Amorphous clay materials of towada ando soils

Towada Ando soils consisted of five soils—Towada-a (1,000 years old), Towada-b (2,000 years old), Chuseri (4,000 years old), Nanbu (8,600 years old), and Ninokura soils (10,000 years Amorphous clay materials of these soils taken at different localities were studied by the combined use of selective dissolution and differential infrared spectroscopy, X-ray analysis, electron microscopy, etc.

The main clay minerals of Towada-a soils, present-day soils, were montmorillonite-vermic-ulite chloritic intergrades and opaline silica, or these minerals and allophane in the humus horizons, and allophane in the non-humus ones. Towada-b soils overlain by the Towada-a soils showed the clay mineralogical constituents similar to those of Towada-a soils. However, allophane was one of the main clay minerals in all the humus horizons as well as non-humus ones. The main clay minerals of Chuseri soils were allophane and layer silicates consisting chiefly of chloritic intergrades and chlorite in the humus horizons, and allophane in the non-humus ones. Opaline silica was present in minor amounts in the humus horizons of Chuseri soils, but nearly absent in Nanbu and Ninokura soils.

There were remarkable differences in the clay mineralogical composition of Nanbu and Ninokura soils with differences of their environmental conditions. Allophane and imogolite Were dominant in the clay fractions of both humus and non-humus horizons of very shallowly buried Nanbu soil which was subjected to the strong leaching process. Allophane was the main clay mineral of deeply buried Nanbu and Ninokura soils which showed the absence of notable accumulation of bases and silica. On the contrary, halloysite with a small amount of siliceous amorphous material appeared in very deeply buried Nanbu and Ninokura soils where bases and silica were distinctly accumulated. The amounts of halloysite in the clay fractions were larger in the humus horizons than non-humus ones, and in Ninokura soil than Nanbu soil.

Soil age, soil organic matter, and depositional overburden of tephras were observed to be conspicuous among various factors relating to the weathering of amorphous clay materials in Towada Ando soils.     

Some applications of paleopedology in Japan

Paleosols in Japan consist of buried soils and relict soils. The former occur primarily in tephra deposit, whereas the latter occupy old land surfaces in various parts of the country. The buried soils affect construction of highways and urban development. The relict soils pose problems in forestry.The paleosols formed in tephra and buried by subsequent volcanic eruptions are chiefly Andosols with their low bulk densities, low solid ratios, high specific surfaces and high water losses. These characteristics are responsible for poor engineering performance of the paleosols and tephras. These have been especially troublesome in the Kanto plain near tokyo and around the Ashitaka Volcano. Some buried soils in tephra, as for example those in the San'in district, are exceptions to the general rule and have desirable properties for construction. Those tephras have clay fractions low in allophane and high in layer-silicate minerals.The buried soils have provided approximate ages of human artifacts through radiocarbon dating of humic horizons. Conversely, identification of artifacts found in buried soils has helped to bracket their ages.Paleosols that are relicts are chiefly members of a Red-Yellow group, many of which seem to be Udults (Ultisols). The soils apparently began forming in warmer past periods but still persist on the land surface. Such soils are strongly acid and very low in plant nutrients, with resulting low productivity when used for forestry or farming. Moreover, such soils are readily subject to erosion because of their landscape positions and poor plant cover.     

ABSTRACT of the Articles Printed in Journal of the Science of Soil and Manure,Japan

A contrasting occurrence of clay minerals was found within a soil profile which was derived from volcanic materials in the suburbs of Fukuoka-city, Northern Kyushu. The soil profile is located on an isolated terrace, and the morphological characteristics of the soil correspond exactly to Andosols, so-called Kuroboku soils or Humic Allophane soils.

The clay fraction of upper horizons of the soil consists largely of alumina-rich gel-like materials, gibbsite, and layer silicates such as chlorite and chloritevermiculite intergrades, while that of lower horizons is composed of allophane and gibbsite or halloysite. There was no positive indication of allophane in the upper horizons. Corresponding with the clay mineralogical composition, quartz is abundant in the fine sand fraction of the upper horizons, while the mineral is very scarce or none in the lower horizons, suggesting a close relation between the petrological nature of parent volcanic materials and the mineralogical composition of weathering products. The dominant clay mineral in the volcanic 1.10il might be dependent on the petrological nature of parent materials, and allophane is mostly formed from andesitic materials, and alumina-rich gel-like materials and layer silicates have come from quartz andesitic materials. Allophane would transform to gibbsite or halloysite according to weathering conditions, and aluminarich gel-like materials change to gibbsite under a well-drained condition.

The soil materials have been so greatly weathered that some horizons contain gibbsite of even more than 40 per cent or halloysite over 70 per cent. The morphology and mineralogy are quite similar to so-cailed “non-volcanic Kuroboku soils.”     

Soil development processes in an Aqualf-Ochrept sequence from loess with admixtures of tephra, New Zealand

The properties of contrasting soils occurring under a 1050–1600 mm rainfall gradient are described. The soils range, with increasing rainfall, from Typic Fragiaqualfs to Andic Dystrochrepts. Sand mineralogy of these soils indicates that they have formed in essentially similar parent materials consisting largely of quartzo-feldspathic loess with admixtures of rhyolitic and andesitic tephra. The Fragiaqualfs have high bulk density, impeded drainage in winter, degraded chlorite, argillic horizons, halloysite and vermiculite. The Dystrochrepts have lower bulk density, free drainage, ferrihydrite, allophane, humus-(Al, Fe) complexes and no argillic horizons. An hypothesis to explain differences between these soil groups proposes that the dense horizons in the Fragiaqualfs arise largely from hydraulic suctions exerted by roots during periods of high summer water deficits. The consequent loss of porosity leads to impeded drainage in winter causing gleying and enhanced clay formation. In the Dystrochrepts the summer deficits are lower, consequently the soils have lower bulk densities and remain free draining.     

Gibbsite and halloysite decomposition in strongly acid podzolic soils developed from granitic saprolite of the Bayerischer Wald

The present study reports the occurrence of gibbsite and halloysite in soils derived from granitic saprolites and from glacial deposits formed from granitic saprolites of the Bayerischer Wald (Germany). Both minerals are common in soils of this area. They were formed in the initial stages of weathering, most probably before the Pleistocene and in a warmer climate. Under present conditions halloysite and gibbsite are unstable in the surface soils, as indicated by a decrease in gibbsite concentration towards the surface and by an undersaturation of the equilibrium soil solution with respect to both minerals. It is assumed that the strongly acid conditions and the high concentration of organic compounds in the surface horizons lead to dissolution of gibbsite and possibly to transformation of halloysite to kaolinite.     

不同年代的埃特纳火山土壤上用甘油萃取有机质的特性

We characterized humic acids (HAs) and glycerol-extractable organic fractions (GEOFs) extracted from four Andisols, taken from comparable soil-climate conditions on the east side of Mount Etna. The soils were formed on old lava (about 9 000 years ago), old tephra (about 8 700 years ago), recent lava (about 2 600 years ago) and recent tephra (about 3 600 years ago). A part of the organic matter of the soils, deprived of HAs and fulvic acids (FAs), was isolated by glycerol extraction. The GEOF can not be extracted with alkaline solutions, probably because it is closely bound to the mineral component of the soil. The characterization of the extracted organic fraction was carried out using elementary and functional group analysis and Fourier transform infrared (FT-IR) spectroscopy. About 20 extractions were necessary to extract the HA and FA from the older soils and about 10 extractions to extract them from the younger soils. Data showed that the GEOFs had a greater ash content and a smaller N content, as well as a greater presence of aliphatic compounds and carboxylic groups as compared to the HA extracted from the same soil. The GEOFs extracted from younger soils also had a lower yield, ash and COOH-group content, and were more aliphatic than the GEOF extracted from older soils. Finally, the GEOFs were more closely bound to the amorphous component of the soil (‘short-range’ minerals) and consequently less subject to biodegradation.     

THE CATEGORIES OF ALUMINIUM- AND IRON-HUMUS COMPLEXES IN ANDO SOILS DETERMINED BY SELECTIVE DISSOLUTION

Thirty-three samples of Ando soils were extracted by sodium pyrophosphate (O.IM; pH 10) and by dithionite-citrate. The Al, Fe, and C contents of these two extracts offer a means of differentiating the status of humus in relation to Al and Fe in the different horizons. The humus that forms at first in the Al horizon has a very low complexing ability for Al and Fe and little is dissolved by pyrophosphate. The humus evolves with time or pedogenesis into forms that complex Al and Fe released from volcanic ash by weathering, and which are dissolved by pyrophosphate. In the old horizons, the humus further reacts with additional Al and Fe, some of which may be present as hydrous oxides or allophane-like constituents, allophane and imogolite. This reaction probably makes the humus less soluble in pyrophosphate.     

Mercury distribution in tephra soil layers in Hokkaido, Japan, with reference to 34,000-year stratification

Tephra from volcanic eruptions contains only small amounts of mercury (Hg) right after the eruption because the high temperature at eruption evaporates Hg in volcanic ash. Thus, accumulation of Hg in tephra soil layers during the dormant periods of the volcano may reflect Hg deposition while the layer was exposed to the atmosphere. To estimate sequential changes in Hg deposition, we measured the Hg content and accumulation in tephra layers from 6 sites in Hokkaido known to have many tephra layers derived from volcanic eruptions over a 34,000-year period. Mercury content and accumulation rate in the soil profiles varied widely depending on the tephra. In each tephra layer, the Hg content and accumulation rates increased principally at the upper soil horizons and decreased at the lower depths. The Hg deposition rates calculated from the amount of Hg accumulated in the tephra layers were similar within the same tephra. These characteristics of Hg distribution indicate that Hg deposition accumulated on the surface of each tephra layer during the period the tephra layer was exposed to the atmosphere. Although physicochemical processes such as leaching out, wind erosion, and volatilization might lead to over- and/or underestimation of the deposition rates, our estimated amounts of Hg were markedly higher in the tephra soils after 1,600 year BP than before that time. The results of this study suggest that tephra layers in Hokkaido offer important implications for understanding of the historical changes in atmospheric Hg deposition.     

Dilute acid-soluble phosphorus in fresh air-borne tephras and fixation with an increase in active aluminum and iron

Fresh rhyolite-to-andesite tephras ground to less than 0.15 mm particles contained dilute acid-soluble phosphorus (P) as in the case of cultivated upland soils in Japan. The amount of P determined by Truog extraction (Truog P) ranged between 119 and 784 mg P₂O₅ kg^-1 in 12 rhyolite-to-andesite tephras, and that determined by a modified Bray P₂ extraction method (modified Bray P₂) ranged between 133 and 812 mg P₂O₅ kg^-1. In contrast, the Truog P-content in fresh basaltic andesite-to-basalt tephras was only 3.4–23 mg P₂O₅ kg^-1, and the modified Bray P₂-content was in the range of 41–185 mg P₂O₅ kg^-1, although the total P-content of the two tephra groups was in almost the same range.

Among 12 rhyolite-to-andesite tephras, those from Mt. Usu that erupted in 1977 and from Mt. Pinatubo that erupted in 1991 were selected for detailed studies. Fine particle size fractions of these tephras showed higher Truog P values than the coarse ones. The Truog P values further increased in the heavy fraction with a particle density of 2.8 or greater. In this heavy fraction, apatite was detected by energy dispersive X-ray (EDX) analysis, indicating the contribution of the mineral to the high Truog P. Dilute sulfuric acid treatment of the tephras at 80°C for 15 d followed by neutralization increased the amount of active Al and Fe and decreased the Truog P values of these tephras. These results suggested that the amount of apatite rapidly decreased with weathering in volcanic ash soils.     

Implications of clay mineralogy to the weathering and chemistry of AP horizons of ando soils in Japan

The clay mineralogy of 22 samples of the Ap horizons of Ando soils was determined by a combination of methods. Of these samples, 15 did and 7 did not contain allophane and imogolite. Opaline silica was found in 4 samples, whereas aluminum—humus complexes, iron oxides and layer silicates were found in all samples. The presence of allophane and imogolite and the absence of opaline silica in a few Ap horizons was related to mixing of A₁ horizons and subsoils by cultivation and to lower supplies of organic matter relative to the amounts of aluminum released from volcanic ash by weathering. The contents of 2:1 and 2:1:1 layer silicates and their intergrades were larger in soils in which quartz predominated in fine fractions. It was inferred that aluminum bound with humus and in allophane-like constituents, rather than aluminum in allophane and imogolite, is important in reactions with phosphate and fluoride.     

Mercury distribution in tephra soil layers in Hokkaido,Japan, with reference to 34,000-year stratification

Abstract

Tephra from volcanic eruptions contains only small amounts of mercury (Hg) right after the eruption because the high temperature at eruption evaporates Hg in volcanic ash. Thus, accumulation of Hg in tephra soil layers during the dormant periods of the volcano may reflect Hg deposition while the layer was exposed to the atmosphere. To estimate sequential changes in Hg deposition, we measured the Hg content and accumulation in tephra layers from 6 sites in Hokkaido known to have many tephra layers derived from volcanic eruptions over a 34,000-year period. Mercury content and accumulation rate in the soil profiles varied widely depending on the tephra. In each tephra layer, the Hg content and accumulation rates increased principally at the upper soil horizons and decreased at the lower depths. The Hg deposition rates calculated from the amount of Hg accumulated in the tephra layers were similar within the same tephra. These characteristics of Hg distribution indicate that Hg deposition accumulated on the surface of each tephra layer during the period the tephra layer was exposed to the atmosphere. Although physicochemical processes such as leaching out, wind erosion, and volatilization might lead to over- and/or underestimation of the deposition rates, our estimated amounts of Hg were markedly higher in the tephra soils after 1,600?year?BP than before that time. The results of this study suggest that tephra layers in Hokkaido offer important implications for understanding of the historical changes in atmospheric Hg deposition.     

Mineralogy of some Italian andosols with special reference to the origin of the clay fraction

The mineralogy of four Italian Andosols - derived from volcanic material either oversaturated or undersaturated with respect to silica - has been investigated by XRD, EM and IR. The crystalline clay minerals in all four profiles are essentially similar, consisting of abundant halloysite with moderate illite and 14A intergrade material, minor kaolinite and occasional gibbsite. The soils also contain large amounts of imogolite and proto-imogolite allophane. With the exception of illite all these clay minerals are believed to be of pedogenic origin. Halloysite occurs in the dehydrated form in the surface horizons but becomes progressively more hydrated with depth. At depths of > 1.4 m the clay fraction consists almost entirely of fully hydrated halloysite, supporting the suggestion that halloysite forms best in a stagnant moisture regime where there is a depositional overburden acting as a silica source. EM observations show that the halloysite may have spherical morphology and may be intimately associated with gas vesicles in pumice grains where it probably forms by the transformation of allophanic material. It seems likely that dehydrated halloysite slowly converts to poorly crystallized kaolinite in the upper horizons of these profiles. The origin of the 2/1 minerals is more problematical. Illite is probably inherited from mica in the parent material but the 14A intergrade material is so poorly ordered that a pedogenic origin seems more likely than formation by inheritance or by transformation of pre-existing 2/1 silicates.     

Clay mineralogy and some chemical properties of Ap horizons of Ando soils used for paddy rice in Japan

The clay mineralogy of the Ap horizons of Ando soils in Japanese paddies was determined by a combination of methods and compared with that of Ando soils of uplands. Six of 13 paddy soil samples contained allophane and imogolite and none contained gibbsite, whereas parallel figures were 15 and 7 for 22 upland soil samples. Substantial numbers of diatoms were found in 5 paddy and 1 paddy-converted upland soil samples. The lack of gibbsite was related to the stage of soil formation rather than the paddy condition, whereas the presence of diatoms was related to both. Regarding layer silicates, there was no particular difference between the paddy and upland soil samples but one unidentified mineral with unique morphology and infrared spectrum was found in two paddy soil samples. There was no particular difference in phosphate adsorption between the paddy and upland soil samples.     

Volcanic ash and its clay mineralogy at Cape Hoskins,New Britain,Papua New Guinea

Volcanic ash falls, the oldest laid down approximately 2500 years ago, are described and correlated wherever possible.Most of these ash deposits are thought to have been derived from the Garbuna volcano, located about 40–50 km from Cape Hoskins.Clay mineral data show with increasing age a weathering sequence in the beds in which allophane changes to halloysite. Charcoal data indicate that large amounts of halloysite are present in fossil soil horizons dated between 300 and 2000 years B.P. This compares with a date of 8000–9000 years from Japan,whereas data from St. Vincent indicate that halloysite can be formed under humid tropical conditions within 4000 years.     

Experimental simulation of the results of clay translocation in the B horizons of soils; the formation of intrapedal cutans

A series of laboratory experiments designed to simulate the formation of intrapedal cutans was carried out through repetitive leachings of undisturbed blocks of soils (6 × 3 × 4 cm³) by suspensions (0.3% concentration) of clay-sized particles from two commonly occurring Bt horizons in southern England. After leaching, thin sections were cut and point-counted, thus enabling the visual recognition, replication and potential quantification of newly formed intrapedal pore and grain cutans. They all exhibit morphological, physical and optical properties diagnostic of illuviation cutans, and can be differentiated from inherited cutans on these and on spatial grounds. A general relationship between numbers of newly formed cutans and increasing leaching cycles was observed, and experimental support obtained from these soils for the significance of the complex, three-dimensional spatial pattern of tubular pores in the translocation of clay-sized materials and the formation of these argillic, Bt horizons. This study highlights both the value and difficulties of designing laboratory-based, soil/water/gravity studies in pedology.     

Tubular and spheroidal halloysite in pyroclastic deposits in the area of the Roccamonfina volcano (Southern Italy)

Halloysite-bearing weathered pyroclastic deposits of the Roccamonfina volcanic area (Southern Italy), consisting generally of light grey clay masses richer in slightly weathered pumice grains, mottled patches of whitish clayey material and yellowish-brown veins along vertical root channels, were characterised by chemical analysis, X-ray diffraction (XRD), infrared spectroscopy (FT-IR), optical (OM), scanning (SEM) and transmission (TEM) microscopy, electron diffraction (ED) and energy dispersive X-ray analysis (EDXRA). Both tubular and spheroidal forms of halloysite were observed, different parts of the deposits being characterised by a particular morphology. No consistent differences in terms of the chemical and mineralogical composition of the deposit materials were found. However, the chemical composition of the different particle-size clay fractions indicated that less silica, with concomitant relative enrichment in aluminium, and loss of bases characterised the <0.5 μm compared with the 0.5–2.0 μm fraction reflecting their differences in the content of primary minerals. The amounts of Fe, Al and Si extracted by dithionite–citrate–bicarbonate (DCB) and oxalate reagents suggested the presence of short-range-order aluminosilicates but this could not be proved by other physical techniques. X-ray analysis revealed the presence of hydrated (1 nm) and dehydrated (0.7 nm) halloysite, mica, sanidine and plagioclase minerals. TEM/EDXRA analysis of the <0.5 μm clay fraction revealed an amorphous Si-rich phase in the sample containing spheroidal halloysite. The differential X-ray diffraction analysis (DXRD) from untreated and DCB treated yellowish-brown material along with the electron diffraction (ED) of the <0.5 μm clay fraction showed the presence of goethite and ferrihydrite. The various weathered pyroclastic materials showed a major difference in terms of their physical characteristics, particularly in terms of their compactness and porosity/permeability as revealed by microscopic and sub microscopic observations. It is suggested that the different morphological forms of halloysite may result from conditions of growth in the different microenvironments related to variability in physical conditions.     

Stratigraphic Distribution of Lignite-Derived Atmospheric Deposits in Forest Soils of the Upper Lusatian Region,East Germany

Atmospheric fly ash emissions from lignite-fired power plantsin the Upper Lusatian and Turówan mining districts stronglyaffected large forest areas along the German-Polish border. Afield study was conducted in old spruce stands (Piceaabies (L.) Karst.) to assess the stratigraphic distributionof fly ash in the forest floor and mineral topsoil in the St. Marienthal forest area in the eastern part of Saxony,Germany. This forest area is subjected to long-termatmospheric depositions by two German and one Polish powerplants since the early 1900s. The three study sites arelocated along a fly ash deposition gradient of 3, 6 and 15 kmfrom the power plant in Turów (Sites Ia, II and III,respectively). An additional site (Site Ib) at a distance of 3 km from Turów was chosen to study the influence of vegetationtype on fly ash deposition intensity in forest soils. Samplesof the humic layer (Oi (L), Oe (F) and Oa (H) horizons) andmineral soil (0–10 cm) were taken in Spring and Fall 1999 andanalysed for their ferromagnetic susceptibility and total ashcontent. Particle size distribution, magnetic susceptibilityof individual size fractions, scanning electron microscopy(SEM), and energy dispersive X-ray microanalysis (EDX) wereperformed on selected samples to evaluate the origin ofmineral particles found in the forest floor. High magneticsusceptibility of the Oa and Oe horizons is a result of thelong-term accumulation of lignite-derived atmospheric depositsin the forest floors of the studied area. Pure conifer stands(year-round filtration of airborne pollutants) resulted inhigher inputs of ferromagnetic fly ash particles in forestsoils. Unusually high total ash contents for humic horizons(up to 77%) were determined in the Oa and Oe horizons atSites Ia and IIb, indicating the need for a new classificationsystems for the organic layer in forest soils near coal-firedpower plants. SEM revealed 4 typical phases of persistent flyash deposits formed by combustion of Lusatian lignite: (1) iron-containing `stable glasses’, (2) aluminium-iron-silicate-minerals,(3) slag fragments and (4) lignite-derived fossilcarbon. Particle size analysis, magnetic susceptibilitymeasurements and SEM-EDX techniques indicated that a greatportion of the mineral particles found in the humic horizonsof forests soils are from atmospheric sources. Fly ashaccumulation consisting of ferromagnetic minerals contributesmainly to the 125–63 and <63 μm fractions in soils. EDXanalysis revealed that atmospheric input of lignite-derivedfly ash increases the contents of the following ecologicalrelevant elements in soils: carbon, iron, aluminium, calcium,potassium, sulphur, titanium and sodium.     

THE MONOSACCHARIDE COMPOSITION OF POLYSACCHARIDES IN ANDO SOILS

The monosaccharide composition of Ando soils, which originate from volcanic ash and have high organic matter content (8–21% carbon), was quite different from that of non-volcanic ash soils (1.2–1.9% carbon), being richer in mannose, fucose and ribose, whereas there was less glucose in cellulose-like form, arabinose, xylose and rhamnose. The Ando soils were also characterized by a lower percentage of organic carbon in the form of saccharide (4.4–7.4%) in comparison with non-volcanic ash soils (10.5%), though the former soils contain a greater amount of saccharides. The monosaccharide composition of Ando soils was unrelated to the vegetation, land usage, or climatic conditions, and is presumed to be a soil characteristic resulting from the preferential accumulation of microbial polysaccharides.     

Changes in soil properties after afforestation in Horqin Sandy Land,North China

We studied the changes in soil properties after afforestation on desertification-affected sandy soils to estimate how much time would be required for soils to recover enough for use in sustainable food production. We surveyed soils near and within 3-, 9-, and 19year- old plantations of poplar (Poplus simonii) in the central part of Naiman County, eastern Inner Mongolia, China. Changes in the soil properties following afforestation included an accumulation of fine particles (clay + silt) and soil organic carbon (SOC) in the surface horizons. The contents of fine particles and SOC increased slowly in the first 9-year period and then rapidly between 10 and 19 years, being higher at concave than convex sites. Soil parameters such as available moisture level, amounts of available N and available P, and CEC that control soil fertility showed a similar trend to that of the contents of fine particles and SOC. The contents of fine particles and SOC were higher at the windward edge than in the center of the 19-year-old poplar plantation, suggesting that the accumulation of fine particles was caused by the decrease in wind velocity due to the presence of vegetation. The increase in the SOC content may be caused by the increased carbon input to soils from the vegetation and by the deposition of fine particles with a higher C concentration than that of native sandy soils. Soil fertility, represented by the amounts of available N in the upper 20 cm layer of the soil, recovered after 19 years under poplars, and was similar to that of adjacent fertile cropland. However, the amount of available N under plantations younger than 10 years was lower than that in cropland soils, suggesting that a period of between 10 and 20 years is required for soils to recover from desertified conditions and be utilized for intensive crop farming once again.     

Similarities and differences of the spheroidal microstructure in Vertisols from Turkey and Israel

Vertisols formed on different parent materials from Turkey (Aslanpınarı and Begde soil series) and Israel (Akko soil series) were studied for their microstructure. The Aslanpınarı and Begde soils showed similar spheroidal microstructural development in the ABss horizons, whereas the spheres of Akko differed by being smaller and lacking granostriation. Micromorphometric analyses of the three soils revealed similar pore characteristics within and between the aggregates of the ABss horizons. Presence of the spheroidal microstructural units and increase of palygorskite and vermiculite in the ABss horizon of the Be de soil, which is in contrast with increasing smectite in the Aslanpınarı and Akko soils, links with an increase in the structural stability index and an increase in the hydraulic conductivity.