soils, the soil N supply was significantly correlated with the particulate OM N (r = 0.87, P < 0.001), the particulate OM C (r = 0.83, P < 0.001), and hot‐water extractable organic N (r = 0.81, P < 0.001). We conclude that pre‐planting concentrations of particulate OM and hot‐water extractable organic N could be early season indicators of the soil N supply in fertilized soils of the Saint Lawrence River Lowlands in Quebec, Canada. The suitability of these pre‐planting indicators to predict the soil N supply under field conditions and in fertilized soils from other regions remains to be determined.  相似文献   

16.
王丽丽  周通  李柱  周嘉文  吴胜春  吴龙华 《土壤》2017,49(5):951-957
采集黏土、壤黏土和砂质壤土,分别设置无压实、低紧实度及高紧实度3种处理,通过盆栽试验研究了土壤紧实度对Cd、Zn超积累植物伴矿景天生长和Cd、Zn吸收性的影响。结果表明,与无压实处理比较,砂质壤土、壤黏土和黏土中伴矿景天地上部生物量在低紧实度下显著下降66.8%~83.5%、59.9%~60.4%和57.9%~71.4%;高紧实度处理却显著提高了伴矿景天的根系活力(142%~241%)。高紧实度处理显著降低了壤黏土上伴矿景天地上部Cd和Zn含量,但低紧实度对砂质壤土和黏土上伴矿景天地上部Cd和Zn含量无显著影响。与无压实处理比较,低紧实度显著降低了砂质壤土、壤黏土和黏土上伴矿景天的Cd吸取量,分别下降50.4%~73.8%、61.4%~74.9%和43.4%~63.3%,Zn吸取量下降48.7%~79.5%、73.6%~79.0%和46.1%~63.5%;土壤紧实度对壤黏土上伴矿景天的镉锌吸取效率影响最明显。  相似文献   

17.
土壤组分对广东省酸性水稻土磷吸附参数的影响   总被引:9,自引:2,他引:7  
Soil components affecting phosphate sorption parameters were studied using acid paddy soils derived from basalt, granite, sand-shale and the Pearl River Delta sediments, respectively, in Guangdong Province.For each soil, seven 2.50 g subsamples were equilibrated with 50 mL 0.02 mol L-1 (pH=7.0) of KCl containing 0, 5, 10, 15, 25, 50 and 100 ng P kg-1, respectively, in order to derive P sorption parameters (P sorption maximum, P sorption intensity factor and maximum buffer capacity) by Langmuir isotherm equation. It was shown that the main soil components influencing phosphate sorption maximum (Xm) included soil clay, pH,amorphous iron oxide (Feo) and amorphous aluminum oxide (Alo), with their effects in the order of Alo >Feo > pH > clay. Among these components, pH had a negative effect, and the others had a positive effect.Organic matter (OM) was the only soil component influencing P sorption intensity factor (K). The main components influencing maximum phosphate buffer capacity (MBC) consisted of soil clay, OM, pH, Feo and Alo, with their effects in the order of Alo > OM > pH > Feo > clay. Path analysis indicated that among the components with positive effects on maximum phosphate buffer capacity (MBC), the effect was in the order of Alo > Feo > Clay, while among the components with negative effects, OM > pH. OM played an important role in mobilizing phosphate in acid paddy soils mainly through decreasing the sorption intensity of phosphate by soil particles.  相似文献   

18.
A comparative study was conducted on the toxicity of Cd to alkaline phosphatase activity (ALP) and dehydrogenase activity (DHA) in 18 top soils with contrasting soil properties representative of 14 major soil types in China. Soil pH and carbonate content, soil organic matter, and cation exchange capacity (CEC) largely affected the Cd toxicity on two enzyme activities; with the soil pH having only minor effect on the median ecological dose values based on total Cd concentrations (ED50 T). The values of ED50 T/ED50 W (based on water-soluble Cd content) of alkaline phosphatase and dehydrogenase were strongly influenced by pH and CEC contents, which explained up to 71% of the variation for alkaline phosphatase, 82% of the variation for dehydrogenase, and also were significantly correlated with the parameter KF derived from Freundlich adsorption isotherms. This study suggests that the values of ED50 T/ED50 W could be useful to evaluate the buffer capacity of soils which protects soil enzymes from harmful effects of heavy metal.  相似文献   

19.
孙婷婷  徐磊  周静  樊剑波  陈晏 《土壤》2016,48(5):946-953
针对江西贵溪Cu、Cd重金属污染土壤,通过田间试验,比较无机生物材料羟基磷灰石及3种植物(海州香薷、巨菌草、伴矿景天)与羟基磷灰石联合修复对土壤总Cu、Cd的吸收及对活性Cu、Cd的钝化吸收能力差异。采用磷脂脂肪酸(PLFA)分析法,比较不同修复模式对土壤微生物群落结构的影响,以评估土壤微生态环境对不同修复措施的响应。研究结果表明:羟基磷灰石的施加可显著提高土壤pH,并有效钝化土壤活性Cu、Cd含量,但对土壤总Cu、Cd的含量影响较小。植物与羟基磷灰石的联合修复在显著降低土壤活性Cu、Cd(P0.05)的同时,减少了植物根际土壤总Cu、Cd的含量(P0.05)。不同修复措施对土壤微生物群落组成影响差异明显。单独施加羟基磷灰石与土壤真菌群落呈显著正相关,使土壤真菌生物量提高,从而引起真菌/细菌(F/B)的升高。植物与羟基磷灰石的联合修复可有效缓解土壤真菌化的趋势,其中巨菌草与羟基磷灰石的联合修复可有效提高土壤革兰氏阳性、革兰氏阴性细菌生物量及多样性,降低F/B值,从而降低土壤真菌病害的风险。不同植物根系活性代谢引起有机质的积累促进植物与羟基磷灰石处理中根际有机碳含量显著提高。聚类增强树(Aggregated boosted tree,ABT)分析结果表明:不同修复模式是影响土壤微生物群落的重要因素,其次土壤pH和Cu的含量及活性也是改变重金属污染区域微生物群落的因子。该研究从微生物群落结构角度解释了植物与羟基磷灰石联合修复对土壤微生态体系的作用,为开展Cu、Cd等重金属污染地植物与无机生物材料的联合修复方式的筛选及实施提供可靠的理论依据。  相似文献   

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